The crystal and molecular structure of diaquadihydroxotetrakis-(m-nitrobenzenesulfonato)discandium(III) in a linear polymeric form, [Sc2(OH)2(O2NC6H4SO3)4(H2O)2]n.
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概要
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The crystal and molecular structures of the title complex has been determined by the single-crystal X-ray diffraction method. It is monoclinic, with the space group <I>Pn</I>, <I>Z</I>=2 (including 4 metal atoms), <I>a</I>=28.90(2), <I>b</I>=10.251(4), <I>c</I>=5.981(1) Å, and β=94.68(3)°. Both of the metal atoms, Sc(1) and Sc(2), have the hexa-coordinated octahedral geometry, being coordinated to four sulfonato oxygen atoms as well as to two water oxygen (Sc(1)) or to two hydroxide oxygen atoms (Sc(2)). Any pair of the neighboring metal atoms along the b-axis are bridged by two sulfonato ions, forming an infinite chain structure; however, the Sc(2)–O bond lengths (2.307(10)–2.556(19) Å; average, Sc(2)–O (sulfonate), 2.422; Sc(2)–O(OH<SUP>−</SUP>), 2.394 Å) are much longer than the Sc(1)–O lengths (2.031(7)–2.150(8) Å; average, Sc(1)–O(sulfonate), 2.055; Sc(1)–O(H<SUB>2</SUB>O), 2.122 Å).
- 公益社団法人 日本化学会の論文
著者
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Suzuki Yasuo
Department Of Applied Physics Faculty Of Engineering Fukui University
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Tateyama Yoshikuni
Department of Industrial Chemistry, Faculty of Engineering, Meiji University
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Ohki Yoshiyuki
Department of Industrial Chemistry, Faculty of Engineering, Meiji University
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Ouchi Akira
Department of Chemistry, College of Arts and Sciences, The University of Tokyo
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