2,3-Methylenedioxynaphthalene の合成

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概要

• 論文の詳細を見る

• 2,3-Methylenedioxynaphthalene (VIII), mp 97-99°, which was first isolated from Cinnamomum camphora SIEB., was synthesized from piperonal (I) via seven steps. In the course of this study, reduction of V to VI was successfully achieved by PdCl_2-NaBH_4 without affecting the carboxyl group. All spectra data (ultraviolet, infrared, mass) of synthesized VIII were almost identical with those of natural product and its nuclear magnetic resonance spectrum also agreed with the structure of VIII. As a result, the structure of natural VIII was synthetically confirmed.

• 公益社団法人日本薬学会の論文
• 1975-04-25

著者

• 沼田 敦

  大阪薬大

• 有本 正生

  大阪薬大

• 有本 正生

  大阪薬科大学

• 沼田 敦

  大阪薬科大学

• 山口 秀夫

  大阪薬科大学

• 円井 敏恵

  大阪薬科大学

• 武田 裕子

  大阪薬科大学

• 有本 正生

  Osaka University Of Pharmaceutical Sciences

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