REGIOSELECTIVE INTRODUCTION OF p-COUMAROYL GROUP TO α-L-ARABINO-PYRANOSIDES. TOTAL SYNTHESES OF INUNDOSIDE-G AND INUNDOSIDE-D_1
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概要
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Stannylation of cholesteryl α-L-arabinopyranoside with Bu_2 SnO followed by p-coumaroylation gave the 3'-o-p-coumarate, which on heating in pyridine rearranged to the 4'-o-p-coumarate. Similarly inundoside-A was converted to its 3'-o-p-coumarate and then 4'-o-p-coumarate, which were identical with inundoside-G and inundoside-D_1,respectively, thus providing their total syntheses.
- 公益社団法人日本薬学会の論文
- 1983-04-25
著者
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津田 喜典
金沢大学
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津田 喜典
Faculty of Pharmaceutical Sciences, Kanazawa University
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津田 喜典
Faculty Of Pharmaceutical Sciences Kanazawa University
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Haque Md.ekramul
Faculty Of Pharmaceutical Sciences Kanazawa University
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