Juvabione Analogs from Abies sachalinensis (FR. SCHM.) MAST. II
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概要
- 論文の詳細を見る
Two new juvabione analogs (4 and 5) were isolated, together with (+)-epijuvabione and (+)-dehydroepijuvabione, from the wood of Abies sachalinensis (FR. SCHM.) MAST. (Pinaceae) grown in the southern base of the Taisetsu mountain range of Hokkaido, Japan. The structures of 4 and 5 were respectively established to be methyl 4(S)-[1(S), 5-dimethyl-3-oxohexyl]-3-oxo-1-cyclohexene-1-carboxylate and methyl 4(R)-[1(S), 5-dimethyl-3-oxohexyl]-3-oxo-1-cyclohexene-1-carboxylate on the basis of chemical and spectral evidence. Juvabione-type compounds had been isolated from the wood of this species, whereas this time the epijuvabione-type compounds alone were obtained. This evidence suggests the existence of a tree-to-tree variation in constituents of the A. sachalinensis wood.
- 社団法人日本薬学会の論文
- 1990-09-25
著者
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沼田 敦
大阪薬大
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沼田 敦
Osaka University of Pharmaceutical Sciences
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河合 健蔵
大阪薬大
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高橋 千佳
大阪薬大
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河合 健蔵
Osaka University of Pharmaceutical Sciences
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高橋 千佳
Osaka University of Pharmaceutical Sciences
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沼田 敦
Osaka College Of Pharmacy
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