Photochemical Syntheses of 2-Heterobicyclo-[3.2.0] heptane and-[4.2.0] octane Ring Systems

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概要

• 論文の詳細を見る

• Irradiation of 3-(3-butenyloxy)- and 3-(4-pentenyloxy)-5,5-dimethyl-2-cyclohexen-1-ones resulted in an intramolecular cycloaddition to give the corresponding 2-oxabicyclo-[n.2.0] alkanes rather than the 2-oxabicyclo [n.1.1] alkanes. Similarly 3-(N-acetyl-N-3-butenylamino)- and 3-(N-acetyl-N-4-pentenylamino)-5,5-dimethyl-2-cyclohexen-1-ones afforded the 2-azabicyclo [n.2.0] alkanes. Some of the ring opening reactions of these photoadducts are also described.

• 公益社団法人日本薬学会の論文
• 1981-07-25

著者

• 石橋 弘行

  Faculty of Pharmaceutical Sciences, Osaka University

• 池田 正澄

  Faculty of Pharmaceutical Sciences, Osaka University

• 本間 光一

  Faculty Of Pharmaceutical Sciences Osaka University

• 大野 一教

  Faculty of Pharmaceutical Sciences, Osaka University

• 石橋 弘行

  金沢大学薬学部

• 石橋 弘行

  京都薬科大学

• 田村 泰光

  Faculty of Pharmaceutical Sciences, Osaka University

• 田村 泰光

  Faculty Of Pharmaceutical Sciences Osaka University

• 大野 一教

  Exploratory Research Laboratories Dainippon Pharmaceutical Co. Ltd.

• Ohno K

  Exploratory Research Laboratories Dainippon Pharmaceutical Co. Ltd.

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