Quinones and Related Compounds in Higher Plants. XIII. Absolute Structure of 2-Carboxy-2-prenyl-4-oxo-1-tetralone, a Key Intermediate in the Biosynthesis of Naphthoquinone Congeners of Catalpa ovata
スポンサーリンク
概要
- 論文の詳細を見る
The absolute configuration at C-2 of 2-carboxy-2-prenyl-4-oxo-1-tetralone (2), a key intermediate in the biosynthesis of prenylnaphthoquinone congeners of the wood and callus tissues of Catalpa ovata, was verified to be S by X-ray crystallographic analysis of the p-bromobenzoate (8) derived from 2.
- 社団法人日本薬学会の論文
- 1981-02-25
著者
-
多賀 徹
Faculty of Pharmaceutical Sciences, Kyoto University
-
井上 博之
Faculty Of Pharmaceutical Sciences Kyoto University
-
井上 博之
京都大学薬学部
-
井上 謙一郎
Faculty Of Pharmaceutical Sciences Kyoto University:(present Address)gifu Pharmaceutical University
-
塩原 義則
Faculty Of Pharmaceutical Sciences Kyoto University
-
大川 滋紀
Faculty of Pharmaceutical Sciences, Kyoto University
-
吉田 和代
Faculty of Pharmaceutical Sciences, Kyoto University
-
大崎 建次
Faculty of Pharmaceutical Sciences, Kyoto University
-
吉田 和代
Faculty Of Pharmaceutical Sciences Kyoto University
-
大川 滋紀
Chemistry Research Laboratories
-
多賀 徹
Faculty Of Pharmaceutical Sciences Kyoto University
-
大崎 健次
Faculty of Pharmaceutial Sciences, Kyoto University
関連論文
- Reaction of 8,8-DibromobicycJo[5.1.0]octanes with Higher-Order Organocuprates(Organic,Chemical)
- Novel Flavonoids from Chrysosplemium grayanum MAXIM. (Saxifragaseae)
- Antiviral Agents of Plant Origin.III. : Scopadulin, a Novel Tetracyclic Diterpene from Scoparia dulcis L.
- 天然着色料クチナシ青色素の分子量及び消化管内における安定性と吸収
- 2 アジサイ(Hydrangea)属植物の新型セコイリドイド配糖体について
- Uber die Monoterpenglucoside und verwandte Naturstoffe. XXI. Zur Stereochemie des Morronisids und seiner Derivate
- Studies on Monoterpene Glucosides and Related Natural Products. LV. Iridane Skeleton Formation from Acyclic Monoterpenes in the Biosynthesis of Iridoid Glucosides in Gardenia jasminoides f. grandiflora Cell Suspension Cultures
- MECHANISM OF IRIDANE SKELETON FORMATION IN THE BIOSYNTHESIS OF IRIDOID GLUOOSIDES IN GARDENIA JASMINOIDES CELL CULTURES
- 29 Streptocarpus dunnii細胞培養におけるキノン類の生合成
- STRUCTURES OF UNUSUALLY PRENYLATED NAPHTHOQUINONES OF STREPTOCARPUS DUNNII AND ITS CELL CULTURES
- 49 イリドイド配糖体の生合成におけるイリダン骨格形成機構について
- 45 プレニルナフトキノン類縁体および関連アントラキノン類の生合成研究
- Studies on Monoterpene Glucosides and Related Natural Products. XXXVII. Biosynthesis of the Iridoid Glucosides in Lamium amplexicaule, Deutzia crenata and Galium spurium var. echinospermon
- 47 クチナシカルス培養細胞によるイリドイド配糖体の生合成研究
- 15 キササゲ(Catalpa ovata)培養組織におけるprenylnaphthoquinone類縁体の産生と生合成
- Uber die Chinone und verwandte Stoffe in hoheren Pflanzen. IV. Zur Biosynthese von Catalpalacton und Catalponol im Holz der Catalpa ovata
- 2 GeraniolからIridoid配糖体への閉環機構
- 30 高等植物におけるプレニルナフトキノン類の生合成研究
- Studies on Monoterpene Glucosides and Related Natural Products. XXIII. Biosynthesis of the Secoiridoid Glucosides, Gentiopicroside, Morroniside, Oleuropein, and Jasminin
- 49 キササゲのcatalpalactoneおよび類縁物貭の生合成研究
- Studies on Monoterpene Glucosides and Related Natural Products. XVIII. Formation Sequences of Iridoid Glucosides in highly Oxidized Levels
- Studies on Monoterpene Glucosides and Related Natural Products. XVII. The Intermediacy of 7-Desoxyloganic Acid and Loganin in the Biosynthesis of Several Iridoid Glucosides
- アケボノソウSwertia bimaculataのXanthone類について
- Studies on Monoterpene Glucosides and Related Natural Products. XIII. Incorporation of [10-^C]-Sweroside into Gentiopicroside and the Alkaloids in Vinca and Cincona Plants
- Studies on Monoterpene Glucosides. XII. Biosynthesis of Gentianaceous Secoiridoid Glucosides
- 42 イリドイド配糖体の酸化順序とloganinのセコイリドイド配糖体への環開裂の機構
- Studies on Monoterpene Glucosides and Related Natural Products. XLVII. Synthesis of ^3H-and ^2H-labeled Iridodial Derivatives for Studies on the Biosynthesis of Iridoid Glucosides
- Studies on Monoterpene Glucosides and Related Natural Products. XLV. Synthesis of ^C-Labeled Acyclic Monoterpenes for Studies on the Mechanism of the Iridane Skeleton Formation in the Biosynthesis of Iridoid Glucosides
- ^1H-Nuclear Magnetic Resonance Studies on Interaction between 4-[4-(N, N-Dimethylcarbamoylme- thoxycarbonymethyl)phenoxycarbonylphenyl]guanidinium Methanesulfonate and Trypsin
- 連続ストレス負荷マウスの性行動及び学習行動に対するイリドイドの影響
- モノテルペン配糖体及び関連天然物の研究(第52報)セコイリドイド配糖体, インドールアルカロイドの生合成において鎖状テルペンよりイリダン骨格が形成される機構について
- INTERMEDIACY OF 10-HYDROXYGERANIOL, 10-HYDROXYNEROL AND IRIDODIAL IN THE BIOSYNTHESIS OF AJMALINE AND VOMILENINE IN RAUWOLFIA SERPENTINA SUSPENSION CULTURES
- MECHANISM FOR IRIDANE SKELETON FORMATION FROM ACYCLIC MONOTERPENES IN THE BIOSYNTHESIS OF SECOLOGANIN AND VINDOLINE IN CATHARANTHUS ROSEUS AND LONICERA MORROWII
- Studies on Monoterpene Glucosides and Related Natural Products. XXXIII. Structure of Bakankosin
- Quinones and Related Compounds in Higher Plants. III. Absolute Structure of Catalponol, a Naphthoquinone Congener of Catalpa ovata
- ホウロクタケTrametes dickinsii BERK.のトリテルペン成分の研究(第2報) Carboxyacetylquercinic Acidの絶対構造^
- ホウロクタケTrametes dickinsii BERK.のトリテルベン成分の研究(第1報) : 数種のトリテルベンの単離とTrametosideの構造
- モノテルペン配糖体および関連天然物の研究(第16報) : リンドウ科, 特にリンドウ属, センブリ属植物におけるセコイリドイド配糖体の分布
- Studies on Monoterpene Glucosides and Related Natural Products. XV. Confirmation of the Absolute Configuration of Catalpol
- Uber die Monoterpenglucoside. XI. Chemische Korrelation des Asperulosids mit Swerosid
- Studies on the Blue Pigments Produced from Genipin and Methylamine. II .On the Formation Mechanisms of Brownish-Red Intermediates Leading to the Blue Pigment Formation
- Studies on the Blue Pigments Produced from Genipin and Methylamine. I. Structures of the Brownish-Red Pigments, Intermediates Leading to the Blue Pigments
- イムノアッセイ法による植物成分の微量定量法に関する研究(第1報) : アトロピンの4種のハプテンの合成とそれらのラジオイムノアッセイへの応用^
- Quinones and Related Compounds in Higher Plants. XXI. New Findings on the Proton and Carbon-13 Nuclear Magnetic Resonance Spectra of Shikonin
- 75 Genipinとアミノ酸より生成するPseudoazulene骨格をもつ青色々素の構造に関する研究
- プレニルナフトキノンおよび類縁アントラキノンの生合成
- Quinones and Related Compounds in Higher Plants. XIII. Absolute Structure of 2-Carboxy-2-prenyl-4-oxo-1-tetralone, a Key Intermediate in the Biosynthesis of Naphthoquinone Congeners of Catalpa ovata
- Quinones and Related Compounds in Higher Plants. IX. Absolute Structures of Catalponol and Its Congeners
- Studies on Monoterpene Glucosides and Related Natural Products. XXXIX. Biogenetic-type Transformation of Geniposide into Plumieride
- Studies on Quinones and Related Compounds in Higher Plants. V. Model Experiments for the Preparation of Tritium-labeled Precursors for the Biosynthetic Studies of Prenylnaphthoquinone Congeners
- SYNTHESIS OF BICYCLO [4. 3. 0] NONENONE AND BICYCLO [3. 3. 0] OCTENONE DERIVATIVES BY INTRAMOLECULAR WADSWORTH-EMMONS REACTION : FORMAL SYNTHESIS OF THE SESQUITERPENE CEDRENE
- モノテルペン配糖体及び関連物質に関する研究(第65報)Amarogentin及びAmaroswerinのBiphenylcarboxylic Acid部分の生合成
- 42 数種のモクセイ科植物のセコイリドイド配糖体の構造と生合成(口頭発表の部)
- Studies on Monoterpene Glucosides and Related Natural Products. XXXIV. Two Further New Glucosides from the Fruit of Gardenia jasminoides ELLIS forma grandiflora (LOUR.) MAKINO
- Studies on Monoterpene Glucosides and Related Natural Products. XXXII. Iridoid Glucosides of Tarenna kotoensis var. gyokushinka
- モノテルペン配糖体および関連天然物の研究(第25報)クチナシGardenia jasminoides ELLIS forma grandiflora [LOUR.]MAKINOのイリドイド配糖体について その1
- クロキSymplocos lucidaのLignan配糖体について
- Synthesis of Methoxyonychine and Use of ^1H- and ^C-Nuclear Magnetic Resonance Spectra for Structure Determination of Geometrical Isomers of Indan-1-one Oxime Derivatives
- A New Iridoid Glucoside, Nepetariaside, from Nepeta cataria(Organic,Chemical)
- STEREOSPECIFIC SYNTHESIS OF NOVEL 1,3-THIAZOLIDIN-2-YL ANALOGUES OF PSEUDOURIDINE
- THE STRUCTURES OF FOUR NEW DITERPENE ALKALOIDS, SPIRAMINES A, B, C, AND D(Communications to the Editor)
- SAMBACOLIGNOSIDE, A NEW LIGNAN-SECOIRIDOID GLUCOSIDE FROM JASMINUM SAMBAC(Communications to the Editor)
- Studies on Monoterpene Glucosides and Related Natural Products. XLII. On the Possibility of the Intermediacy of 10-Hydroxyloganin in the Biosynthesis of Secologanin
- Studies on Monoterpene Glucosides and Related Natural Products. XLI. Chemical Conversion of Geniposide into 10-Hydroxyloganin
- 高等植物のキノンおよび関連物質の研究(第7報)キササゲの材の成分研究補遺
- Multiple Binding of Inhibitors in the Complex Formed by Bovine Trypsin and Fragments of a Synthetic Inhibitor, 4-[4-(N, N-Dimethylcarbamoylmethoxycarbonylmethyl)phenoxycarbonylphenyl]guanidinium Methanesulfonate (FOY-305)
- STEPHADIAMINE, A NEW SKELETAL ALKALOID FROM STEPHANIA JAPONICA : THE FIRST EXAMPLE OF A C-NORHASUBANAN ALKALOID
- NEW SECOIRIDOID GLUCOSIDES, HYDRANGENOSIDES E, F AND G FROM HYDRANGEA SCANDENS
- Novel Type Secoiridoid Glucosides, Hydrangenosides B, C and D from Hydrangea macrophylla
- Triterpenoids from the Fruits of Phellodendron chinense SCHNEID. : : The Stereostructure of Niloticin
- Application of High Performance Liquid Chromatography and Field Desorption Mass Spectroscopy to Separative Analysis of Bitter Secoiridoid Glucosides of Swertiae Herba
- X-Ray Crystallographic Determination of the Structure of the Alkaloid Protostemonine
- Studies on Monoterpene Glucosides. VIII. Artefacts formed during Extraction of Asperuloside and Paederoside
- Studies on Monoterpene Glucosides. VII. Iridoid Glucosides of Paederia scandens
- Physical Properties of Pyrimidine and Purine Antimetabolites. II. Permeation of 5-Fluorouracil and 1-(2-Tetrahydrofuryl)-5-fluorouracil through Cellophane, Collagen, and Silicone Membranes
- Monotropeinおよび関連化合物の構造
- New Synthetic Routes to (±)-Perhydrohistrionicotoxin. Stereoselective Synthesis of (6S^*, 7S^*, 8S^*)-7-Butyl-8-hydroxy-1-azaspiro [5.5]-undecan-2-one and Its (6R^*)-Isomer
- Separation and Identification of Amine-Carbohydrate Reaction Product in Aqueous Solution(Pharmaceutical)
- DETHIO-TETRA (METHYLTHIO) CHETOMIN, A NEW ANTIMICROBIAL METABOLITE OF CHAETOMIUM GLOBOSUM KINZE EX FR. STRUCTURE AND PARTIAL SYNTHESIS FROM CHETOMIN
- Stereo-Structures of Reaction Products of dl-1,3-Dimethylthymine Epoxide with Amines and L-Amino Acid Ethyl Esters(Organic,Chemical)
- Oxidation of Pyrimidine Base Derivatives with m-Chloroperbenzoic Acid
- Structure Redetermination and Packing Analysis of Aspirin Crystal
- OXIDATION OF 1,3-DIMETHYL DERIVATIVES OF PYRIMIDINE BASES WITH m-CHLOROPERBENZOIC ACID
- Uber die Monoterpenglucoside. X. Secoiridoid-Glucoside aus Swertia japonica. Isolierung von funf Secoiridoid-Glucosiden sowie die Strukturaufklarung des Swerosids, des Swertiamarins und des Gentiopicrosids
- Uber die Monoterpenglucoside. VI. Zur Stereochemie des Monotropeins
- 8 リンドウ科植物苦味配糖体の構造研究
- ポリアミドクロマトグラフィーの研究(第2報) : 数種のフェノール性物質分離へのポリアミドカラムクロマトグラフィーの応用
- ポリアミドクロマトグラフィーの研究(第1報) : ポリアミドによる薄層クロマトグラフィー
- せんぶりSwertia japonica MAKINOより得られる人工塩基について
- モノテルペン配糖体の研究(第4報) : ユズリハDaphniphyllum macropodum MIQ.のモノテルペン配糖体
- Uber die Monoterpenglucoside. II. Zur Stereochemie des Bisdesoxydihydromonotropeins, eines Hydrierungsproduktes des Monotropeins und des Asperulosids.
- Uber die Bestandteile der Pyrolazeen. XIV. Uber die Struktur des Monotropeins
- Uber die Monoterpenglucoside. III. Die Stereochemische Beziehung zwischen Monotropein, Asperulosid und Aucubin und die Absolute Konfiguration des Letzteren
- Quinones and Related Compounds in Higher Plants. II. On the Naphthoquinones and Related Compounds from Catalpa Wood
- Structure of Catalpalactone, a New Phthalide from Catalpa Wood
- Uber die Monoterpenglucoside und verwandte Naturstoffe. XX. Uber die Struktur des Forsythids, eines neuen Iridoidglucosides aus Forsythia viridissima
- Uber die Gibbs'sche Farbreaktion. I.
- Uber die Bestandteile der Pirolaceae-Pflanzen. X. Die Konstitution des Pirolatins. (5). Synthese des Tetrahydropirolagenins.
- Studies on Monoterpene Glucosides and Related Natural Products. XXX. The Fate of the C-8 Proton of 7-Deoxyloganic Acid in the Biosynthesis of Secoiridoid Glucosides
- 生薬および関連植物の抗コクシジウム活性成分の探索(I) : アジサイからのcisならびにtrans-febrifugineの単離および抗コクシジウム活性について