Syntheses and crystal and molecular structure of (hexaaquabis(2-naphthalenesulfonato)lanthanoid(III)) 2-naphthalenesulfonate trihydrate, (Ln(C10H7SO3)2(H2O)6)(C10H7SO3)3H2O(Ln=Pr, Nd, Sm, Eu, Gd, Dy, Er, and Yb).

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概要

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• Eight isomorphous 2-naphthalenesulfonato complexes of lanthanoids(III) (Pr, Nd, Sm, Eu, Gd, Dy, Er, and Yb) were synthesized, and the structures of five of them were determined by the single-crystal X-ray-diffraction method. They are monoclinic, with the space group of P2<SUB>1</SUB>; the cell constants of the Pr<SUP>III</SUP> complex, for example, were <I>a</I>=18.228(8), <I>b</I>=7.498(4), <I>c</I>=14.177(9) Å, β=107.75(4)°, <I>Z</I>=2, and its final <I>R</I> value was 0.043. The unit-cell size of the complex decreases with the increase in the atomic number of the metal atom. The central metal atom is in a square-antiprism geometry and is octa-coordinated with two unidentate 2-naphthalenesulfonato ligands and six water–oxygen atoms. Nonligated oxygen atoms of the sulfonato ions form hydrogen-bonds with the coordinated and lattice water molecules to form a double-layered network along the ab-plane. All the naphthalene rings stand together to form hydrophobic sheets between the hydrogen-bonding networks.

• 公益社団法人 日本化学会の論文

著者

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Suzuki Yasuo

  Department Of Applied Physics Faculty Of Engineering Fukui University

• NAKAMURA Masao

  Department of Applied Physics, The University of Tokyo

• Ohki Yoshiyuki

  Department of Industrial Chemistry, Faculty of Engineering, Meiji University

• Ouchi Akira

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Nakamura Masao

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Nakamura Masao

  Department of Applied Chemistry, Faculty of Engineering, Nagoya University

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