REGIOSELECTIVE MONO-OXIDATION OF NON-PROTECTED GLYCOSIDES BY THE BIS-TRIBUTYLTIN OXIDE-BROMINE METHOD
スポンサーリンク
概要
- 論文の詳細を見る
Treatment of methyl glycosides with an excess of bis-tributyltin oxide and molecular sieves 3A in chloroform followed by brominolysis resulted in monooxidation to yield oxo-glycosides regioselectively. Thus Me β-D-Glc and Me β-D-Xyl gave the 3-oxo derivatives in more than 90% yield, and Me α-D-Glc, Me α-D-Gal, Me α-D-Xyl, and Me β-L-Ara gave the 4-oxo derivatives in 70-80% yield.
- 公益社団法人日本薬学会の論文
- 1985-09-25
著者
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津田 喜典
金沢大学
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津田 喜典
Faculty of Pharmaceutical Sciences, Kanazawa University
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津田 喜典
金沢大学薬学部
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津田 喜典
Faculty Of Pharmaceutical Sciences Kanazawa University
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松平 直久
Faculty of Pharmaceutical Sciences, Kanazawa University
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金光(吉本) 公浩
Faculty Of Pharmaceutical Sciences Kanazawa University
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松平 直久
Faculty Of Pharmaceutical Sciences Kanazawa University
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