The structure of dichloro(4-hydroxy-L-proline)cadmium(II).

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概要

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• An X-ray diffraction study of the title complex has been carried out. The crystal is monoclinic, with the space group P2<SUB>1</SUB>; <I>Z</I>=2; <I>a</I>=8.196(4), <I>b</I>=7.275(3), <I>c</I>=7.740(4) Å, β=103.73(4)° Full-matrix least-squares refinements have led to the final <I>R</I> value of 0.030. The structure consists of one-dimensional polymers bridged by chlorine atoms and a carboxyl group. Four chlorine atoms coordinate to a cadmium atom and form a square plane. The planes extend in the direction of the b axis like an infinite folding screen, sharing opposite edges. From the trough positions in the zigzag structure, the carboxyl oxygen atoms of 4-hydroxy-L-proline coordinate forkedly to two cadmium atoms. The ligand is a zwitter ion in the complex.

• 公益社団法人 日本化学会の論文

著者

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Takeuchi Toshio

  Department Of Aquatic Biosciences Faculty Of Fisheries Tokyo University Of Fisheries

• Yukawa Yasuhiko

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Inomata Yoshie

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Ouchi Akira

  Department of Chemistry, College of General Education, The University of Tokyo

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