Lanthanide-Induced Nuclear Magnetic Resonance Shifts and Molecular Structure of L-Azetidine-2-Carboxylic Acid. I. Evaluation of the Shifts Intrinsic to the Lanthanide-Substrate 1:1 Complex
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概要
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The lanthanide-induced PMR shifts (LIS) were observed in D<SUB>2</SUB>O solution of L-azetidine-2-carboxylic acid using europium, nitrate as shift reagent. Two series of measurements were carried out with the successive dilution and the incremental dilution methods. The analysis of observed data shows that the formation of 1: 2 complex between the lanthanide ion and the substrate molecule should be taken into account in addition to 1:1 complex. The LIS's intrinsic to 1: 1 and 1:2 complexes were evaluated. An experimental method appropriate for obtaining the ratio of the LIS's intrinsic to 1: 1 complex is proposed.
- 公益社団法人 日本化学会の論文
著者
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Miyazawa Tatsuo
Department Of Biophysics And Biochemistry Faculty Of Science The University Of Tokyo
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Inagaki Fuyuhiko
Department of Biophysics and Biochemistry, Faculty of Science, The University of Tokyo
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Tasumi Mitsuo
Department of Biophysics and Biochemistry, Faculty of Science, The University of Tokyo
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Takahashi Seizo
Department of Biophysics and Biochemistry, Faculty of Science, The University of Tokyo
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