Studies on Monoterpene Glucosides and Related Natural Products. XXXIX. Biogenetic-type Transformation of Geniposide into Plumieride
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概要
- 論文の詳細を見る
A biogenetic-type transformation of geniposide (9) into plumieride (1) was carried out. The tetraacetyl-geniposide (12) prepared from geniposide (9) via 10-dehydrogeniposide (10) was subjected to sensitized photooxygenation to give tetraacetyl-gardenoside (13). Oxidation of the allylic hydroxy group of 13,followed by condensation of the resulting aldehyde (23) with ethyl acetoacetate afforded tetraacetyl-13-dehydroplumieride (24). This compound (24), on reduction followed by acetylation, gave a pair of epimers, 28 and 29,of which the major one (28) was deacetylated to give plumieride (1).
- 社団法人日本薬学会の論文
- 1979-12-25
著者
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西村 洋
Faculty Of Pharmaceutical Sciences Kyoto University
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井上 博之
Faculty Of Pharmaceutical Sciences Kyoto University
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井上 博之
京都大学薬学部
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武田 美雄
Faculty of Integrated Arts and Sciences, University of Tokushima
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井上 謙一郎
Faculty Of Pharmaceutical Sciences Kyoto University:(present Address)gifu Pharmaceutical University
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武田 美雄
Faculty Of Integrated Arts And Sciences The University Of Tokushima
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