Controlling of Ceramic-Metal Interfacial Structure Using Molten Metals
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This article reviews the dominating factors of wettability of ceramics by molten metals and interface strength of ceramic/metal joint. The role of titanium in copper-titanium alloys during brazing is discussed. The formation of TiN nitride or TiC, Ti_3SiC_2 carbide at the interface and the wetting of Cu-Si alloy against compounds formed during brazing are attributable to the better wettability of Cu-Ti alloy against Si_3N_4 or SiC. The Al-base alloys are also used for joining ceramics to metal. The Al rich alloys with small amount of alloying element shows the superior strength of Si_3N_4/Si_3N_4 joints. The superior wettabilities and mechanical properties of the alloys are attributable to the improvement of strength for ceramic/metal joint. The physical effect of ultrasound is also applied to joining ceramics to metals.
- 大阪大学の論文
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