Absolute Configuration of a Polyol Fragment of Blasticidin A, a Specific Inhibitor of Aflatoxin Production
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概要
- 論文の詳細を見る
Blasticidin A (1) and aflastatin A (2), Streptomyces metabolites with similar structures, are specific inhibitors of aflatoxin production by Aspergillus parasiticus. The stereochemistry of the polyol fragment of 1 (3a) containing ten chiral centers was elucidated by applying acetonide and MTPA methods to a variety of acetonide derivatives of 3a, which determined the absolute configuration of 3a. By using the similar methods, the absolute configuration of the polyol fragment of 2 (4a) was determined, which was the same as that elucidated by J-based and other chemical methods previously.
- 社団法人 日本農芸化学会の論文
- 2004-02-23
著者
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作田 庄平
東京大学大学院農学生命科学研究科応用生命化学専攻
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Sakuda S
Department Of Applied Biological Chemistry The University Of Tokyo
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Nagasawa Hiromichi
Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The U
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SAKUDA Shohei
Department of Applied Biological Chemistry, University of Tokyo
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IKEDA Hiroyuki
Department of Applied Biological Chemistry, University of Tokyo
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Sakuda Shohei
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Nihira Takuya
Department Of Biotechnology Osaka University
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NAKAMURA Takefumi
Department of Applied Biological Chemistry, The University of Tokyo
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Nakamura Takefumi
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Nagasawa Hiromichi
Graduate School Of Agricultural And Life Sciences University Of Tokyo
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Nagasawa Hiromichi
Department Of Agricultural Chemistry Faculty Of Agriculture The University Of Tokyo
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Nagasawa Hiromichi
Department Of Applied Biological Chmistry Graduate School Of Agricultural And Life Sciences The Univ
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Nihira T
International Center For Biotechnology Osaka University
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Ikeda Hiroyuki
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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作田 庄平
東大 大学院
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Ikeda Hiroyuki
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Nihira T
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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SAKUDA Shohei
Department of Agricultural Chemistry, The University of Tokyo
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