Structural Study of Molten Silver Halides by Neutron Diffraction

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概要

• 論文の詳細を見る

• The Structure factors of molten AgCl, AgBr and Agl have been obtained byneutron scattering measurements at two different temperatures in order to investigatethe local structure and its temperature dependence. The partial structural parameterssuch as a partial coordination number and an infer ionic distance have been defer-mined by curve fitting analysis. Molten silver halides are found to have tetrahedralcoordination of the local order near the melting points. The local order for moltenAgCl and AgBr is broken with increasing temperature, while that for molten Agl ispreserved even at high temperature. This suggests that the bonding in molten Agl hasmore covalent character than that in molten AgCl and AgBr.[neutron diffraction, local structure, molten silver chloride, molten silver ll bromide, molten silver iodide, molten saltlI

• 社団法人日本物理学会の論文
• 1991-09-15

著者

• YAMAGUCHI Yasuo

  Institute for Materials Research, Tohoku University

• 山下 洋

  京都大学フィールド科学教育研究センター舞鶴水産実験所里海生態保全学分野

• Tamaki Shigeru

  Department of Physics, Faculty of Science, Niigata University

• Inui Masanori

  College of General Education, Kyushu University

• Shirakawa Yoshiyuki

  Graduate School of Science and Technology, Niigata University

• Waseda Yoshio

  Research Institute of Mineral Dressing and Metallurgy(SENKEN)

• Waseda Y

  Tohoku Univ. Sendai Jpn

• Takeda S

  Laboratory Of Entomology Faculty Of Agriculture Gifu University

• Waseda Yoshio

  Inst. Of Multidisciplinary Res. For Advanced Materials Tohoku Univ.

• Shirakawa Y

  Osaka Univ. Osaka

• Shirakawa Yoshiyuki

  Department Of Materials Science And Processing Faculty Of Engineering Osaka University

• Yamaguchi Yasuo

  Institute For Materials Research Tohoku University

• Yamaguchi Y

  Central Workshop Osaka University

• Waseda Yoshio

  Institute For Advanced Materials Proedding (amp) Tohoku University

• Shigeru Tamaki

  Department Of Physics Faculty Of Science Niigata University

• Tamaki Shigeru

  Graduate School Of Integrated Science Yokohama City University

• Tamaki Shigeru

  Faculty Of Science Niigata University

• Tamaki Shigeru

  Facully Of Sciance Of Sciance Niigata University

• Shirakawa Yoshiyuki

  Graduate School Of Science And Technology Niigata University

• Shin′ichi Takeda

  Department Of Physics College Of General Education Kyushu University

• Tamaki Shigeru

  Department Of Physics Faculty Of Science Niigata Unibersity

• Waseda Yoshio

  Research Institute Of Mineral Dressing And Metallurgy

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