The reactions of (trichlorostannato)rhodates(III) with trichlorostannate(II) in hydrochloric acid solutions.
スポンサーリンク
概要
- 論文の詳細を見る
(Trichlorostannato)rhodate(III) complexes, [(CH<SUB>3</SUB>)<SUB>4</SUB>N]<SUB>3</SUB>[RhCl<I><SUB>n</SUB></I>(SnCl<SUB>3</SUB>)<SUB>6−<I>n</I></SUB>] (<I>n</I>=2, 3, and 4), reacted with tin(II) in hydrochloric acid solutions to form a purple species. This purple species is assumed to be [Rh<SUP>I</SUP>(SnCl<SUB>3</SUB>)<SUB>5</SUB>]<SUP>4−</SUP>. The formation reaction of the purple species involved two independent paths, fast and slow paths. The main path was the fast one, in which the reactant mixture was in equilibria among [RhCl<SUB>3</SUB>(SnCl<SUB>3</SUB>)<SUB>3</SUB>]<SUP>3−</SUP>, [RhCl<SUB>2</SUB>(SnCl<SUB>3</SUB>)<SUB>4</SUB>]<SUP>3−</SUP>, [RhCl(SnCl<SUB>3</SUB>)<SUB>5</SUB>]<SUP>3−</SUP>, and probably [Rh(SnCl<SUB>3</SUB>)<SUB>6</SUB>]<SUP>3−</SUP>. The reaction orders in the formation of the purple species were 1, 2, and −2 with respect to the concentrations of the total rhodium(III) complexes, SnCl<SUB>3</SUB><SUP>−</SUP>, and Cl<SUP>−</SUP> respectively. The absorpton spectra of the reactant mixture showed an interaction absorption between [RhCl<SUB>2</SUB>(SnCl<SUB>3</SUB>)<SUB>4</SUB>]<SUP>3−</SUP> and SnCl<SUB>3</SUB><SUP>−</SUP>.
- 公益社団法人 日本化学会の論文
著者
-
Nagai Takashi
Department Of Animal Breeding And Reproduction National Institute Of Livestock And Grassland Science
-
Miki Eiichi
Department Of Chemistry College Of Science Rikkyo University
-
Ishimori Tatsujiro
Department Of Chemistry College Of Science Rikkyo University
-
Mizumachi Kunihiko
Department Of Chemistry College Of Science Rikkyo University
-
Iwasaki Shigemi
Department of Chemistry, College of Science, Rikkyo University
-
Nagai Takashi
Department of Chemistry, College of Science, Rikkyo University
関連論文
- Reactive Hypoglycemia Associated with Transient Hyperthyroidism in the Background of the Prediabetic Stage
- 沖縄島漫湖饒波川のマングローブ域における大型底生生物の分布と出現量
- Introduction of Various Vietnamese Indigenous Pig Breeds and Their Conservation by Using Assisted Reproductive Techniques
- Effect of Cryoprotectant Composition on In Vitro Viability of In Vitro Fertilized and Cloned Bovine Embryos Following Vitrification and In-Straw Dilution
- Deterioration of Retinopathy After Starting Interferon Therapy for Chronic Hepatitis C with Diabetic Triopathy
- Secondary Hemochromatosis Accompanied by Diabetes Mellitus and Hypogonadism.
- Seroconversion of Glutamic Acid Decarboxylase Antibodies in a Patient Initially Diagnosed as Having Type 2 Diabetes Mellitus
- Metformin Use in an Obese Diabetic Patient from Weeks 1 to 21 of Pregnancy.
- Sarcoid Granulomatous Interstitial Nephritis Accompanied by Type 2 Diabetes Mellitus
- Developmental Competence of Cat Oocytes from Ovaries Stored at Various Temperature for 24 h
- シクロヘキシミドへの曝露が電気的に活性化したネコ卵母細胞の発育に及ぼす効果
- Taxonomy of the Terrestrial Crab Geothelphusa tenuimanus (Crustacea: Decapoda: Brachyura: Potamidae) of Okinawa Island, Central Ryukyus, Japan
- Evaluation of Developmental Competence of In Vitro-produced Porcine Embryos Based on the Timing, Pattern and Evenness of the First Cleavage and Onset of the Second Cleavage
- Intracytoplasmic Sperm Injection in the Pig : Where is the Problem?
- Nuclear and Cytoplasmic Maturation In Vitro of Porcine Oocytes
- Effect of Bezafibrate or Pravastain on Serum Lipid Levels and Albuminuria in MIDDM Patients
- Effect of Nephropathy on the Composition of Apolipoprotein-Containing Particles in NIDDM
- Prader-Willi Syndrome with Elevated Follicle Stimulating Hormone Levels and Diabetes Mellitus
- Diabetes Mellitus Accompanied by Nonocclusive Colonic Ischemia
- Candida Glabrata Fungemia After Amputation of an Infected Diabetic Foot
- Cervical Spinal Epidural Abscess and Perirenal Abscess Associated with Diabetes Mellitus
- An Overwhelming Postsplenectomy Infection Syndrome Associated with Diabetes M ellitus
- M ultiple Organ Failure Followed by Intrauterine Klebsiella Pneumoniae Infection Associated with Diabetes M ellitus
- An approach for conservation of pig resources by xenograft of gonadal tissue to mice
- Effect of Centrifugation Treatment before Vitrification on the Viability of Porcine Mature Oocytes and Zygotes Produced In Vitro
- 初期胞状卵胞から採取した牛卵母細胞の生存と体外成長に及ぼす酸素濃度の影響
- Crystal Structure of Bis-(2, 2'-bipyridine)chloronitrosylruthenium(II)Perchlorate
- A Comparison of Cryotop and Solid Surface Vitrification Methods for the Cryopreservation of In Vitro Matured Bovine Oocytes
- Interspecies Nuclear Transfer Embryos Reconstructed from Cat Somatic Cells and Bovine Ooplasm
- Health Status and Productive Performance of Somatic Cell Cloned Cattle and Their Offspring Produced in Japan
- Larval Development of a Pontoniine Shrimp, Periclimenes brevicarpalis (Crustacea : Decapoda : Palaemonidae) Reared in the Laboratory
- 無血清成熟培地へのシステアミンの添加がウシ未成熟卵子の体外成熟率,体外受精率およびその後の発生率に及ぼす影響
- Reversible Thermal Isomerization of Three Geometrical Isomers for Chlorobis (2-methyl-8-quinolinolato) nitrosylruthenium(III)
- Pregnancy complicated with Alport syndrome : A good obstetric outcome and failure to diagnose an infant born to a mother with Alport syndrome by umbilical cord immunofluorescence staining
- Developmental Competence of Cat Oocytes from Ovaries Stored at Various Temperature for 24h
- Effect of Cycloheximide on In Vitro Development of Electrically Activated Feline Oocytes
- Development of Porcine Embryos Reconstructed by Nuclear Transfer of Cultured Cumulus Cells into In Vitro Matured and Enucleated Oocytes
- Ejaculated Boar Spermatozoa Can Penetrate Oocytes Maturing In Vitro without Preincubation
- Solids Circulation Rate in Screen-Bottomed Spouted Bed with Draft-Tube
- Nitrogen Uptake by Paddy Rice (Oryza sativa L.) from ^N Labelled Coated Urea and Ammonium Sulfate
- HUMAN NEUROPHYSINS DURING PREGNANCY, PUERPERIUM AND MENSTRUAL CYCLES
- Growth, Prey Consumption and Food Assimilation Efficiency in a Mantid, Paratenodera angustipennis (S.)
- Germinal Vesicle Stages in Pig Follicular Oocytes Collected by Different Methods
- Evaluation of Developmental Competence of In Vitro-produced Porcine Embryos Based on the Timing, Pattern and Evenness of the First Cleavage and Onset of the Second Cleavage
- 4Cで冷蔵保存された精巣上体から採取・凍結・融解した精子を用いたブタの繁殖の試み
- Effect of β-Merchaptoethanol on the Preimplantation Development of Bovine Embryos Fertilized In Vitro
- A Long- lived Intermediate with a Unidentate Dmbpy Ligand in the Photosubstitution of [Ru(bpy)_2(dmbpy)]^ (dmbpy=3,3'-dimethyl-2,2'-bipyridine)
- 91. Concerning the Clinical Significance of Air Myelography
- In Situ Lymph Dynamic Characterization through Lymph Nodes in Rabbit Hind Leg : Special Reference to Nodal Inflammation
- 66. Clincal Investigation on Ossification of Postero-Longitudinal Ligamentum around the Cervical Vertebrae with Cord Compression. (Proceedings of the XXVth Annual Meeting of the Japan Neurosurgical Society)
- Constant transmission of mitochondrial DNA in intergeneric cloned embryos reconstructed from swamp buffalo fibroblasts and bovine ooplasm
- Real-time imaging of the lymphatic channels and sentinel lymph nodes of the stomach using contrast-enhanced ultrasonography with Sonazoid in a porcine model
- SPOUTED BED WITH A DRAFT-TUBE WITHOUT GAS INLET NOZZLE OR ORIFICE
- Downregulation of Histone Methyltransferase Genes SUV39H1 and SUV39H2 Increases Telomere Length in Embryonic Stem-like Cells and Embryonic Fibroblasts in Pigs
- A case of an autonomously functioning thyroid nodule associated with low triiodothyronine concentrations.
- Infrared Spectra of Pentacyanonitrosylmanganese (14NO and 15NO) Complexes
- Reaction of (CoL2)2H2O, (Co(NO)L2), or (Co(NO)L2(py)) (L=8-quinolinolate ion; py=pyridine) with nitrogen monoxide: Disproportionation of nitrogen monoxide induced by cobalt complexes.
- The reaction of (CoL2) or (CoL2(NO))(L=4-methyl-8-quinolinolate ion) with nitrogen monoxide.
- A Case of Adrenocortical Adenoma Producing 11-Deoxycorticosterone (DOC) Independent of ACTH Control.
- Syntheses of Trinuclear Riitheniiim(III) Complexes with Dichloroacetato Ligands
- Chloropentakis(trichlorostannato)ruthenate(II)
- Infrared Spectra of Nitrosylplatinum (14NO and 15NO) Complexes
- Infrared Spectra of Some Transition-metal (Fe, Co, Ru, and Ir) Nitrosyl (14NO and 15NO) Complexes
- The Cation-exchange Separation of Nitrosylruthenium(III) from Ruthenium(III and IV) and Its Radiochemical Applications
- Optical resolution of di-2-pyridylamine complexes of ruthenium(II).
- Crystal and molecular structures of two isomers for chlorobis(2-methyl-8-quinolinolato)nitrosylruthenium(III).
- Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their Properties
- Reaction of bis(4-methyl-8-quinolinolato)nitrosylpyridinecobalt(II) with nitrogen monoxide in dichloromethane.
- A case of pheochromocytoma accompanied with augmentation of growth hormone due to administration of growth hormone releasing hormone.
- Nitrosyliron complexes containing 8-quinolinolate or its derivatives.
- The reactions of (trichlorostannato)rhodates(III) with trichlorostannate(II) in hydrochloric acid solutions.
- Nitrosylrhodium (14NO and 15NO) Compounds Containing Triphenylphosphine
- Potassium .MU.-(trans-hyponitrito-N,N')-bis{pentacyanocobaltate(III)} and potassium .MU.-(trans-hyponitrito-O,O')-bis-{pentacyanocobaltate(III)}.
- Ruthenium Complexes with Coordinated Hydroxyiminoacetylacetonato or Bridging Nitrosyl Groups Formed by the Reactions of Nitrosylruthenium(III) with Acetylacetone
- New red pentaamminenitrosylcobalt(III) complexes obtained by the reaction of a cobalt(II)-ammoniacal solution with nitrogen oxide.
- Synthesis and structure of cis(O,O),trans(N,N)-chlorobis(8-quinolinolato-N1,O8)nitrosylruthenium.
- A case of T-cell non-hodgkin lymphoma with hypercalcemia due to massive bone metastatic lesions.
- Downregulation of Histone Methyltransferase Genes SUV39H1 and SUV39H2 Increases Telomere Length in Embryonic Stem-like Cells and Embryonic Fibroblasts in Pigs