The Partial Synthesis of Heteroyohimbine Alkaloids : Akuammigine, 3-Isorauniticine and Corynanthe Alkaloid ; Corynantheidine
スポンサーリンク
概要
- 論文の詳細を見る
Heteroyohimbine alkaloids, akuammigine and 3-isorauniticine, were synthesized using a modified Polonovski reaction followed by NaCNBH_3 reduction from desmethylhirsuteine N-oxide, which was derived from the indole alkaloid hirsuteine. Corynanthe alkaloid, corynantheidine was also synthesized using the same method from hirsuteine N-oxide.
- 1978-08-25
著者
-
坂井 進一郎
Faculty of Pharmaceutical Sciences, Chiba University
-
新間 信夫
Department of Microbiology and Chemotherapy, Nippon Roche Research Center
-
新間 信夫
Department Of Microbiology And Chemotherapy Nippon Roche Research Center
-
坂井 進一郎
Showa College of Pharmaceutical Sciences
-
新間 信夫
Faculty of Pharmaceutical Sciences, Chiba University
-
坂井 進一郎
Faculty Of Pharmaceutical Sciences Chiba University
関連論文
- New Corymine-Related Indole Alkaloids from Hunteria zeylanica in Thailand
- A NEW CLASS OF TWO DIMERIC INDOLE ALKALOIDS, CORYZEYLAMINE AND DEFORMYLCORYZEYLAMINE, FROM THE LEAVES OF HUNTERIA ZEYLANICA IN THAILAND
- Novel Indole Alkaloids from the Leaves of Rauwolfia sumatrana JACK. in Thailand
- HUNTERIOSIDE, FIRST BIOSE BOUND MONOTERPENOID INDOLE ALKALOID FROM HUNTERIA ZEYLANICA
- Two New Dimeric Indole Alkaloids from Tabernaemontana subglobosa MERR. from Taiwan
- A Nuclear Magnetic Resonance Study on the Eleven Stereoisomers of Heteroyohimbine-Type Oxindole Alkaloids
- KINGINOSIDE, A NEW ACYL GROUP CARRYING IRIDOID BIOSIDE FROM LONICERA MORROWII
- The Structure of Garcinone E
- On the Alkaloidal Constituents of Aconitum sanyoense NAKAI var. tonense NAKAI
- SYNTHESIS OF LYALOSIDE, A PROTOTYPAL β-CARBOLINE GLUCO INDOLE ALKALOID IN RUBIACEOUS PLANTS
- STRUCTURES OF TWO NEW BITTER PRINCIPLES ISOLATED FROM A THAI MEDICINAL PLANT, VERNONIA EXTENSA D. C.
- FIVE NEW NAPELLINE-TYPE DITERPENE ALKALOIDS FROM ACONITUM LIANGSHANIUM
- Partial Synthesis of Rauwolfia Alkaloids, Vomilenine and (19Z)-Vomilenine, and Their Relative Thermodynamic Stability as Revealed by Their Transformation into Perakine
- STRUCTURE AND SYNTHESIS OF TWO NEW TYPES OF OXINDOLE ALKALOIDS FOUND FROM UNCARIA SALACCENSIS
- TWO NEW DITERPENE ALKALOIDS, 10-HYDROXYISOTALATIZIDINE AND 10-HYDROXY-TALATIZAMINE
- New Platelet Aggregation Inhibitors from Tan-Shen ; Radix of Salvia miltiorrhiza BUNGE
- SYNTHESES OF THE β-ERYTHROIDINE SKELETON(Communications to the Editor)
- The Structures of Gardnerine, Gardnutine and Hydroxygardnutine and the Absolute Configuration of Gardnerine
- THE STRUCTURE AND ABSOLUTE CONFIGURATION OF HANAMISINE
- THE STRUCTURE AND ABSOLUTE CONFIGURATION OF SADOSINE
- THE STRUCTURE OF IGNAVINE
- STRUCTURE OF TWO NEW DITERPENE ALKALOIDS, 3-EPI-IGNAVINOL AND 2,3-DEHYDRODELCOSINE
- GARDNERIA ALKALOIDS PART 14. THE STRUCTURE OF GARDFLORAMINE AND 18-DEMETHOXYGARDFLORAMINE(Communications to the Editor)
- HYDROLYTIC DEGRADATION OF β-CARBOLINE-TYPE MONOTERPENOID GLUCOINDOLE ALKALOIDS : A POSSIBLE MECHANISM FOR HARMAN FORMATION IN Ophiorrhiza AND RELATED RUBIACEOUS PLANTS
- Studies on Plants containing Indole Alkaloids. VIII Indole Alkaloid Glycosides and Other Constituents of the Leaves of Uncaria rhynchophylla MIQ.
- PARTIAL SYNTHESIS OF DIHYDROTHYSANOLACTONE
- Structure Elucidation of a New Aconite Alkaloid, 15-α-Hydroxyneoline
- THE STRUCTURES OF ADDITIONAL TELEOCIDIN CLASS TUMOR PROMOTERS
- The Synthesis of Secamine and Presecamine Skeletons and the Isolation of Tetrahydrosecamine from Amsonia elliptica ROEM et SCHULT.
- SYNTHESIS OF SAFRAMYCINS. I. TOTAL SYNTHESIS OF (±)-SAFRAMYCIN B AND ITS CONGENERS.(Communication to the Editor)
- Studies on Plants containing Indole Alkaloids. VI. Minor Bases of Uncaria rhynchophylla MIQ.
- The C2-C3 Bond Cleavage Reaction of Indole Alkaloids
- THE PREPARATION OF 14-HYDROXYLATED YOHIMBINE AND RESERPINE DERIVATIVES
- Dioxopyrrolines. XXXII. X-Ray Determination of the Molecular Structure of a Photoadduct of 2-Trimethylsilyloxybutadiene to 3-Ethoxycarbonyl-2-phenyl-Δ^2-pyrroline-4,5-dione
- Gardneria Alkaloids. XII. Carbon Magnetic Resonance Spectra of Gardneria Alkaloids. A Study on the Configuration of the Side Chain Double Bonds of Indole Alkaloids
- Structure of Gardneramine and 18-Demethylgardneramine
- インドールアルカロイド類の転換反応(第2報)インドールアルカロイドのC/D環開環ならびに閉環反応とVobasine型アルカロイドの合成について
- 37 インドールアルカロイド類の転換反応 : C/D環,開環並びに閉環反応について
- Oxidation of 2,3-Disubstituted Indole Derivatives with Selenium Dioxide
- Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XIII. Mass Spectra of Azanaphthalene N-Oxides and Their Photochemical Reaction Products
- A Novel Skeletal Rearrangement of Aromatic N-Oxides upon Electron Impact
- ELUCIDATION OF THE STRUCTURES OF OLIVORETIN B AND C
- SYNTHESIS OF OPTICALLY ACTIVE TELEOCIDIN DERIVATIVES. ABSOLUTE CONFIGURATION OF TELEOCIDIN B AND OLIVORETIN A
- ELUCIDATION OF THE STRUCTURE OF OLIVORETIN A AND D (TELEOCIDIN B)
- A New Indole Alkaloid, 14α-Hydroxyrauniticine : Structure Revision and Partial Synthesis
- A Convenient Synthesis of 1,2,3,4,6,7,12,12b-Octahydroindolo-[2,3-α]quinolizine Derivatives
- Transformation of Indole Alkaloids. VI. A Novel Conversion of Oxindole Alkaloids into Indole Alkaloids via Indoline Derivatives
- Indole系アルカロイド含有植物の検索 その2 日本産カギカズラ(Uncaria rhynchophylla MIQ.)の塩基成分について
- THE CONVERSION OF PSEUDOKOBUSINE TO KOBUSINE
- THE STRUCTURE OF THE NEW DITERPENE ALKALOID NOMININE AND THE ABSOLUTE CONFIGURATION OF KOBUSINE
- THE STRUCTURE OF A NEW DITERPENE ALKALOID : SANYONAMINE
- THE STRUCTURE OF HYPOGNAVINE
- THE PARTIAL SYNTHESIS OF ISODELPHININE
- オオレイジンソウ (Aconitum gigas LEV.et VAN.)の塩基成分並びに新塩基Gigactonineの化学構造
- SYNTHESIS OF RESTRICTINOL AND 9,10,11,12-TETRAHYDRO-7-DESMETHYLRESTRICTICIN
- The Partial Synthesis of Heteroyohimbine Alkaloids : Akuammigine, 3-Isorauniticine and Corynanthe Alkaloid ; Corynantheidine
- インドールアルカロイド類の転換反応(第5報)C-Mavacurine型インドールアルカロイド, 16-Epipleiocarpamineの合成
- A New Synthesis of Dihydromancunine
- Transformation of Indole Alkaloids. The Chemical Transformation of Corynantheine Type Alkaloids to C-Mavacurine Type Alkaloids
- 23 Corynantheine型アルカロイドよりC-Mavacurine型アルカロイドへの化学変換
- Asymmetric Synthesis and Absolute Configuration of (-)-Trypargine
- ASYMMETRIC SYNTHESIS OF (1S)-(-)-TRYPARGINE
- Thiazole Analogs of Benzomorphans. II. Synthesis of Novel Thiazolo [5,4-f] morphans
- Studies on Plants containing Indole Alkaloids. VII. Isolation of Several Aspidosperma-and Vincamine-type Alkaloids from the seeds of Amsonia elliptica ROEM. et SCHULT.
- Antinociceptive and Antipyretic Effects of Alkaloids Extracted from the Stem Bark of Hunteria zeylanica
- A REARRANGEMENT OF AN ASPIDOSPERMA TYPE ALKALOID INTO A TETRAHYDROQUINOLINE DERIVATIVE : UNAMBIGUOUS CONFIRMATION OF THE RESULTING SKELETON STRUCTURE
- Synthetic Sutdies on the Picraline-Type Indole Alkaloids-I : Improved Synthesis of C-Mavacurine-Type Compounds and a New Skeletal Rearrangement in a Corynanthe-Type Derivative
- ISOLATION AND STRUCTURE ELUCIDATION OF TELEOCIDIN B-1,B-2,B-3,AND B-4
- A Convenient Synthesis of 1,2,3,4,6,7,12,12b-Octahydroindolo-[2,3-a] quinolizine
- Imidazo{2,1-b]benzothiazoles. II. : Synthesis and Antinflammatory Activity of Some Imidazo[2,1-b]benzothiazoles
- Imidazo[2,1-b]benzothiazoles. I
- The Chemical Transformation of Gardnerine to 2-Acylindole Alkaloid"Ochropine"
- Uber die Konstitution des Hypognavins
- INDOLE ALKALOIDS ISOLATED FROM GELSEMIUM ELEGANS(THAILAND) : 19-(Z)-AKUAMMIDINE, 16-EPI-VOACARPINE, 19-HYDROXYDIHYDRO-GELSEVIRINE, AND THE REVISED STRUCTURE OF KOUMIDINE(Communications to the Editor)
- 4,4-Dimethyl Effect. (5). The Conformation of 8αH, 14βH-Onocerane-3,21-dione (Onoceranedione-I) in the Crystalline State
- STRUCTURES OF TOROKONINE AND GOMANDONINE, TWO NEW DITERPENE ALKALOIDS FROM ACONITDM SUBCUNEATUM NAKAI(Communications to the Editor)
- SYNTHESIS OF THYSANOLACTONE FROM HYDROXYHOPANONE
- CHEMICAL CONVERSION OF GARDNERINE INTO KOUMIDINE BY INVERTING THE ETHYLIDENE SIDE CHAIN WITH PALLADIUM CATALYST