Chloropentakis(trichlorostannato)ruthenate(II)
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概要
- 論文の詳細を見る
The cesium and triethylammonium salts of chloropentakis(trichlorostannato)ruthenate(II), Cs<SUB>4</SUB>[RuCl(SnCl<SUB>3</SUB>)<SUB>5</SUB>]·CsCl and (Et<SUB>3</SUB>NH)<SUB>4</SUB>[RuCl(SnCl<SUB>3</SUB>)<SUB>5</SUB>], were prepared. Their IR absorption bands near 210 cm<SUP>−1</SUP>are thought to be due to the Ru–Sn stretching vibration. The electronic spectra of dilute hydrochloric acid solutions of the complex salts were the same as the spectrum of a single crystal of the cesium salt. This suggests the presence of the complex ion, [RuCl(SnCl<SUB>3</SUB>)<SUB>5</SUB>]<SUP>4−</SUP>, in acid solutions. A hydrolysis product of the complex ion contained ruthenium, tin and chlorine in the atom ratio of 1 : 5 : [α(<1)], and the cesium salt was yielded from a dilute hydrochloric acid solution of the hydrolysis product. The observations show the presence of the Ru–Sn bonds in the complex ion.
- 公益社団法人 日本化学会の論文
著者
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Ishimori Tatsujiro
Department Of Chemistry College Of Science Rikkyo University
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Mizumachi Kunihiko
Department Of Chemistry College Of Science Rikkyo University
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Okuno Hisateru
Department of Chemistry, College of Science, Rikkyo (St. Paul's) University
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Ihochi Haruhiko
Department of Chemistry, College of Science, Rikkyo (St. Paul's) University
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Ishimori Tatsujiro
Department of Chemistry, College of Science, Rikkyo (St. Paul's) University
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Ihochi Haruhiko
Department of Chemistry, College of Science, Rikkyo (St. Paul's) University
関連論文
- Crystal Structure of Bis-(2, 2'-bipyridine)chloronitrosylruthenium(II)Perchlorate
- Reversible Thermal Isomerization of Three Geometrical Isomers for Chlorobis (2-methyl-8-quinolinolato) nitrosylruthenium(III)
- A Long- lived Intermediate with a Unidentate Dmbpy Ligand in the Photosubstitution of [Ru(bpy)_2(dmbpy)]^ (dmbpy=3,3'-dimethyl-2,2'-bipyridine)
- Infrared Spectra of Pentacyanonitrosylmanganese (14NO and 15NO) Complexes
- Reaction of (CoL2)2H2O, (Co(NO)L2), or (Co(NO)L2(py)) (L=8-quinolinolate ion; py=pyridine) with nitrogen monoxide: Disproportionation of nitrogen monoxide induced by cobalt complexes.
- The reaction of (CoL2) or (CoL2(NO))(L=4-methyl-8-quinolinolate ion) with nitrogen monoxide.
- Syntheses of Trinuclear Riitheniiim(III) Complexes with Dichloroacetato Ligands
- Chloropentakis(trichlorostannato)ruthenate(II)
- Infrared Spectra of Nitrosylplatinum (14NO and 15NO) Complexes
- Infrared Spectra of Some Transition-metal (Fe, Co, Ru, and Ir) Nitrosyl (14NO and 15NO) Complexes
- The Cation-exchange Separation of Nitrosylruthenium(III) from Ruthenium(III and IV) and Its Radiochemical Applications
- Optical resolution of di-2-pyridylamine complexes of ruthenium(II).
- Crystal and molecular structures of two isomers for chlorobis(2-methyl-8-quinolinolato)nitrosylruthenium(III).
- Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their Properties
- Reaction of bis(4-methyl-8-quinolinolato)nitrosylpyridinecobalt(II) with nitrogen monoxide in dichloromethane.
- Nitrosyliron complexes containing 8-quinolinolate or its derivatives.
- The reactions of (trichlorostannato)rhodates(III) with trichlorostannate(II) in hydrochloric acid solutions.
- Nitrosylrhodium (14NO and 15NO) Compounds Containing Triphenylphosphine
- Potassium .MU.-(trans-hyponitrito-N,N')-bis{pentacyanocobaltate(III)} and potassium .MU.-(trans-hyponitrito-O,O')-bis-{pentacyanocobaltate(III)}.
- Ruthenium Complexes with Coordinated Hydroxyiminoacetylacetonato or Bridging Nitrosyl Groups Formed by the Reactions of Nitrosylruthenium(III) with Acetylacetone
- New red pentaamminenitrosylcobalt(III) complexes obtained by the reaction of a cobalt(II)-ammoniacal solution with nitrogen oxide.
- Synthesis and structure of cis(O,O),trans(N,N)-chlorobis(8-quinolinolato-N1,O8)nitrosylruthenium.