Copper(I) chloride complex containing p-benzoquinone as a ligand.
スポンサーリンク
概要
- 論文の詳細を見る
A new complex [(NH<SUB>4</SUB>)Cu<SUB>3</SUB>Cl<SUB>4</SUB>(C<SUB>6</SUB>H<SUB>4</SUB>O<SUB>2</SUB>)<SUB>3⁄2</SUB>·H<SUB>2</SUB>O] was synthesized from CuCl<SUB>2</SUB>, hydroquinone, and NH<SUB>4</SUB>Cl in an aqueous solution, and its structure was characterized on the bases of its UV, IR, and ESR spectra and TGA. On heating, this complex was stable up to 100 °C, but above 120 °C <I>p</I>-benzoquinone was released quantitatively. The complex was found to be a polynuclear copper(I) complex containing <I>p</I>-benzoquinone molecules and chlorides as ligands, and to be a charge-transfer complex in which π-electrons of the ring carbons of <I>p</I>-benzoquinone form coordinate bonds with Cu(I). The formation process of the complex was:<BR>3CuCl<SUB>2</SUB>+3/2(C<SUB>6</SUB>H<SUB>6</SUB>O<SUB>2</SUB>)+H<SUB>2</SUB>O+NH<SUB>4</SUB>Cl=(NH<SUB>4</SUB>)Cu<SUB>3</SUB>Cl<SUB>4</SUB>(C<SUB>6</SUB>H<SUB>4</SUB>O<SUB>2</SUB>)<SUB>3⁄2</SUB>·H<SUB>2</SUB>O+3HCl
- 公益社団法人 日本化学会の論文
著者
-
Yamaguchi Hiroko
Department Of Bioresources Chemistry Faculty Of Horticulture Chiba University
-
Kimura Hiroshi
Department Of Anatomy Ii Shiga University Of Medical Science
-
Yasukouchi Kazuo
Department of Industrial Chemistry, Faculty of Engineering, Kumamoto University
関連論文
- A New Aspect of the Carotid Body Function Controlling Hypoxic Ventilatory Decline in Humans
- The scid Mutation Does Not Affect Slowly Repairing Potentially Lethal Damage That Is Sensitive To 0.23 M NaCl.
- Mental Stress Reduces Coronary Flow Velocity Reserve
- Membrane Localization of Protein-Tyrosine Phosphatase 1B is Essential for its Activation of Sterol Regulatory Element-Binding Protein-1 Gene Expression and Consequent Hypertriglyceridaemia
- Properties of Monolithic Silica Columns for HPLC
- THE ORIGIN AND THE EVOLUTION OF THE THIOESTER-CONTAINING PROTEIN(Physiology,Abstracts of papers presented at the 74^ Annual Meeting of the Zoological Society of Japan)
- FUNCTIONAL INVESTIGATION OF THE DRP/DHP/CRAM/UNC-33 FAMILY IN PLANARIANS, DUGESIA JAPONICA(Developmental Biology,Abstracts of papers presented at the 74^ Annual Meeting of the Zoological Society of Japan)
- Possibility of Preventive Treatment for EBV-associated NK Cell-lineage Proliferative Disorders
- RESULTS OF MULTIPLE CORONARY ARTERY BYPASS GRAFTING IN JAPANESE PATIENTS
- CORONARY ARTERY BYPASS GRAFTING BY UTILIZING THE INTERNAL MAMMARY ARTERY GRAFT IN 100 JAPANESE PATIENTS
- Trial of intraventricular ribavirin therapy for subacute sclerosing panencephalitis in Japan
- Primary Cerebral Angiitis Containing Marked Xanthoma Cells With Massive Intraparenchymal Involvement : Case Report
- Drug-Induced Hypersensitivity Syndrome due to Mexiletine Associated with Human Herpes Virus 6 and Cytomegalovirus Reactivation
- Molecular Properties of Mycelial Aggregate-Specific Lectin of Pleurotus cornucopiae(GENETICS, MOLECULAR BIOLOGY, AND GENE ENGINEERING)
- Two Genes Encoding Fruit Body Lectins of Pleurotus cornucopiae : Sequence Similarity with the Lectin of a Nematode-Trapping Fungus(Biochemistry & Molecular Biology)
- Postnatal development of Serotonergic terminal in rat cerebral cortex
- Ontogenesis of 5HT immunoreactive neurons in the rat brain
- Oral Vitamin C restores impaired Coronary Flow Reserve in Smokers
- Circadian Variation in Coronary Flow Reserve is disappeared in Coronary Heart Disease
- CD4- and CD56-positive T-cell line MTA, established from natural killer-like T-cell leukemia/lymphoma
- Heterotactic Polymerization of Methacrylates Having C-3 Ester Group
- 32. On the Experience of the Brachial Vertebral Angiography
- 29. A surgical case of an enormous acoustic tumor with atypical symtoms.
- 72. Experimental studies of hypothermia from the neurosurgical point of view. IV.
- 70. Experimental studies of hypothermia from the neurosurgical point of view. II.
- Neurocysticercosis as Solitary Parenchymal Lesion Confirmed by Mitochondrial Deoxyribonucleic Acid Sequence Analysis : Case Report
- Synthesis of Optically Active Polyarylates Having Axially Chiral Binaphthylene Unit
- Biosynthesis of Poly(3-hydroxyalkanoate)s with Terminal Alkene Groups in the Side Chains by Chromobacterium sp.
- Biosynthesis of Poly(3-hydroxyalkanoate)s with Terminal Alkene Groups in the Side Chains by Chromobacterium sp.
- Production of Polyester Blend of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) and Poly(3-hydroxyalkanoate) with Saturated and Unsaturated Monomers from 4-Hydroxybutyric Acid by Chromobacterium sp.
- Synthesis and Biodegradation of Polyesters Based on O - Methylene Tartaric Acid
- Effective Biosynthesis of Poly(3-hydroxybutyrate) from Plant Oils by Chromobacterium sp.
- Synthesis and Photoinduced Transformation of a Helical Aromatic Polyamide Having Optically Active Binaphthol Units in the Main Chain
- Production and Characterization of Poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid) from L-Valine by Ralstonia eutropha
- Biosynthesis of Terpolythioesters with 3-Mercaptopropionate Unit
- Purificaiton and characterization of Secretory-Type GDP-L-Fucose: β-D-Galactoside 2-α-L-Fucosyltransferase from Human Gastric Muscosa
- Hemiconvulsion-hemiplegia syndrome and primary human herpesvirus 7 infection
- Early changes in bone mineral content caused by acute irradiation are not observed after daily fractionation: A study dual-energy X-ray absorptiometry
- Postmortem computed tomography findings as evidence of traffic accident-related fatal injury
- Successful Treatment of Neonatal Herpes Simplex-Type 1 Infection Complicated by Hemophagocytic Lymphohistiocytosis and Acute Liver Failure
- Multiplex real-time PCR for the simultaneous detection of herpes simplex virus, human herpesvirus 6, and human herpesvirus 7
- Comparison of Real-Time and Nested PCR Assays for Detection of Herpes Simplex Virus DNA
- Investigation of Varicella-Zoster Virus DNA in Lymphocyte Subpopulations by Quantitative PCR Assay
- Prevalence of Maternal Cytomegalovirus (CMV) Antibody and Detection of CMV DNA in Amniotic Fluid
- FIBRONECTIN-LIKE IMMUNOREACTIVE STRUCTURES IN EMBRYONIC RAT BRAIN (Modern Histo- and Cytochemistry in Neuroscience : Embryogenesis and Regeneration of the Nervous System)
- Immunohistochemical Demonstration of Fibronectin in the Rat Embryo.
- Arterial and Mixed Venous Oxygen Desaturation during Incremental Exercise in Patients with Chronic Pulmonary Disease
- Control of Upper Airway Function in Response to Hypoxia in Patients with Obstructive Sleep Apnea Syndrome
- Compensatory Excretion of Prostacyclin and Thromboxane Metabolites in Obstructive Sleep Apnea Syndrome
- Analysis of Heart Rate Profile during Obstructive Sleep Apnea
- Detection of Herpesvirus DNA in the Serum of Immunocompetent Children
- Chronic active Epstein-Barr virus infection with dilatation of the Valsalva sinus
- Proposed categorization of pathological states of EBV-associated T/natural killer-cell lymphoproliferative disorder (LPD) in children and young adults : Overlap with chronic active EBV infection and infantile fulminant EBV T-LPD
- -316- IONIC ALTERATIONS IN MYOCARDIAL CELLS DURING OPEN HEART SURGERY STUDIED BY X-RAY MICROANALYSIS
- Combination therapy with intraventricular interferon-α and ribavirin for subacute sclerosing panencephalitis and monitoring measles virus RNA by quantitative PCR assay
- Hepatic parenchymal transection using ultrasonic coagulating shears : a preliminary report
- In Process Nanocrystalline Control Consolidation of the Amorphous ZrO_2-20mol%Al_2O_3 Powder
- Immunocytochemical demonstration of serotonin (5HT) in the human platelet.
- Taurine-like Immunoreactive Structures in the Mouse Liver
- Immunohistochemical demonstration of 6-HT-containing neurons in the CNS.
- DISTRIBUTION OF NEURONAL CELL BODIES AND AXONS CONTAINING GLICENTIN-LIKE IMMUNOREACTIVITY IN THE RAT BRAIN
- Transient Up-regulation of Myotonic Dystrophy Protein Kinase-binding Protein, MKBP, and HSP27 in the Neonatal Myocardium
- Genetic analysis of the STR system D20S161 in Japanese and Bangladeshi
- Imunohistochemical Demonstration of Fibronectin in Rat Brains Lesioned with 5,6-dihydroxytryptamine (5,6DHT).
- Viral Load in Epstein-Barr Virus-Associated Hemophagocytic Syndrome
- ELECTRON MICROSCOPIC ALTERATIONS IN NORADRENALINE NERVE TERMINALS IN VAS DEFERENS OF THE RAT FOLLOWING CHRONIC ADMINISTRATION OF RESERPINE AND CHLORPROMAZINE
- POSTNATAL ALTERATIONS IN NORADRENALINE NERVE TERMINALS IN THE PERIVENTRICULAR HYPOTHALAMUS OF THE RAT
- Extrapancreatic Proinsulin/Insulin-expressing Cells in Diabetes Mellitus : Is History Repeating Itself?
- High-pressure sintering of the amorphous TiAl powder (特集 各種粉末の焼結機構と新しい焼結技術の展開)
- Association of Cytomegalovirus with Infantile Hepatitis
- The polymorphisms of fucosyltransferases
- A Sensitive Wet-Histofluorescence Method by Glyoxylic Acid for Central Catecholamine Terminals
- A STABLE AND SIMPLE METHOD OF "FAGLUPAGAS FIXATION" FOR CATECHOLAMINES FOR ROUTINE EXAMINATION
- A STABLE AND SIMPLE METHOD OF "FAGLUPAGAS FIXATION" FOR CATECHOLAMINES IN AIM OF ROUTINE EXAMINATION
- Cell transformation from ameboid cells to microglia in the neonatal rats injected fluorescent dye.
- Electron microscopic observation of noradrenergic nerve terminals in the dorsal horn of rat spinal cord (II)
- Divergent Projection of Catecholamine Neuron of Locus Ceruleus as revealed by Fluorescent Retrograde Double Labeling Technique
- Double Labeling Technique of Central Catecholamine Neuron by means of Fluorescent Dyes
- ALTERATION OF DOPAMINE AND TRH IN RAT BRAIN DURING HYPOTHERMIA
- Concurrent Subarachnoid Hemorrhage Due to Ruptured Aneurysm and Hypertensive Intracerebral Hemorrhage : Case Report
- Comparison of the Sauve-Kapandji procedure and the Darrach procedure for the treatment of rheumatoid wrists
- Production of New Type of Antisera to Thyrotropin Releasing Hormone (TRH) Using Carbodiimide Coupling and an Application to Immunohistochemistry
- Unrelated Bone Marrow Transplantation Induced Long-Term Remission in a Patient with Life-Threatening Epstein-Barr Virus-Associated Hemophagocytic Lymphohistiocytosis
- Distinctive distribution of AIM1 polymorphism among major human populations with different skin color
- IMMUNOHISTOCHEMICAL AND BIOCHEMICAL STUDIES OF SUBSTANCES WITH TAURINE-LIKE IMMUNOREACTIVITY IN THE BRAIN
- A New Technique for Immunohistochemistry Using Hybrid IgG. : I. Procedure of Hybrid IgG Production.
- Production of new type antisera to thyrotropin releasing hormone (TRH) using carbodiimide coupling and the application to immunohistochemistry.
- SILVER IMPREGNATION AND FLUORESCENCE HISTOCHEMISTRY OF THE SUBEPENDYMAL CELLS IN THE PREOPTIC RECESS OF THE BULLFROG : Rana Catesbeiana
- Synthesis and Properties of Helical Polyamides Containing Atropisomeric Binaphthyl Units and Crown Ether Rings in the Main Chain
- A fatal case of hyperthermia due to tricyclic antidepressant intoxication
- Myocardial "elektive disseminierte Parenchymnekrose" revisited
- Immunohistochemistry of Serotonin (5-HT) Neurons in the Central Nervus System
- Orthograde transport of horseradish peroxidase (HRP) in central nervous system of young rat.
- Suppression of Ground Radar Interference in JERS-1 SAR Data(Sensing)
- Helicobacter pylori infection in patients with idiopathic short stature
- Vibration spectra and rotational isomerism of chain molecules. VII. 1-Chloro-, 1-bromo-, and 1-iodopropanes, and 1-chloro-, 1-bromo-, and 1-iodobutanes.
- Anodic oxidation of N,N-dimethyl-m-toluidine at a platinum electrode in an acetonitrile solution.
- The crystal and molecular structure of silver (I) N,N-diethyldithiocarbamate.
- The crystal and molecular structure of the copper(I) chloride complex containing p-benzoquinone as a ligand.
- Copper(I) chloride complex containing p-benzoquinone as a ligand.