Infrared and Raman Spectra and Rotational Isomerism of 1,4-Pentadiene
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概要
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Rotational isomerism of 1,4-pentadiene has been studied. Normal frequencies have been calculated for the low frequency vibrations of four possible rotational isomers. From the change in the spectra in the gaseous, liquid, glassy, and solid states, it has been concluded that the two skew-skew forms (SS and SS′) and the <I>cis</I>-skew form (CS) are stable in the liquid and gaseous states, the SS and SS′ forms coexist in the glassy state, and only the SS form remains in the solid state. It has also been found that the energy difference among the three isomers in liquid state is not appreciably large.
- 公益社団法人 日本化学会の論文
著者
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Sakakibara Masaaki
Department of Chemistry, Faculty of Science, University of Tokyo
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Harada Issei
Department of Chemistry, Faculty of Science, The University of Tokyo
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Inagaki Fuyuhiko
Department of Biophysics and Biochemistry, Faculty of Science, The University of Tokyo
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Shimanouchi Takehiko
Department of Chemistry, Faculty of Science, The University of Tokyo
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