The synthesis and the crystal and molecular structure of (tris(dibutyl sulfoxide)bis(O,O'-diisopropyl dithiophosphato)neodymium(III))(tetrakis(O,O'-diisopropyl dithiophosphato)neodymium(III)) (Nd{(C3H7O)2PS2}2{(C4H9)2SO}3)(Nd{(C3H7O)2PS2}4).

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概要

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• The title complex has been synthesized, and its crystals and molecular structure has been determined by the use of the single-crystal X-ray-diffraction method. The crystal of Nd<SUB>2</SUB>C<SUB>60</SUB>H<SUB>138</SUB>O<SUB>15</SUB>P<SUB>6</SUB>S<SUB>15</SUB>, F. W.=2055.03, was monoclinic, with a space group of An; <I>a</I>=23.696(4), <I>b</I>=23.466(4), <I>c</I>=20.208(4) Å, β=111.22(2) °, <I>Z</I>=4, <I>V</I>=10475(4) Å<SUP>3</SUP>, <I>D</I><SUB>m</SUB>=1.30(3), <I>D</I><SUB>x</SUB>=1.30 Mg m<SUP>−3</SUP>, and μ(Mo <I>K</I>α)=1.41 mm<SUP>−1</SUP>. The complex consists of cationic and anionic species, as is shown in the title. The metal atom of the cationic complex is hepta-coordinated and is in a pentagonal-bipyramidal geometry, while the anionic one is octa-coordinated and is in a dodecahedral geometry.

• 公益社団法人 日本化学会の論文

著者

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Suzuki Yasuo

  Department Of Applied Physics Faculty Of Engineering Fukui University

• Ohki Yoshiyuki

  Department of Industrial Chemistry, Faculty of Engineering, Meiji University

• Ouchi Akira

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Nagai Kiyofumi

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Nakamura Masao

  Department of Applied Chemistry, Faculty of Engineering, Nagoya University

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