ビスデヒドロジヒドロエンメインの熱分解物の合成(第2報) : (一)-6-Methyl-7-oxobicyclo [3.2.1] octaneの合成

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概要

• 論文の詳細を見る

• For the purpose of establishing the absolute configuration of enmein (I) by chemical means, (-)-6-methyl-7-oxobicyclo [3. 2. 1] octane (VIII) was prepared by a sequence of reactions shown in Chart 3 and 5. The synthesized compound was found to be an enantiomer of the compound (XXXIII) obtained by pyrolysis of disdehydrodihydroenmein. Since the absolute configuration of VIII is deduced from that of the intermediate (XXIIIb), the absolute configuration of the pyrolysis product (XXXIII) has been clarified. The result thus obtained is in agreement with the absolute configuration of enmein proposed in in the previous paper.

• 公益社団法人日本薬学会の論文
• 1968-10-25

著者

• 鈴木 隆

  大日本製薬株式会社中央研究所

• 上尾 庄次郎

  京都大学薬学部

• 沼田 敦

  Osaka College Of Pharmacy

• 沼田 敦

  京都大学薬学部

• 鈴木 隆

  京都大学薬学部

• 大野 孝正

  京都大学薬学部

• 大野 孝正

  Faculty of Pharmaceutical Sciences Kyoto University

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• ビスデヒドロジヒドロエンメインの熱分解物の合成(第2報) : (一)-6-Methyl-7-oxobicyclo [3.2.1] octaneの合成
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