The structure and properties of the triaquahexakis(methylthioacetato)dineodymium(III) polymer, (Nd2(C3H5SO2)6(H2O)3)n, and the same-ligand complexes of lanthanoid elements.
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概要
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The crystal and molecular structure of the title complex has been determined by the X-ray diffraction method. The crystal was triclinic, space group P\bar1, <I>a</I>=12.80(1), <I>b</I>=16.65(1), <I>c</I>=8.659(9) Å, α=104.6(1), β=93.7(2), γ=107.5(1)°, <I>Z</I>=2, <I>D</I><SUB>X</SUB>=1.892(3), <I>D</I><SUB>m</SUB>=1.91(2) Mg m<SUP>−3</SUP>, μ(Mo <I>K</I>α)=3.45 mm<SUP>−1</SUP>, and the final <I>R</I> value was 0.051 for 3577 reflections. The coordination number of both neodymium atoms is nine, although the coordinated atoms around one neodymium atom are arrayed in a tri-capped trigonal prism, and those around the other neodymium atom, in a mono-capped tetragonal antiprism. The neodymium atoms are arrayed on a linear chain bridged by the ligand; however, no metal-metal interaction is observed. The corresponding complexes of cerium(III), praseodymium(III), and europium(III) form isomorphous crystals with the title complex, but the complex of lanthanum(III) has the formula of ML<SUB>3</SUB>·4.5H<SUB>2</SUB>O (HL=(methylthio)acetic acid), and the complexes of dysprosium(III) and ytterbium(III), ML<SUB>3</SUB>·2H<SUB>2</SUB>O.
- 公益社団法人 日本化学会の論文
著者
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Shimoi Mamoru
Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo
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Kondo Satoshi
Department Of Chemistry And Chemical Engineering Yamagata University
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Takeuchi Toshio
Department Of Aquatic Biosciences Faculty Of Fisheries Tokyo University Of Fisheries
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Ouchi Akira
Department of Chemistry, College of Arts and Sciences, The University of Tokyo
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