The crystal and molecular structure of bis(4-methylpyridine)-bis(thiocyanato)cadmium(II) in polymeric form, (Cd(SCN)2(CH3C5H4N)2)n.

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概要

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• The crystal and molecular structure of the title complex was determined by a single-crystal X-ray diffraction technique. The crystal is triclinic with a space group <I>P</I>\bar1, <I>a</I>=11.323(4), <I>b</I>=18.383(10), <I>c</I>=9.284(5) Å, α=104.62(4), β=114.26(3), γ=77.71(4)°, <I>Z</I>=4; the final <I>R</I> value obtained was 0.034. All cadmium atoms are lined approximately along the [111] axis and each pair of metal atoms are bridged by two thiocyanate ions (SCN), one of which is <I>S</I>-coordinated and the other is <I>N</I>-coordinated to the same side metal atom. Also bonded with two nitrogen atoms of 4-methylpyridine (pic) ligands, the metal atom is 4<I>N</I>2<I>S</I>-hexa-coordinated and is in an octahedral geometry. The cadmium atoms, where the ligated respective pairs of N(SCN), N(pic), and S(SCN) atoms are all in a trans configuration, and the metal atoms where the ligated respective pairs of N(pic) and S(SCN) are in cis, while the pair of the N(SCN) in trans configuration, appear alternatively in the polymer chain.

• 公益社団法人 日本化学会の論文

著者

• Taniguchi Masahiro

  Department Of Bioapplied Chemistry Faculty Of Engineering Osaka City University

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Ouchi Akira

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

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