Studies on Plants containing Indole Alkaloids. VII. Isolation of Several Aspidosperma-and Vincamine-type Alkaloids from the seeds of Amsonia elliptica ROEM. et SCHULT.
スポンサーリンク
概要
- 論文の詳細を見る
Four known (tabersonine (1), tetrahydroalstonine (2), Δ^<14>-vincamine (6) and 16-epi-Δ^<14>-vincamine (5)) and four new indole alkaloids (3-oxo-tabersonine (3), 14,15-epoxy-3-oxo-vincadifformine (4), 16-carbomethoxy-16-hydroxy-14,15-epoxy-3-oxo-1,2-dehydroaspidospermidine (7) and tabersonine N_<(b)>-oxide (8)) were isolated from the seeds of Amsonia elliptica ROEM. et SCHULT. (Apocynaceae). Δ^<14>-Vincamine (6) and its C_<(16)>-epimer (5) were partially synthesized from tabersonine (1). Unusual oxidative chlorination was observed when tabersonine hydrochloride was oxidized with m-chloroperbenzoic acid.
- 公益社団法人日本薬学会の論文
- 1978-04-25
著者
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相見 則郎
Faculty Of Pharmaceutical Sciences University Of Tokyo
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坂井 進一郎
Faculty of Pharmaceutical Sciences, Chiba University
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萩庭 丈寿
千葉大学薬学部
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萩庭 丈寿
Faculty of Pharmaceutical Sciences, Chiba University
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荻庭 丈寿
千葉大 薬
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萩庭 文寿
千葉大・藥
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浅田 善久
Faculty Of Pharmaceutical Sciences Chiba University
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坂井 進一郎
Faculty Of Pharmaceutical Sciences Chiba University
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