NAD(P)+-NAD(P)H model. 63. Regioselective reduction of dienoic ketones and aldehydes with an NAD(P)H model on silica gel.

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概要

• 論文の詳細を見る

• The Hantzsch ester reduces carbon–carbon double bonds in α,β-unsaturated ketones and aldehydes under the catalysis of silica gel. The 1,4-selectivity is satisfactorily high even in the reductions of polyenes conjugated to a carbonyl group. Methyl substituent at an olefinic position (α or β to the carbonyl group) retards the reduction. The reduction can be used as a useful tool in obtaining building blocks for the syntheses of terpenoids and their derivatives.

• 公益社団法人 日本化学会の論文

著者

• Ohno Atsuyoshi

  Institute For Chemical Research Kyoto Univ.

• Nakamura Kaoru

  Institute For Chemical Research Kyoto University

• Oka Shinzaburo

  Institute For Chemical Research Kyoto University

• YASUI Shinro

  Tezukayama College

• Fujii Masayuki

  Institute for Chemical Research, Kyoto University

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