Synthesis of All Four Possible Stereoisomers of 1-Phenyl-2,3-butanediol and Both Enantiomers of 3-Hydroxy-4-phenyl-2-butanone to Determine the Absolute Configuration of the Natural Constituents

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概要

• 論文の詳細を見る

• Enantioselective syntheses of all the possible stereoisomers of 1-phenyl-2, 3-butanediol (erythro isomer 1 and threo isomer 2) and of 3-hydroxy-4-phenyl-2-butanone 3, the odor components of wisteria flowers, was accomplished via Sharpless asymmetric epoxydation. The absolute configurations of 1-3 were determined by an HPLC analysis of the corresponding MTPA esters of synthetic samples.

• 社団法人日本農芸化学会の論文
• 1995-07-23

著者

• Kitahara Takeshi

  Department Of Applied Biological Chemistry Division Of Agriculture And Agricultural Life Science The

• Takagi Y

  Saga Univ. Saga Jpn

• Mori Kenji

  Department of Biochemistry, National Cardiovascular Center Research Institute

• Takagi Y

  Iwate Univ. Morioka Jpn

• 松浦 克子

  キッコーマン株式会社 研究本部

• Yanai Tetsuya

  Technical Research Center, T. Hasegawa Co., Ltd.

• Takagi Yoshikazu

  Technical Research Center, T. Hasegawa Co., Ltd.

• Awano Ken-Ichi

  Technical Research Center, T. Hasegawa Co., Ltd.

• Watanabe Ichiro

  Technical Research Center, T. Hasegawa Co., Ltd.

• Takagi Yoshikazu

  Technical Research Center T. Hasegawa Co. Ltd.

• Yanai Tetsuya

  Technical Research Center T. Hasegawa Co. Ltd.

• Awano Ken-ichi

  Technical Research Center T. Hasegawa Co. Ltd.

• Mori K

  Sci. Univ. Tokyo Tokyo Jpn

• Kitahara T

  The University Of Tokyo

• Kitahara T

  Department Of Agricultural Chemistry The University Of Tokyo

• Mori Kenji

  Department Of Biochemistry National Cardiovascular Center Research Institute

• Mori Kenji

  Department Of Agricultural Chemistry The University Of Tokyo

• Kitahara Takeshi

  Department Of Agricultural Chemistry The University Of Tokyo

• Kitahara Takeshi

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni

• Mori Kenji

  Department Of Agricultural Chemistry Nagoya University

• Mori Kenji

  Department Of Agricultural Chemistry College Of Science And Technology The University Of Tokyo

• Watanabe Ichiro

  Technical Research Center T. Hasegawa Co. Ltd.

• Kitahara Takeshi

  School Of Pharmacy Teikyo Heisei Univ.

• Takagi Yoshiakzu

  Kawasaki Research Laboratory T. Hasegawa Co. Ltd.

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