The Syntheses and Properties of the Benzothiazole or Benzimidazole Derivative Adducts of Tin(II, IV) and Antimony(III) Halides

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概要

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• The benzothiazole, 2-amino-benzothiazole, benzimidazole-2-thiol, and benzothiazole-2-thiol adducts of tin(II, IV) chlorides, antimony(III) chloride, and antimony (III) bromide with the formulae of M<SUP><I>n</I>+</SUP>L<I><SUB>m</SUB></I>X<I><SUB>n</SUB></I><SUP>−</SUP> (where L is the ligand and where X is Cl or Br) were synthesized. From their electronic and infrared spectra, it can be seen that the 2-amino-benzothiazole adducts are more stable than those of other ligands and that the metal-ligand bonds in the former remain, even in the ethanolic solution.

• 公益社団法人 日本化学会の論文

著者

• Takeuchi Toshio

  Department Of Aquatic Biosciences Faculty Of Fisheries Tokyo University Of Fisheries

• Ouchi Akira

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Taminaga Iwao

  Department of Chemistry, College of General Education, The University of Tokyo

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