Vibration spectra and rotational isomerism of chain molecules. VII. 1-Chloro-, 1-bromo-, and 1-iodopropanes, and 1-chloro-, 1-bromo-, and 1-iodobutanes.
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概要
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The Raman and infrared spectra of 1-chloro-, 1-bromo-, and 1-iodopropanes, CH<SUB>3</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>X (X=Cl, Br, and I), and 1-chloro-, 1-bromo-, and 1-iodobutanes, CH<SUB>3</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>X (X=Cl, Br, and I), were measured for the gaseous, liquid, glassy, and crystalline states. The normal vibration frequencies were calculated, a consistent set of force constants explaining the frequencies of basic halogenoalkanes being assumed. The rotational isomerism was studied on the basis of the spectral observations and the normal coordinate calculations. The enthalpy differences among the rotational isomers were examined.
- 公益社団法人 日本化学会の論文
著者
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Yamaguchi Hiroko
Department Of Bioresources Chemistry Faculty Of Horticulture Chiba University
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Matsuura Hiroatsu
Department Of Chemistry Faculty Of Science Hiroshima University
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Shimanouchi Takehiko
Department of Chemistry, Faculty of Science, University of Tokyo
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Ogawa Yoshiki
Department of Chemistry, Faculty of Science, University of Tokyo
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Harada Issei
Department of Chemistry, Faculty of Science, University of Tokyo
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Imazeki Shuji
Department of Chemistry, Faculty of Science, University of Tokyo
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Harada Issei
Department of Chemistry, Faculty of Science, The University of Tokyo
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Shimanouchi Takehiko
Department of Chemistry, Faculty of Science, The University of Tokyo
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