Regioselective Mono-oxidation of Non-protected Carbohydrates by Brominolysis of the Tin Intermediates
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概要
- 論文の詳細を見る
Most of the glycosides examined were smoothly oxidized by the bis-tributyltin oxide-bromine method without protection of the other hydroxyl groups to the mono-oxo derivatives in high yield and with high regioselectivity. The regioselectivity (position of oxidation) can be predicted from two independent rules : anomeric control (the oxidation takes place at C-3 for the glycosides which have an equatorial glycosidic linkage and at C-4 for those which have an axial glycosidic linkage) and axial oxidation for cis-1,2 glycols.
- 公益社団法人日本薬学会の論文
- 1989-09-25
著者
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津田 喜典
金沢大学
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津田 喜典
Faculty of Pharmaceutical Sciences, Kanazawa University
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津田 喜典
金沢大学薬学部
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津田 喜典
Faculty Of Pharmaceutical Sciences Kanazawa University
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金光 公浩
Faculty of Pharmaceutical Sciences, Kanazawa University
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奥野 之宏
Faculty of Pharmaceutical Sciences, Kanazawa University
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花島 万紀子
Faculty of Pharmaceutical Sciences, Kanazawa University
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松平 直久
Faculty of Pharmaceutical Sciences, Kanazawa University
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金光 公浩
Faculty Of Pharmaceutical Sciences Kanazawa University
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奥野 之宏
Faculty Of Pharmaceutical Sciences Kanazawa University
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松平 直久
Faculty Of Pharmaceutical Sciences Kanazawa University
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花島 万紀子
Faculty Of Pharmaceutical Sciences Kanazawa University
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