Synthesis of Alkaloids, (±)-Xylopinine and (±)-Tetrahydropalmatine, by a Photo-Induced Rearrangement of Spirobenzylisoquinolines in the Presence of Vitamin C
スポンサーリンク
概要
- 論文の詳細を見る
The presence of vitamin C during the photo-induced rearrangement reaction of spirobenzylisoquinolines in ethanol suppressed the formation of the oxidation product, improving the yield of the berbinium compound, which yields the tetrahydroprotoberberine type compound on reduction with sodium borohydride. Synthesis of two alkaloids, (±)-xylopinine and (±)-tetrahydropalmatine, was accomplished by this method in fair yield.
- 公益社団法人日本薬学会の論文
- 1986-09-25
著者
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入江 寛
長崎大薬
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入江 寛
長崎大学薬学部
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入江 寛
Faculty Of Pharmaceutical Sciences Kyoto University
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武田 成子
Faculty of Pharmaceutical Sciences, Nagasaki University
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武田 成子
Faculty Of Pharmaceutical Sciences Nagasaki University
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竹下 和男
Faculty Of Pharmaceutical Sciences Nagasaki University
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