Vibration spectra and rotational isomerism of chain molecules. II. Butane, pentane, hexane, pentane-d12, and hexane-d14.
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概要
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The Raman spectra of butane, pentane, hexane, pentane-<I>d</I><SUB>12</SUB>, and hexane-<I>d</I><SUB>14</SUB> and infrared spectra of pentane-<I>d</I><SUB>12</SUB> and hexane-<I>d</I><SUB>14</SUB> were measured for the liquid and solid states. The rotational isomerism of normal paraffins was studied on the basis of the spectral observations and the normal coordinate calculations. The spectra of the deuterated compounds were useful in the confirmation of the less stable isomers and the establishment of the local symmetry force field of normal paraffins. The enthalpy differences among the rotational isomers were studied on pentane and hexane, which yielded some important data for the study of the conformations and properties of longer hydrocarbons.
- 公益社団法人 日本化学会の論文
著者
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Takeuchi Hideo
Department Of Applied Physics Faculty Of Engineering Osaka City University
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Matsuura Hiroatsu
Department Of Chemistry Faculty Of Science Hiroshima University
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Sakakibara Masaaki
Department of Chemistry, Faculty of Science, University of Tokyo
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Harada Issei
Department of Chemistry, Faculty of Science, The University of Tokyo
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Shimanouchi Takehiko
Department of Chemistry, Faculty of Science, The University of Tokyo
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