Syntheses and crystal structures of diaquatris(m-hydroxybenzoato)lanthanoid(III) m-hydroxybenzoic acid dihydrate (M=La,Ce,Pr, and Nd), and di-.MU.-(m-hydroxybenzoato)bis{triaquabis(m-hydroxybenzoato)lanthanoid(III)}dihydrate (M=Sm,Gd,Dy,Er, and Yb).

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概要

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• Two types of lanthanoid(III) <I>m</I>-hydroxybenzoates, indicated in the title, have been synthesized, and the crystal and molecular structures of four representative complexes, where M=La (<B>1</B>), Nd (<B>2</B>), Sm (<B>3</B>), and Er (<B>4</B>), were determined by the single-crystal X-ray diffraction method. They are all triclinic, space group P\bar1, and the cell constants are as follows: (<B>1</B>) <I>a</I>=12.351(11), <I>b</I>=15.533(10), <I>c</I>=9.250(4) Å, α=109.86(4), β=101.40(6), γ=62.95(6)°; (<B>2</B>) <I>a</I>=12.287(4), <I>b</I>=15.542(7), <I>c</I>=9.194(3) Å, α=109.64(3), β=101.46(3), γ=62.83(3)°; (<B>3</B>) <I>a</I>=10.580(1), <I>b</I>=12.006(5), <I>c</I>=10.105(2) Å, α=111.14(2), β=90.27(1), γ=97.16(2)°; (<B>4</B>) <I>a</I>=10.586(4), <I>b</I>=11.943(6), <I>c</I>=10.027(5) Å, α=111.11(3), β=90.53(4), γ=97.26(4)°. The final <I>R</I> values obtained were (<B>1</B>) 0.039, (<B>2</B>) 0.038, (<B>3</B>) 0.030, and (<B>4</B>) 0.039. The central metal atoms of both types of complexes are octa-coordinated, and each is in a square-antiprism geometry. In <B>1</B> and <B>2</B>, one free acid molecule is present, and the molecule is hydrogen-bonded to the oxygen atoms of the coordinated water molecules through its carboxyl oxygen atoms. <B>1</B> and <B>2</B> have linear polymeric structure, and each pair of the metal atoms is bridged by a pair of the carboxylate ligands, while <B>3</B> and <B>4</B> have a dimeric structure, where metal atoms are bridged by two carboxylate ligands.

• 公益社団法人 日本化学会の論文

著者

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Takeuchi Toshio

  Department Of Aquatic Biosciences Faculty Of Fisheries Tokyo University Of Fisheries

• Suzuki Yasuo

  Department Of Applied Physics Faculty Of Engineering Fukui University

• Koizumi Yukio

  Department of Applied Biological Science, Tokyo University of Agriculture and Technology

• Ouchi Akira

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Koizumi Yukio

  Department of Industrial Chemistry, Faculty of Engineering, Meiji University

• Sawase Hiroshi

  Department of Industrial Chemistry, Faculty of Engineering, Meiji University

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