Vibration spectra and rotational isomerism of chain molecules. VIII. 1-Chloro-, 1-bromo-, and 1-iodopentanes, and 1,4-dichloro- and 1,4-dibromobutanes.
スポンサーリンク
概要
- 論文の詳細を見る
The Raman and infrared spectra of 1-chloro-, 1-bromo, and 1-iodopentanes CH<SUB>3</SUB>(CH<SUB>2</SUB>)<SUB>4</SUB>X (X=Cl, Br, and I), and 1,4-dichloro- and 1,4-dibromobutanes X(CH<SUB>2</SUB>)<SUB>4</SUB>X (X=Cl and Br) were measured for the gaseous, liquid, glassy, and crystalline states. The normal coordinates were calculated for these molecules by the use of a consistent set of force constants. The rotational isomerism was studied by analyzing the spectra with reference to the results of the calculation. The study clarified the isomers present not only in the crystalline state but also in other states of aggregation. In the crystal, 1-chloro-, 1-bromo-, and 1-iodopentanes take the <I>trans</I>-<I>trans</I>-<I>trans</I> form and 1,4-dichloro- and 1,4-dibromobutanes take the <I>gauche</I>-<I>trans</I>-<I>gauché</I> form.
- 公益社団法人 日本化学会の論文
著者
-
Matsuura Hiroatsu
Department Of Chemistry Faculty Of Science Hiroshima University
-
Shimanouchi Takehiko
Department of Chemistry, Faculty of Science, University of Tokyo
-
Ogawa Yoshiki
Department of Chemistry, Faculty of Science, University of Tokyo
-
Harada Issei
Department of Chemistry, Faculty of Science, University of Tokyo
-
Imazeki Shuji
Department of Chemistry, Faculty of Science, University of Tokyo
-
Sakakibara Masaaki
Department of Chemistry, Faculty of Science, University of Tokyo
関連論文
- Raman Spectroscopic Observations of Anomalous Conformational Behavior of Short Poly(oxyethylene) Chains in Water
- Conformational Stability of 1,2-Dimethoxyethane in the Gas Phase Studied by Infrared Spectroscopy : Importance of an Intramolecular 1,5-CH…O Interaction
- Deuterium Nuclear Magnetic Resonance Study of Lipophilic Chains in the C_E_3/Decane/Water Ternary System
- Conformational Dynamics of Alkyl Chains in the Lamellar Phase of a Nonionic Surfactant C_E_3 Studied by Deuterium Nuclear Magnetic Resonance
- Protonation-induced Conformational Changes of 2-(N, N-Dimethylamino)ethanethiol. Importance of Strong N-H^+・・・S and N-H^+・・・S^- Hydrogen Bonding
- Protonation-Induced Conformational Changes of N,N,N',N'-Tetramethylethylenediamine. Importance of Strong N-H^+…N Hydrogen Bonding
- Conformational Order of the Alkyl Chain in a Nonionic Surfactant α-Dodecyl-ω-hydroxytris (oxyethylene) (C_E_3) in Water
- Melting of the All-trans Planar Modification of Triblock Oligomers α-n-Alkyl-ω-n-alkoxyoligo(oxyethylene)s
- Remarkable Changes in the (N)CH_3 Stretching Wavenumbers of Amines on Protonation
- Thermal Stability of the Hydration Structure of Short-chain Poly(oxyethylene) in Carbon Tetrachloride : An Infrared Spectroscopic Observation of the Breakdown of Hydrogen Bonds
- Temperature Dependence of the Anomalous Conformational Behavior of a Short-Chain Poly(oxyethylene) in Water Studied by Raman Spectroscopy
- High-Pressure Infrared Spectroscopy of Molecular Conformations of Diblock Oligomers α-Decyl-ω-hydroxyoligo(oxyethylene)s in the Solid State
- Hydration of Short-chain Poly(oxyethylene)s in Carbon Tetrachloride Studied by Infrared Spectroscopy
- Infrared Absorption Studies of Tropolone and Allied Compounds
- Vibration spectra and rotational isomerism of chain molecules. IV. Diethyl sulfide, ethyl propyl sulfide, and butyl methyl sulfide.
- Vibration spectra and rotational isomerism of chain molecules. I. Methyl propyl ether, ethyl propyl ether, and butyl methyl ether.
- Vibration spectra and rotational isomerism of chain molecules. VII. 1-Chloro-, 1-bromo-, and 1-iodopropanes, and 1-chloro-, 1-bromo-, and 1-iodobutanes.
- Vibration-Rotation Spectrum of Methyl Fluoride. I. Analysis of 2ν3 Band
- Vibration spectra and rotational isomerism of chain molecules. VI. 2-Chloro-, 2-bromo-, and 2-iodoethyl methyl ethers.
- Vibration spectra and rotational isomerism of chain molecules. II. Butane, pentane, hexane, pentane-d12, and hexane-d14.
- Vibration spectra and rotational isomerism of chain molecules. VIII. 1-Chloro-, 1-bromo-, and 1-iodopentanes, and 1,4-dichloro- and 1,4-dibromobutanes.
- Vibration-rotation spectrum of the coriolis-interacting band system .UPSILON.6 and .UPSILON.3 of acetonitrile-d3.
- Vibration spectra and rotational isomerism of chain molecules. III. Ethyl methyl sulfide and deuterium compounds.
- Vibration spectra and rotational isomerism of chain molecules. V. 2,5-Dioxahexane, 2,5-dithiahexane, and 2-oxa-5-thiahexane.
- The Polarization Measurement of He-Ne Laser Excitation Raman Lines of Liquid Acetone
- Crystal vibrations and intermolecular interactions of CH3X and CD3X (X=Cl, Br, and I).
- Hydration of the oxyethylene chain. Hypersonic velocities in aqueous solutions of .ALPHA.-methyl-.OMEGA.-methoxyoligo(oxyethylene)s and .ALPHA.-methyl-.OMEGA.-hydroxyoligo(oxyethylene)s as studied by Brillouin scattering.
- Vibrational spectra and rotational isomerism of alkyl vinyl ethers.
- Molecular force field of dialkyl selenides.
- Infrared and Raman Spectra and Rotational Isomerism of 1,4-Pentadiene
- Vibrational spectra and rotational isomerism of 2-chloro- and 2-bromoethyl methyl sulfides.