X-Ray Photoelectron Spectra of Valence Electron in (Cu_xNi_<1-x>)S_2 and ZnS_2(Physics)
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概要
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X-ray photoelectron energy distribution in the valence band has been measured for the system (Cu_xNi_<1-x>)S_2 and for ZnS_2 with the pyrite-type crystal structure. Intensity difference between Cu_<0.25>Ni_<0.75>S_2 and NiS_2 spectra shows three peaks, whose energies correspond to sulphur 3p, cationic t_<2g> and e_g bands. The FWHM of resolved e_g peak is larger than that of t_<2g>. The spectrum of the valence band in ZnS_2 shows a sharp peak of Zn 3d and a broad S 3p band which has three humps on it. These humps are discussed compared with the result of a band calculation.
- 東北大学の論文
著者
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Onodera Hideya
The Research Institute For Iron Steel And Other Metals
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Yamamoto Hisao
The Research Institute For Iron Steel And Other Metals
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Watanabe Hiroshi
The Research Institute For Iron Steel And Other Metals
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