On the Possibility of Direct O-1β→ -6 Acyl Migration in 1-O-Acyl-β-D-glucose Derivatives
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概要
- 論文の詳細を見る
In order to clarify whether or not direct O-1β→ -6 acyl migration in O-acyl-D-glucose derivatives really occurs, 3-O-methyl-1-O-myristoyl-β-D-glucopyranose and 3-deoxy-1-O-myristoyl-β-D-glucopyranose were synthesized and their acyl migration was examined under thermal, solvolytic, and base- and acid-catalyzed conditions. Neither compound showed any tendency for acyl migration under these conditions (only partial solvolysis was observed under solvolytic conditions). Consequently, it was concluded that O-1β→ -6 acyl migration does not occur directly, but proceeds through the path O-1β→ -3→ -6.
- 公益社団法人日本薬学会の論文
- 1983-12-25
著者
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津田 喜典
金沢大学
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津田 喜典
Faculty of Pharmaceutical Sciences, Kanazawa University
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津田 喜典
金沢大学薬学部
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津田 喜典
Faculty Of Pharmaceutical Sciences Kanazawa University
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吉本 公浩
Faculty of Pharmaceutical Sciences, Kanazawa University
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吉本 公浩
金沢大学薬学部
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