Infrared Spectra of Pentacyanonitrosylmanganese (<SUP>14</SUP>NO and <SUP>15</SUP>NO) Complexes

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概要

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• The <SUP>15</SUP>NO-complexes for K<SUB>3</SUB>[Mn(CN)<SUB>5</SUB>(NO)]·2H<SUB>2</SUB>O, K<SUB>3</SUB>[Mn(CN)<SUB>5</SUB>(NO)] and Ag<SUB>2</SUB>[Mn(CN)<SUB>5</SUB>(NO)] were prepared. By measuring and calculating the effect of the nitrogen isotope <SUP>15</SUP>N on the infrared spectra, the Mn–N–O arrangement was found in all the complexes, and the absorption bands due to the skeletal vibrations between the manganese and the NO group were clearly assigned.

• 公益社団法人 日本化学会の論文

著者

• Miki Eiichi

  Department Of Chemistry College Of Science Rikkyo University

• Ishimori Tatsujiro

  Department Of Chemistry College Of Science Rikkyo University

• Mizumachi Kunihiko

  Department Of Chemistry College Of Science Rikkyo University

• Okuno Hisateru

  Department of Chemistry, College of Science, Rikkyo (St. Paul's) University

• Kubo Soto-o

  Department of Chemistry, College of Science, Rikkyo University

関連論文

• Crystal Structure of Bis-(2, 2'-bipyridine)chloronitrosylruthenium(II)Perchlorate
• Reversible Thermal Isomerization of Three Geometrical Isomers for Chlorobis (2-methyl-8-quinolinolato) nitrosylruthenium(III)
• A Long- lived Intermediate with a Unidentate Dmbpy Ligand in the Photosubstitution of [Ru(bpy)_2(dmbpy)]^ (dmbpy=3,3'-dimethyl-2,2'-bipyridine)
• Infrared Spectra of Pentacyanonitrosylmanganese (14NO and 15NO) Complexes
• Reaction of (CoL2)2H2O, (Co(NO)L2), or (Co(NO)L2(py)) (L=8-quinolinolate ion; py=pyridine) with nitrogen monoxide: Disproportionation of nitrogen monoxide induced by cobalt complexes.
• The reaction of (CoL2) or (CoL2(NO))(L=4-methyl-8-quinolinolate ion) with nitrogen monoxide.
• Syntheses of Trinuclear Riitheniiim(III) Complexes with Dichloroacetato Ligands
• Chloropentakis(trichlorostannato)ruthenate(II)
• Infrared Spectra of Nitrosylplatinum (14NO and 15NO) Complexes
• Infrared Spectra of Some Transition-metal (Fe, Co, Ru, and Ir) Nitrosyl (14NO and 15NO) Complexes
• The Cation-exchange Separation of Nitrosylruthenium(III) from Ruthenium(III and IV) and Its Radiochemical Applications
• Optical resolution of di-2-pyridylamine complexes of ruthenium(II).
• Crystal and molecular structures of two isomers for chlorobis(2-methyl-8-quinolinolato)nitrosylruthenium(III).
• Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their Properties
• Reaction of bis(4-methyl-8-quinolinolato)nitrosylpyridinecobalt(II) with nitrogen monoxide in dichloromethane.
• Nitrosyliron complexes containing 8-quinolinolate or its derivatives.
• The reactions of (trichlorostannato)rhodates(III) with trichlorostannate(II) in hydrochloric acid solutions.
• Nitrosylrhodium (14NO and 15NO) Compounds Containing Triphenylphosphine
• Potassium .MU.-(trans-hyponitrito-N,N')-bis{pentacyanocobaltate(III)} and potassium .MU.-(trans-hyponitrito-O,O')-bis-{pentacyanocobaltate(III)}.
• Ruthenium Complexes with Coordinated Hydroxyiminoacetylacetonato or Bridging Nitrosyl Groups Formed by the Reactions of Nitrosylruthenium(III) with Acetylacetone
• New red pentaamminenitrosylcobalt(III) complexes obtained by the reaction of a cobalt(II)-ammoniacal solution with nitrogen oxide.
• Synthesis and structure of cis(O,O),trans(N,N)-chlorobis(8-quinolinolato-N1,O8)nitrosylruthenium.

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