REGIOSELECTIVE OXIDATION OF A β-L-ARABINOPYRANOSIDE VIA CYCLIC TIN INTERMEDIATE. FACILE SYNTHESIS OF 4-AMINO-4-DEOXY-L-ARABINOSE, AN AMINO-SUGAR FOUND IN LIPOPOLYSACCHARIDES OF SOME SALMONELLA R MUTANT STRAINS
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概要
- 論文の詳細を見る
Stannylation of methyl β-L-arabinopyranoside with Bu_2SnO followed by brominolysis afforded methyl β-L-threo-pentopyranos-4-uloside regioselectively, which was characterized as the oxime. Hydrogenation of this gave methyl 4-amino-4-deoxy-β-L-arabinopyranoside which was identified by converting to the known N-acetyl-di-O-mesyl derivative.
- 公益社団法人日本薬学会の論文
- 1983-10-25
著者
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津田 喜典
金沢大学
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吉本 公浩
Faculty of Pharmaceutical Sciences, Kanazawa University
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吉本 公浩
金沢大学薬学部
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花島 万紀子
Faculty of Pharmaceutical Sciences, Kanazawa University
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花島 万紀子
Faculty Of Pharmaceutical Sciences Kanazawa University
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