The crystal and molecular structure of silver (I) N,N-diethyldithiocarbamate.

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structure of silver (I) <I>N</I>,<I>N</I>-diethyldithiocarbamate was determined by the X-ray diffraction method. The crystals are monoclinic, with the space group P2<SUB>1</SUB>/c, and with two hexameric molecules in a unit cell with dimensions of <I>a</I>=10.90±0.02, <I>b</I>=24.72±0.01, <I>c</I>=11.51±0.02 Å, and β=125.8±0.1°. The structure was solved by a heavy-atom method and was refined by block-diagonal least-squares methods to a final <I>R</I>-value of 0.029 for 2108 observed reflections. The structure consists of hexameric molecules, [AgS<SUB>2</SUB>CN(C<SUB>2</SUB>H<SUB>5</SUB>)<SUB>2</SUB>]<SUB>6</SUB>. The hexameric structure was essentially consistent with Hesse's preliminary result (1960). The terminal silver atom in one molecule is bridged by a sulfur atom to that in the adjacent hexamer, forming a chain structure along the a axis. All the silver atoms are connected to five atoms (either 1Ag and 4S or 2Ag and 3S). The dithiocarbamate ligands are classified into three types: bidentate, intra-, and inter-molecule tetradentate.

• 公益社団法人 日本化学会の論文

著者

• Yamaguchi Hiroko

  Department Of Bioresources Chemistry Faculty Of Horticulture Chiba University

• Kido Azuma

  Department Of Organic Synthesis Faculty Of Engineering Kyushu University

• Uechi Tetsuo

  General Education Department of Kyushu University

• Yasukouchi Kazuo

  Department of Industrial Chemistry, Faculty of Engineering, Kumamoto University

関連論文

• Molecular Properties of Mycelial Aggregate-Specific Lectin of Pleurotus cornucopiae(GENETICS, MOLECULAR BIOLOGY, AND GENE ENGINEERING)
• Two Genes Encoding Fruit Body Lectins of Pleurotus cornucopiae : Sequence Similarity with the Lectin of a Nematode-Trapping Fungus(Biochemistry & Molecular Biology)
• Heterotactic Polymerization of Methacrylates Having C-3 Ester Group
• Characterization of Organic Compounds Eluted from Coal under Water Digestion〔含 討論〕
• Vibration spectra and rotational isomerism of chain molecules. VII. 1-Chloro-, 1-bromo-, and 1-iodopropanes, and 1-chloro-, 1-bromo-, and 1-iodobutanes.
• Anodic oxidation of N,N-dimethyl-m-toluidine at a platinum electrode in an acetonitrile solution.
• The crystal and molecular structure of silver (I) N,N-diethyldithiocarbamate.
• The crystal and molecular structure of the copper(I) chloride complex containing p-benzoquinone as a ligand.
• Copper(I) chloride complex containing p-benzoquinone as a ligand.
• A study of the reduction mechanism of p-dimethylaminobenzaldehyde to 1,2-bis(p-dimethylaminophenyl)-1,2-ethanediol by rotating disk electrode voltammetry.

スポンサーリンク