SYNTHESIS OF BICYCLO [4. 3. 0] NONENONE AND BICYCLO [3. 3. 0] OCTENONE DERIVATIVES BY INTRAMOLECULAR WADSWORTH-EMMONS REACTION : FORMAL SYNTHESIS OF THE SESQUITERPENE CEDRENE
スポンサーリンク
概要
- 論文の詳細を見る
Annulation by the intramolecular Wadsworth-Emmons reaction for constructing bicyclo [4. 3. 0] nonenone and bicyclo [3. 3. 0] octenone is described. As an application of the reaction, the formal synthesis of the sesquiterpene cedrene was accomplished.
- 社団法人日本薬学会の論文
- 1984-07-25
著者
-
多賀 徹
Faculty of Pharmaceutical Sciences, Kyoto University
-
入江 寛
Faculty of Pharmaceutical Sciences, Nagasaki University
-
入江 寛
長崎大薬
-
入江 寛
長崎大学薬学部
-
入江 寛
Faculty Of Pharmaceutical Sciences Kyoto University
-
冨松 公典
Faculty Of Pharmaceutical Sciences Kyoto University
-
武田 成子
Faculty of Pharmaceutical Sciences, Nagasaki University
-
山村 敦
Faculty of Pharmaceutical Sciences, Nagasaki University
-
水野 行雄
Faculty of Pharmaceutical Sciences, Kyoto University
-
芦澤 一則
Faculty of Pharmaceutical Sciences, Kyoto University
-
多賀 徹
Faculty Of Pharmaceutical Sciences Kyoto University
-
山村 敦
Faculty Of Pharmaceutical Sciences Nagasaki University
-
水野 行雄
Faculty Of Pharmaceutical Sciences Kyoto University
-
武田 成子
Faculty Of Pharmaceutical Sciences Nagasaki University
-
芦澤 一則
Faculty Of Pharmaceutical Sciences Kyoto University
関連論文
- Reaction of 8,8-DibromobicycJo[5.1.0]octanes with Higher-Order Organocuprates(Organic,Chemical)
- 34 糸状菌胞子の発芽を自己制御する化学因子に関する研究(口頭発表の部)
- Novel Flavonoids from Chrysosplemium grayanum MAXIM. (Saxifragaseae)
- Antiviral Agents of Plant Origin.III. : Scopadulin, a Novel Tetracyclic Diterpene from Scoparia dulcis L.
- Synthesis of a Germination Self-Inhibitor, (-)-Gloeosporone, and Related Compounds and Evaluation of Their Activities
- Synthesis of Amaryllidaceae Alkaloids, (±)-Cherylline and (±)-Latifine
- 69(P48) ビリジオファンジンAの合成と絶対構造の決定(ポスター発表の部)
- 117(P58) 海洋天然物(-)-オクタラクチンAの合成(ポスター発表の部)
- 13 エポキシアルコールへの立体および位置選択的アミノ基導入の新手法 : α-置換セリン構造を持つ天然物の合成(口頭発表の部)
- Studies on Peptides. LXXIX. : By-Products derived from N^α-Protected Tryptophan by Acids
- Studies on Peptides. LXXIII. Examination of the Methanesulphonic Acid Procedure for the Synthesis of Peptides containing Methionine
- 第2回薬物の分子設計と開発に関する日豪合同シンポジウム
- エンバク冠さび菌夏胞子の自己発芽抑制物質の合成アナログの特異的活性
- 43 ジョロウグモ(Nephila clavata)の神経毒Nephilatoxin類の合成研究II : 合成とその活性(口頭発表の部)
- Studies on the Structure-Toxicity Relationship of AK-Toxin, a Host-Specific Toxin to Japanese White Pear, Produced by Alternaria kikuchiana : Synthesis of Methyl (4S, 5R)-4-(N-Acetylphenylalanyl)oxy-5,6-epoxy-5-methylhex-2(E)-enoate and Its Stereoisomers
- 85 Aspergillus niger NH-401株の生産する新規抗菌性物質antafumicin AとBの構造と合成(ポスター発表の部)
- 13 新規鎖状立体制御法を基盤としたポリプロピオネート系抗生物質の合成研究(口頭発表の部)
- Synthesis of 5,6,7,8-Tetrahydroquinolines by Thermolysis of Oxime O-Allyl Ethers in the Presence of Boron Trifluoride Etherate
- Synthesis of the Simple Macrolides, Patulolide A and Patulolide C
- Cyclopentenone Annulation of 1,4-Diketones with Potassium Phosphate Tribasic : A Synthesis of a Monoterpene Alkaloid, (±)-Tecomanine
- A Synthesis of (-)-Bursatellin
- 植物と植物病原菌の生活環に係わる二, 三の物質
- Synthesis of Methyl Esters of AF-Toxin IIa and IIc, Toxins to Japanese White Pear Produced by Alternaria alternata Strawberry Pathotype
- 35 γ,δ-エポキシアクリル酸エステルを合成ブロックとするポリプロピオネートの新規鎖状立体制御法とその天然物合成への応用(ポスター発表の部)
- Synthesis of (-)-Patchoulipyridine and Related Compounds
- Synthesis of (±)-Heritol, a Sesquiterpene Lactone belonging to the Aromatic Cadinane Group
- Synthesis of the Methyl Ester of AK-Toxin II, a Host-Specific Toxin to Japanese white Pear, and Its Congeners : : Structure-Toxicity Relationship of the Toxin
- (105) AK-toxin II の合成と類縁体の生理活性 (昭和62年度日本植物病理学会大会講演要旨)
- TOTAL SYNTHESIS OP ESTERS OP AK-TOXIN II AND AF-TOXIN IIC STARTING FROM VITAMIN C AS A CHIRAL MATERIAL(Communications to the Editor)
- SYNTHESIS OF THE HOST-SPECIFIC TOXINS AF-TOXIN II_C AND AK-TOXIN CONGENERS AND THEIR STEREOSTRUCTURE-TOXICITY RELATIONSHIP
- ^1H-Nuclear Magnetic Resonance Studies on Interaction between 4-[4-(N, N-Dimethylcarbamoylme- thoxycarbonymethyl)phenoxycarbonylphenyl]guanidinium Methanesulfonate and Trypsin
- Structure and Synthesis of Acid A, an Oxidation Product of Lycoramine
- Quinones and Related Compounds in Higher Plants. XIII. Absolute Structure of 2-Carboxy-2-prenyl-4-oxo-1-tetralone, a Key Intermediate in the Biosynthesis of Naphthoquinone Congeners of Catalpa ovata
- SYNTHESIS OF BICYCLO [4. 3. 0] NONENONE AND BICYCLO [3. 3. 0] OCTENONE DERIVATIVES BY INTRAMOLECULAR WADSWORTH-EMMONS REACTION : FORMAL SYNTHESIS OF THE SESQUITERPENE CEDRENE
- 13 Onychine関連化合物の合成と、Indan-1-one Oxime類のNMRによる構造決定(ポスター発表の部)
- Synthesis of Methoxyonychine and Use of ^1H- and ^C-Nuclear Magnetic Resonance Spectra for Structure Determination of Geometrical Isomers of Indan-1-one Oxime Derivatives
- STEREOSPECIFIC SYNTHESIS OF NOVEL 1,3-THIAZOLIDIN-2-YL ANALOGUES OF PSEUDOURIDINE
- THE STRUCTURES OF FOUR NEW DITERPENE ALKALOIDS, SPIRAMINES A, B, C, AND D(Communications to the Editor)
- Thermolysis of Oxime O-Allyl Ethers : A New Method for Pyridine Synthesis
- Multiple Binding of Inhibitors in the Complex Formed by Bovine Trypsin and Fragments of a Synthetic Inhibitor, 4-[4-(N, N-Dimethylcarbamoylmethoxycarbonylmethyl)phenoxycarbonylphenyl]guanidinium Methanesulfonate (FOY-305)
- Synthesis of the Alkaloid, Xylopinine and the Related Compound by Photo-induced Rearrangement of Spiroisoquinoline
- STEPHADIAMINE, A NEW SKELETAL ALKALOID FROM STEPHANIA JAPONICA : THE FIRST EXAMPLE OF A C-NORHASUBANAN ALKALOID
- 5 (±)-Lycoramineの全合成
- Alkaloids of the Amaryllidaceae. A New Alkaloid, Sanguinine, from Lycoris sanguinea MAXIM. var. Kiushiana MAKINO, and Pretazettine from Lycoris radiata HERB.
- ビスデヒドロジヒドロエンメインの熱分解物の合成 : 第1報 6-Hydroxy-7-methylphthalideおよび2-Hydroxymethyl-6,6-dimethyl-5-oxo-1-cyclohexenecarboxylic Acid Lactoneの合成
- エンメインの構造に関する化学的研究
- Triterpenoids from the Fruits of Phellodendron chinense SCHNEID. : : The Stereostructure of Niloticin
- An Improved Synthesis of N-(Butylaminocarbonyl)-4-hydroxymethyl-benzenesulfonamide, One of the Metabolites of Tolbutamide, and Synthesis of Its Formyl Derivative
- ジヒドロリコリンの合成
- Fumariline型塩基のマススペクトルについて(第1報)C環上のアルコオキシ基の位置とそのマススペクトルの関係および中間体法を用いた開裂機構
- 1,2,3,6-Tetrahydro-6-(3,4-dimethoxyphenyl)-phthalic Acidおよび関連化合物のFriedel-Crafts反応について
- Dimethoxyindanone類のマススペクトルについて
- Isolation and Characterization of 10,11-Dihydroatlantone and Related Compounds from Ginkgo biloba L.
- 36 (±)-Clivonineおよび(±)-Clividineの合成研究
- X-Ray Crystallographic Determination of the Structure of the Alkaloid Protostemonine
- シラネアオイの根茎の成分研究(第2報) : Glaupalolの全合成
- 22 Dihydrolycorineの合成
- ハマウド根の成分 : その6 Hamaudolの絶対配置について
- 31 (±)-Ochotensine及び類似化合物の全合成
- ハマウド根の成分 その5 : 5,7-Dimethoxy-3-hydroxy-2,2-dimethyl-chromanのJones酸化反応成績体について
- シラネアオイの根茎の成分研究(第1報) : Glaupalolの構造について
- イチョウ心材成分の研究(第5報) : Bilobanoneの構造と絶対配置について
- The Structure of Stenine, a New Alkaloid Occurring in Stemona Tuberosa
- The structure of the Rearrangement Product obtained by a Prevost-Woodward Reaction on 14-Hydroxydeoxydihydrocodeine Methine
- A Synthesis of Tetrahydrooxocrinine Methine
- Studies on the Heterocyclic Compounds. XXI. A New Alkylation of Pyridazines with Nitromethane and Nitroethane
- Studies on the Heterocyclic Compounds. XX. The Reaction of 4-Cyano-3,6-dichloropyridazine with Amines
- Studies on the Heterocyclic Compounds. XIX. A Novel Ring Isomerization of 3-Ylideneaminoimidazo [4,5-c] pyridazines
- 複素環化合物の研究(第18報)Imidazo[1,2-c]-およびPyrimido[1,2-c]pyrimidine誘導体の合成
- Studies on the Pyridazine Derivatives. XVII. Structural Studies on the Product of 3-Hydrazino-4-aminopyridazine with Formic Acid (A Novel Ring Isomerization)
- Studies on the Pyridazine Derivatives. XVI. Reaction of 3-Alkoxy-4-nitro-(and 4,6-dinitro) pyridazine 1-Oxides with Amines
- Studies on the Synthesis of Pyridazine Derivatives. XIII. Synthesis of Imidazo-[4,5-d]- and v-Triazolo[4,5-d]pyridazine Derivatives and Reaction of 4-Alkoxy-v-triazolo[4,5-d]pyridazines with Various Amines
- Studies on the Synthesis of Pyridazine Derivatives. XII. Synthesis of 4,5-Diaminopyridazine Derivatives
- Studies on the Synthesis of Pyridazine Derivatives. IX. Synthesis of 10H-Pyridazino (3,2-b) quinazolin-10-one and Its Derivatives. (3)
- Studies on Peptides. LXXIV. Convenient Procedure for the Preparation of Methionine Sulphoxide Derivatives
- AN APPROACH TO A SYNTHESIS OF THE HOST-SPECIFIC TOXINS AK-TOXIN I AND II, STARTING FROM VITAMIN C AS A CHIRAL MATERIAL
- 19 エンバクの冠さび病抵抗性に関与する化学物質
- 2 エンバク冠さび病感染組織より単離されたファイトアレキシンの化学生物学的研究
- New Synthetic Routes to (±)-Perhydrohistrionicotoxin. Stereoselective Synthesis of (6S^*, 7S^*, 8S^*)-7-Butyl-8-hydroxy-1-azaspiro [5.5]-undecan-2-one and Its (6R^*)-Isomer
- Separation and Identification of Amine-Carbohydrate Reaction Product in Aqueous Solution(Pharmaceutical)
- DETHIO-TETRA (METHYLTHIO) CHETOMIN, A NEW ANTIMICROBIAL METABOLITE OF CHAETOMIUM GLOBOSUM KINZE EX FR. STRUCTURE AND PARTIAL SYNTHESIS FROM CHETOMIN
- Stereo-Structures of Reaction Products of dl-1,3-Dimethylthymine Epoxide with Amines and L-Amino Acid Ethyl Esters(Organic,Chemical)
- Oxidation of Pyrimidine Base Derivatives with m-Chloroperbenzoic Acid
- Structure Redetermination and Packing Analysis of Aspirin Crystal
- OXIDATION OF 1,3-DIMETHYL DERIVATIVES OF PYRIMIDINE BASES WITH m-CHLOROPERBENZOIC ACID
- 29 4-Methylene-cyclohex-Z-enoneをMichael acceptorとする環化反応を用いた2,3のセスキテルペンの合成研究
- (73) アベナルミンおよび前駆物質フェニールプロパノイド化合物の抗菌性 (昭和57年度日本植物病理学会大会講演要旨)
- 協同研究への志向(薬学第二世紀の出発点に立って)
- Studies on Peptides. XCVI. Behavior of S-Acetamidomethylcysteine Sulfoxide under Deprotecting Conditions in Peptide Synthesis
- Studies on Peptides. LXXXIII. Behavior of S-Substituted Cysteine Sulfoxides under Deprotecting Conditions in Peptide Synthesis
- (67) エンバクのファイトアレキシン "アベナルミン(Avenalumin) I"の化学構造 (昭和54年度 日本植物病理学会大会講演要旨)
- Behaviour of S-Substituted Cysteine Sulfoxide under Acidolytical Deprotecting Conditions
- Studies on Peptides. L. Acidolysis of Protecting Groups in Peptide Chemistry by Fluorosulphonic Acid and Methanesulphonic Acid
- Tazettine Chemistry. IX. Isomeric Lactones Derived from 1-(2-Hydroxymethyl-4,5-methyl-enedioxyphenyl)-4-hydroxycyclohexanecarboxylic Acid.
- Synthesis of Alkaloids, (±)-Xylopinine and (±)-Tetrahydropalmatine, by a Photo-Induced Rearrangement of Spirobenzylisoquinolines in the Presence of Vitamin C