Concise Synthesis of a Racemic and Diastereomeric Mixture of the Sex Pheromones of Matsucoccus Pine Scales

スポンサーリンク

概要

• 論文の詳細を見る

• A short (3-5 steps) synthesis of a racemic and diastereomeric mixture of Matsucoccus sex pheromones (1-3) is described. The key reaction is Lewis acid-mediated cyanation of symmetric tertiary alcohol 6 to afford common intermediate 7.

• 社団法人日本農芸化学会の論文
• 1997-01-23

著者

• MORI Kenji

  The University of Tokyo

• Kitahara Takeshi

  Department Of Applied Biological Chemistry Division Of Agriculture And Agricultural Life Science The

• WATANABE HIDENORI

  Department of Applied Biological Chemistry, The University of Tokyo

• Mori Kenji

  Department of Biochemistry, National Cardiovascular Center Research Institute

• WATANABE Takeru

  Department of Electrical Engineering, Faculty of Science and Technology, Science University of Tokyo

• Watanabe H

  The University Of Tokyo

• Mori K

  The University Of Tokyo

• Kitahara T

  The University Of Tokyo

• Kitahara T

  Department Of Agricultural Chemistry The University Of Tokyo

• Watanabe Hidenori

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni

• Mori Kenji

  Department Of Biochemistry National Cardiovascular Center Research Institute

• Watanabe Takeru

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni

• Mori Kenji

  Department Of Agricultural Chemistry The University Of Tokyo

• Watanabe Hidenori

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni

• Kitahara Takeshi

  Department Of Agricultural Chemistry The University Of Tokyo

• Kitahara Takeshi

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni

• Mori Kenji

  Department Of Agricultural Chemistry Nagoya University

• Watanabe Hidenori

  Department Of Applied Biological Chemistry Graduate School Of Agricultural And Biological Sciences T

• Mori Kenji

  Department Of Agricultural Chemistry College Of Science And Technology The University Of Tokyo

• Kitahara Takeshi

  School Of Pharmacy Teikyo Heisei Univ.

関連論文

• Plenary Lecture: Searching Environmentally Benign Methods for Pest Control: Reflection of a Synthetic Chemist (日本農薬学会誌 [第11回IUPAC農薬化学国際会議]特別号(2007))
• Structure of Tyroscherin, an Antitumor Antibiotic against IGF-1-dependent Cells from Pseudallescheria sp
• Absolute Configuration of Migrastatin, a Novel 14-Membered Ring Macrolide
• C-type Natriuretic Peptide, a Novel Antifibrotic Agent, Attenuates Cardiac Remodeling and Improves Left Ventricular Dysfunction in Dilated Cardiomyopathy(Cardiovascular Pharmacology, Basic/Clinical 1 (H), The 69th Annual Scientific Meeting of the Japanese
• Calcineurin-NFAT Pathway-Dependent Cardiac Remodeling in Mice Deficient for GC-A, a Receptor for Atrial and Brain Natriuretic Peptides(Cardiac Hypertrophy 1 (M), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Interaction between C-Type Natriuretic Peptide and Endothelin-1 in Hypertrophic Response of Cultured Rat Cardiac Myocytes
• Endogenous Endothelin-1 Secreted from Cultured Rat Cardiac Nonmyocytes Inhibits Doxorubicin-Induced Cardiac Myocyte Apoptosis via ERK-Dependent CREB Activation
• A case of Kabuki syndrome presenting West syndrome
• Structure-activity Relationship for FR901464 : A Versatile Method for the Conversion and Preparation of Biologically Active Biotinylated Probes
• Short-step Syntheses of All Stereoisomers of Preussin and Their Bioactivities(Organic Chemistry)
• Radicicol Binding to Swo1/Hsp90 and Inhibition of Growth of Specific Temperature-sensitive Cell Cycle Mutants of Fission Yeast(Biochemistry & Molecular Biology)
• Stereoselective Synthesis of Methyl Epijasmonate(Organic Chemistry)
• PE-468 Angiographic and Clinical Outcomes of Severe Calcified Lesions Requiring Rotational Atherectomy in Hemodialysis(HD) and Non-hemodialysis Patients after SES Implantation(PE079,Coronary Revascularization, PCI (Complex Lesions) (IHD),Poster Session (E
• PE-149 Enhanced Platelet Activation in Patients with Hemodialysis after Coronary Stent Implantation(PE025,Thromboembolism/Antithrombotic Therapy/Thrombolysis 2 (IHD),Poster Session (English),The 73rd Annual Scientific Meeting of The Japanese Circulation S
• OE-158 Significance of Pre-test Likelihood of Coronary Artery Disease in Patients with Coronary Artery Calcium Score Zero(OE27,CT/MRI (Coronary/Vascular) 1 (I),Oral Presentation (English),The 73rd Annual Scientific Meeting of The Japanese Circulation Soci
• OJ-211 Significance of VlDAS D-dimer for Acute Coronary Syndrome Patients(Acute coronary syndrome, basic / clinical(02)(IHD),Oral Presentation (Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
• PE-462 Comparison of Clinical Outcomes of Percutaneous Transluminal Angioplasty to Superficial Femoral Artery with and without Stenting in Hemodialysis Patients(Peripheral circulation/Vascular disease-3, The 71st Annual Scientific Meeting of the Japanese
• Trial of intraventricular ribavirin therapy for subacute sclerosing panencephalitis in Japan
• Synthesis of Pironetin and Related Analogs : Studies on Structure-Activity Relationships as Tubulin Assembly Inhibitors
• Neuronal protein NP25 interacts with F-actin
• Neuronal protein25は神経細胞の分化により増加する
• Pathophysiology of the transient temporal lobe lesion in a patient with Menkes disease
• Serial brain imaging analysis of stroke-like episodes in MELAS
• Favorable response of ADHD with giant SEP to extended-release valproate
• Administration of secretin for autism alters dopamine metabolism in the central nervous system
• Synthesis of 4-Hydroxy-3(2H)-furanone Acyl Derivatives and Their Anti-cataract Effect on Spontaneous Cataract Rats (ICR/f)
• Antioxidative Activities of 4-Hydroxy-3 (2H)-furanones and Their Anti-cataract Effect on Spontaneous Cataract Rat (ICR/f)
• Synthesis of Methyl (5Z, 9Z, 17R)-17-Methylnonadeca-5, 9-dienoate, the (R)-Enantiomer of the Structure Proposed for a Metabolite of the Philippine Sponge Plakinastrella sp.(Organic Chemistry)
• Patients with West syndrome whose ictal SPECT showed focal cortical hyperperfusion
• A case of acute encephalitis with refractory, repetitive partial seizures, presenting autoantibody to glutamate receptor Gluε2
• Successful Management of Intractable Epilepsy with Lidocaine Tapes and Continuous Subcutaneous Lidocaine Infusion
• A case of idiopathic portal hypertension associated with rheumatoid arthritis
• Synthesis of Both the Enantiomers of trans-Chrysanthenol and trans-Chrysanthenyl Acetate as the Characteristic Major Constituents of Kougiku
• Synthesis of All Four Possible Stereoisomers of 1-Phenyl-2,3-butanediol and Both Enantiomers of 3-Hydroxy-4-phenyl-2-butanone to Determine the Absolute Configuration of the Natural Constituents
• Simple Synthesis of Dehydrololiolide
• Synthesis of (±)-Methyl Epijasmonate and (±)-Methyl Cucurbate(Organic Chemistry)
• A Simple and Efficient Synthesis of (±)-Methyl Dihydroepijasmonate(Organic Chemistry)
• Stereoselective Synthesis of erythro-Serricornin, (4R, 6R, 7S)-, and (4596R, 75)-4?6-Dimethyl-7-hydroxynonan-3-one9 Stereoisomers of the Sex Pheromone of Cigarette Beetle
• Molecular Action Mode of Hippospongic Acid A, an Inhibitor of Gastrulation of Starfish Embryos
• Enantioselective Synthesis of Both the Enantiomers of Jasmine Ketolactone and Its Epimer
• PE-083 The Predictors of Incomplete Stent Expansion with Percutaneous Coronary Intervention in Hemodialysis Patients(Coronary revascularization, PCI-8 (IHD) PE14,Poster Session (English),The 70th Anniversary Annual Scientific Meeting of the Japanese Circu
• Biological activity of pestalotins on the elongation growth of rice seedlings
• Subtilisin-Like Proprotein Convertases, PACE4 and PC8, as Well as Furin, are Endogenous Proalbumin Convertases in HepG2 Cells
• Biological Activities of YTIT/YTIY Analogous Sequences Present in Fibronectin-Like Type III Repeats
• The Change of Memory Formation According to STDP in a Continuous-Time Neural Network Model
• A remarkable large hamartoma around the knee in a patient with tuberous sclerosis
• P-359 SYNTHETIC STUDY ON AZADIRACHTIN
• Simple Synthesis of Enantiomerically Pure Sauriols A and B
• Long-term follow-up of a patient with subacute sclerosing panencephalitis successfully treated with intrathecal interferon alpha
• Adrenocorticotropic hormone therapy for infantile spasms alters pyruvate metabolism in the central nervous system
• Biotransformation of α-Isomethylionone to 1-(2, 6, 6-Trimethyl-2-cyclohexen-1-yl)propan-2-one
• Behavioral and Electroantennogram Responses of Male American Cockroaches to Periplanones and Their Analogs(Organic Chemistry)
• Pb7 HAUPTMANN'S PERIPLANONE-A : CHARACTERIZATION AND ELUCIDATION OF THE FORMATION
• Syntheses of Four Methyl-branched Secondary Acetates and a Methyl-branched Ketone as Possible Candidates for the Female Pheromone of the Screwworm Fly, Cochliomyia hominivorax(Organic Chemistry)
• Syntheses of Racemic and Diastereomeric Mixtures of 3,7,11,15-Tetramethylhentriacontane and 4,8,12,16-Tetramethyldotriacontane, the Cuticular Tetramethylalkanes of the Tsetse Fly, Glossina brevipalpis(Organic Chemistry)
• Concise Synthesis of a Racemic and Diastereomeric Mixture of the Sex Pheromones of Matsucoccus Pine Scales
• Determination of the (2E, 4E)-Geometry of the 3,5-Dimethyl-2,4-diene System of Antibiotic 1233A by NMR Comparison with the Four Geometrical Isomers of Methyl 3,5-Dimethyl-2,4-heptadienoate
• Percutaneous hot water injection and microwave coagulation therapy for small hepatocellular carcinoma
• P-443 Synthesis and Sensory Evaluation of Enantiopure Sedanolides
• Genomic Organization and Alternative Splicing of Human PACE4 (SPC4), Kexin-Like Processing Endoprotease
• Synthesis of Gerfelin and Related Analogous Compounds
• Synthesis of (+)-Turmeronol A, an Inhibitor of Soybean Lipoxygenase, and (+)-ar-Turmerone
• Synthesis of the Glycosidic Precursor of Isomeric Marmelo Lactones, Volatile Components of the Quince Fruit, Cydonia oblonga(Organic Chemistry)
• Human Subtilisin-Like Proprotein Convertase, PACE4 (SPC4) Gene Expression Is Highly Regulated through E-Box Elements in HepG2 and GH4C1 Cells
• Synthesis of the Enantiomers of 7-Methyl-1,6-dioxaspiro[4.5]decane, Pheromone of the Common Wasp and the Pine Beetle
• Synthesis of (4aR, 10aS)-(-)-8-Methoxy-1, 1, 4a-trimethyl-2-oxo-1, 2, 3, 4, 4a, 9, 10, 10a-octahydrophenanthrene, an Optically Active Intermediate for the Synthesis of Diterpenes(Organic Chemistry)
• Synthesis of (±)-Hiburipyranone, a Cytotoxic Metabolite of Marine Sponge Mycale adhaerens
• Synthesis of the Esterified Cerebroside in the Epidermis of Guinea Pigs
• Reinvestigation of the Structure of the Esterified Cerebroside in the Epidermis of Guinea pigs
• Synthesis of (-)-Allosamizoline, the Pseudoaminosugar Moiety of Allosamidin, a Chitinase Inhibitor
• Brassinolide and Homobrassinolide Promotion of Lamina Inclination of Rice Seedlings
• Synthesis of (R)-Callosobruchusic Acid from Methyl (R)-3-Carboxybutanoate
• Compounds with Juvenile Hormone Activity. I. Inhibitory Effects of the Synthetic Juvenile Hormone and Its Analogues on the Metamorphosis of Several Insects
• New Optically Active 4,4-Dialky1-γ-lactones as Chiral Dopants for Ferroelectric Liquid Crystals
• Synthesis of (S,E)-1-Methyl-9-dodecenyl Acetate, the Sex Pheromone of the Hessian Fly, Mayetiola destructor
• B-10-5 Synthesis of Substances related to Gibberellins(Terpenoids)
• Sex Pheromone of the Comstock Mealybug, Pseudococcus comstocki KUWANA : Isolation and Identification
• Synthesis of Brassinolide Analogs with a Modified Ring B and Their Plant Growth-promoting Activity(Organic Chemistry)
• Juvenile Hormone Activity of Terpeniod Esters and Phenyl-Geranyl-Ethers with Different Alkyl Substituents against the Silkworm, Bombyx mori L. (Lepidoptera : Bombycidae)
• Juvenile Hormone and synthetic Analogues : II. : Novel Substances with High Juvenile Hormone Activity
• Increased Accumulation of Silk Protein Accompanying JH-Induced Prolongation of Larval Life in Bombyx mori L.(Lepidoptera : Bombycidae)
• Synthesis of the Racemate and Both Enantiomers of Massoilactone(Organic Chemistry)
• Synthesis of (2S,4R,5S)-2,4,6-Trimethyl-5-heptanolide, a Sex Pheromone Component for Macrocentrus grandii
• Simple Synthesis of a Mixture of (E)- and (Z)-5-Undecenoic Acid, Sex Pheromone of the Varied Carpet Beetle(Organic Chemistry)
• Indium-Catalyzed Cross-Coupling Reactions between α, β-Unsaturated Carbonyl Compounds and Aromatic Aldehydes
• InCl_3-Catalyzed Reductive Coupling of Aromatic Carbonyl Compounds in the Presence of Magnesium and Chlorotrimethylsilane
• New Synthesis of Macrolide Pheromones of the Flat Grain Beetle, Cryptolestes pusillus Schonherr(Organic Chemistry)
• "Aqua-space^【○!R】", a New Headspace Method for Isolation of Natural Floral Aromas Using Humidified Air as a Carrier Gas
• Lipase-catalyzed Kinetic Resolution of (±)-cis, cis-Spiro [4.4] nonane-1,6-diol
• Synthesis of (2RS,8R,10R)-YM-193221 and an Improved Approach to Tyroscherin, Bioactive Natural Compounds from Pseudallescheria sp.
• Cloning and Sequencing of the Pz-Peptidase Gene from Bacillus licheniformis N22
• Spliceostatin A blocks angiogenesis by inhibiting global gene expression including VEGF
• P-358 SYNTHESIS OF FUNGAL 10-MEMBERED LACTONES, MICROCARPALIDE AND SCH642305
• Synthesis and biological evaluation of analogs of the tetrahydropyran acetogenin, muconin
• Inactivation of Proprotein Convertase, PACE4, by α1-Antitrypsin Portland (α1-PDX), a Blocker of Proteolytic Activation of Bone Morphogenetic Protein during Embryogenesis: Evidence That PACE4 Is Able to Form an SDS-Stable Acyl Intermediate with α1- PDX
• A Novel Human PACE4 Isoform, PACE4E Is an Active Processing Protease Containing a Hydrophobic Cluster at the Carboxy Terminus^1
• Synthesis of FF8181-A
• Short-step Synthesis of Chenodiol from Stigmasterol
• Synthesis of (R)- and (S)- Muscone(Organic Chemistry)
• A Facile Synthetic Method for Indolic Enamides

もっと見る 閉じる

スポンサーリンク