X-ray crystal structures of cis- and trans-dinitrobis(1,4-butanediamine)cobalt(III) nitrates. Conformation of seven-membered chelate rings.

スポンサーリンク

概要

• 論文の詳細を見る

• The structures of <I>cis</I>- and <I>trans</I>-dinitrobis(1,4-butanediamine)cobalt(III) nitrates were determined by the single-crystal X-ray diffraction method. <I>cis</I>-[Co(NO<SUB>2</SUB>)<SUB>2</SUB>(tmd)<SUB>2</SUB>]NO<SUB>3</SUB> (tmd=H<SUB>2</SUB>N(CH<SUB>2</SUB>)<SUB>4</SUB>NH<SUB>2</SUB>) is monoclinic with the space group <I>P</I>2<SUB>1</SUB>⁄<I>a</I>; the cell constants are <I>a</I>=23.878(4), <I>b</I>=8.403(1), <I>c</I>=16.675(3) Å, β=103.24(1)°; <I>Z</I>=8, and the final <I>R</I> value was 0.051. <I>trans</I>-[Co(NO<SUB>2</SUB>)<SUB>2</SUB>(tmd)<SUB>2</SUB>]NO<SUB>3</SUB>·H<SUB>2</SUB>O is triclinic with the space group <I>P</I>\bar1; the cell constants are <I>a</I>=9.753(3), <I>b</I>=13.909(4), <I>c</I>=6.327(1) Å, α=102.07(2), β=91.05(2), γ=87.83(3)°; <I>Z</I>=2, and the final <I>R</I> value was 0.058. Both complexes have a slightly distorted octahedral geometry around the cobalt center. The conformations of the seven-membered chelate rings have twist-chair and chair forms for the cis and trans complexes, respectively.

• 公益社団法人 日本化学会の論文

著者

• Ogino Hiroshi

  Department Of Chemistry Faculty Of Science Tohoku University

• Kanamori Kan

  Department Of Chemistry Faculty Of Science Toyama University

• Shimoi Mamoru

  Department Of Basic Science Graduate School Of Arts And Sciences The University Of Tokyo

• Fujinawa Yuki

  Department of Chemistry, Faculty of Science, Tohoku University

• Kawai Kiyoyasu

  Department of Chemistry, Faculty of Science, Toyama University

関連論文

• Preparation of Silanediyl-Bridged Fe-Fe and Fe-W Dinuclear Complexes. X-Ray Structures of [Cp^*Fe(CO)(μ-CO){μ-Si(H)CHPh_2}(CO)_nMCp](Cp^*=C_5Me_5, Cp=C_5H_5, M=Fe, n=1;M=W, n=2
• Synthesis of New Paramagnetic Heterodinuclear Complexes with Dithiolene Bridging Ligands, (Ph_2C_2S_2)Fe(Cp'Ru)(μ-Ph_2C_2S_2)_2(Cp'= η^5-C_5H_4SiMe_3(Cp^),η^5-C_5Me_5(Cp^*)), by Replacement of a Metal Fragment
• Photon-, Reductant-, and Oxidant-Induced Substitution of a CO Ligand on closo-[Cp^*_2Fe_3S_2(CO)_3](Cp^*=η^5-C_5Me_5)
• Kinetic Study of the Skeletal Inversion in a Tetrairon-Sulfur Cluster {η^5-C_5H_4(SiMe_3)}_4Fe_4S_6
• Synthesis and Structure of[CP^*_3(Ph_2C_2S_2)Fe_4S_5)](BF_4)・Me_2CO: Implication of the Flexible Fe_4S_5 Framework
• Isolation and Structural Characterization of Complexes Formed in the Reactions of [{C_5H_4(SiMe_3)}_2Fe_2(CO)_4] and [{1,3-C_5H_3(SiMe_3)_2}_2Fe_2(CO)_4] with Elemental Sulfur
• Light- and Heat-Induced Geometric Isomerization of Chloro(hydrido)iridium(III) Complex Containing a (2-Phosphinoethyl)silyl Chelate Ligand
• Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate
• Coordinatively Unsaturated Ru(II) Species Ru(xantsil)(CO) : A New Active Catalyst for Oligomerization/Deoligomerization of HSiMe_2SiMe_3 [xantsil = (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]. Isolation of a Stabilized Form of the Silyl(silylene) I
• Dehydrogenative Coupling of Monohydrosilanes Mediated by (2-Phosphinoethyl)silylrhodium(I) Complex
• Synthesis of Tri- and Tetranuclear Metal-Sulfur Clusters by the Reaction of a Trisulfido-Bridged Diiron Complex with W(CO)_5THF
• Stepwise Construction of Clusters Containing Ru_2PtWS_4 and Ru_2Pt_2WS_4 Cores by the Thermal Reaction of [{Cp^*Ru(CO)}_2(WS_4)] (Cp^* = η^5-C_5Me_5) with [PtMe_2(cod)] (cod = 1, 5-cyclooctadiene)
• Synthesis and Structure of the Cationic External Donor - Stabilized Silyleneiron Complex [ Cp(OC)_2 Fe = Si(p - Tol)_2・HMPA] PF_6 by Hydride Abstraction from a (Hydrosilyl)iron Complex
• Formation of Acylyron Complexes CpFe(CO){P(OR')_3}COR' by Reaction of Silyliron Complexes CpFe(CO)_2SiR_3 with Alkylphosphites P(OR')_3
• Reactions of[Chloro(1, 2-phenylenedioxy)silyl]iron Complex Cp(CO)_2FeSiCl(ο-O_2C_6H_4)with Nucleophiles
• Synthesis of the First Iron Complexes Containing 1, 2-Phenylenedioxysilyl Group
• Synthesis and Properties of s-Alkyl-Substituted Silanediyl-Bridged and Silanetriyl-Bridged Diiron Complexes, Cp_2(CO)_2Fe_2(μ-CO)[μ-Si(X)CHR_2]and Cp_2(CO)_2Fe_2(μ-CO)[μ-Si(DMAP)CHR_2]^+I^- (X = H, I; R = Et, Ph; DMAP = 4-(Dimethylamino)pyridine)
• Immunohistochemical study of HLA antigens and lymphocytic infiltrations in advanced vaginel cancer regressed by adjuvant therapy with intratumoral sizofiran
• INFLUENCE OF PTAQUILOSIDE ON THE DEVELOPMENT OF NEWBORN MICE
• Thermal Reaction of Ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III)Complex-Formation of a {(2-Phosphinoethyl)silyl}(ethene)iridium(I)Complex-
• 6-Phosphogluconate Dehydrogenase Is a 45-kDa Antigen Recognized by S4D5,a Monoclonal Antibody Specific to Vanadocytes in the Vanadium-Rich Ascidian Ascidia sydneiensis samea
• A Computational Study on Fluxional Behavior of Group 6 and 7 Transition-metal Complexes of Borane-Lewis Base Adducts
• H-D Exchange Reaction of Borane-Lewis Base Adducts by Rhenium Polyhydride Complexes
• Syntheses of Ruthenium Chlorohydroborato Complexes Cp*Ru (PMe_3)(η^2-BH_3Cl) and Cp*Ru (PMe_3)(η^2-BH_2Cl_2) : Unexpected Chloride Transfer from Ruthenium to Boron
• Synthesis and Structure of the First Base-Stabilized Germylyne-Bridged Dinuclear Complex [Cp_2Fe_2(CO)_3(μ-Ge ^tBu・DMAP]OTf (DMAP =4-(Dimethylamino)pyridine; OTf=CF_3SO_3)
• Synthesis and Properties of Germylese-Bridged Diiron Complexes Using t-Butylgermane as a Precursor of Ligands
• A Vanadium-based Chemical Oscillator
• Synthesis and Novel Spectroscopic Behavior of Octahedral Bis(β-diketonato) Complexes of Paramagnetic Cr(III)and Ni(II)Ions Containing a Nitronyl Nitroxide Radical Chelate
• Synthesis and Reactivity of Triiron Complexes Containing Selenide and Diselenide Bridging Ligands:X-ray Structure of[Cp^*_3Fe_3(μ_2-Se)(μ_3-Se_2)_2](PF_6)(Cp^*=η^5-C_5Me_5)
• Subunit C of the Vacuolar-Type ATPase from the Vanadium-Rich Ascidian, Ascidia sydneiensis samea, Rescued the pH Sensitivity of Yeast vma5 Mutants
• Isolation of cDNAs Encoding Subunits A and B of the Vacuolar-Type ATPase from the Vanadium-Rich Ascidian, Ascidia sydneiensis samea(Physiology)
• A 100-kDa Antigen Recognized by a Newly Prepared Monoclonal Antibody Specific to the Vanadocytes of the Vanadium-Rich Ascidian, Ascidia sydneiensis samea, is Glycogen Phosphorylase(Physiology)
• Glucose-6-Phosphate Dehydrogenase in the Pentose Phosphate Pathway Is Localized in Vanadocytes of the Vanadium-Rich Ascidian, Ascidia sydneiensis samea
• Structures and Properties of Vanadium(III) Complexes with 1,2-Diaminoethane-N,N'-diacetate-N,N'-dipropionate and N, N-Bis(carboxymethyl)-β-alanate
• Syntheses, Characterization, and Properties of Vanadium(III) Complexes Containing Tripodal Tetradentate Ligands with Single Pyridyl Groups
• Preparation and Structure of Dinuclear Vanadium(III) Complex Triply Bridged by Three Different Groups
• Kinetic Study of interconversion between Two Geometrical Isomers of the Methoxy-Bridged Bis(silylene)iron Complex, (η-C_5Me_5)(OC)Fe{(SiMe_2)・・・OMe・・・(SiMeOMe)}
• Synthesis and Crystal Structure of the Novel Dinuclear Vanadium(III) Complex K_2[V_2(dpot)_2]・7H_2O Containing 1, 3-Diamino-2-propanol-N, N, N', N'-tetraacetate (dpot)
• Fluxional Behavior of Alkoxy-Bridged Bis (silylene) ruthenium Complexes Cp*(Me_3P) Ru {SiMe_2 …O (R) …SiMe_2} (R=Me,^tBu) Caused by Rotation of the Silylene Ligands
• Photoreactions of Silyliron (II) Complexes Cp'Fe (CO) _2SiMe_3 (Cp'=η^5-C_5H_5, η^5-C_5Me_5) with Di-p-tolygermane (p-Tol)_2 GeH_2
• Structures and Magnetic Properties of Dinuclear Vanadium(III)Complexes with Alkoxo Bridge
• Syntheses and Structures of Trimethylphosphine-complexed Primary Boryl Complexes of Group 8 Metals, Cp*M(CO)_2(BH_2・PMe_3)(M = Fe, Ru)
• Synthesis, Structure, and Magnetic Properth of a Dinuclear Vanadium(III) Complexes with N-Hydroxyethyliminodiacetate
• Preparation and Structure of Oxo-bridged Dinuclear Vanadium(III) Complex 〔V^_2(L-his)_4(μ-O〕・2H_2O
• Preparation and Structure of the Novel Dinuclear Vanadium(III) Complex Bridged by an Alkoxo Group and a Carboxylato Group
• Synthesis and Characterization of a Peroxovanadium (V) Complex Containing N-Carboxymethylhistidine as a Medel for the Vanadium Haloperoxidase Enzymes
• Reduction of Vanadium(IV) to Vanadium(III) by Cysteine Methyl Ester in Water in the Presence of Amino Polycarboxylates
• Photolysis of CpFe(CO)_2SiMe_2H in the Presence of Methanol. Indirect Evidence for the Transient Formation of a Disileneiron Complex
• Reactivity of Alkoxy-bridged Bis(silylene)iron Complexes
• Iridium-Catalyzed Redistribution of Hydrodisilanes vea a Silyl(silylene)iridium(III)Complex : Synthesis of a Donor-Stabilized Silyl(silylene)iridium(III)Complex
• Generation of Hydrido(silylene)iridium(I)Complex via[1, 2]H Shift from the Silicon Atom to the Iridium(I)Metal Center
• Synthesis of a Donor-Stabilized Silyl(silylene)iron Complex. Direct Observation of 1, 3-Methyl Migration from Silyl to Silylene Ligands
• Synthesis, Structure, and Phosphine-Induced Degradation of a Ruthenapentaborane Cluster with a Sterically Demanding Hexamethylbenzene Ligand
• Dehydrocoupling Reactions of Secondary and Primary Amine-Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)_3], [(η^6-C_6H_6)Cr(CO)_3], and [CpV(CO)_4]
• Syntheses of Diruthenaborane Clusters, [[Cp^*Ru(μ - H)}_2B_3H_7], [{(Cp^*Ru)_2(μ - H)}B_4H_9], and [(Cp^*Ru)_2(μ - H)(PMe_3)(μ - η^4 - B_2H_5)]
• Synthesis, X-ray Structures, and Solution Properties of Vanadium(III) and -(IV) Complexes with N-(2-Hydroxyphenyl)-N-(2-pyridylmethyl)amine
• Preparations, Structures, and Properties of Sulfato-Bridged Dinuclear and Tetranuclear Vanadium(III) Complexes with a Dinucleating Ligand, 2-Oxo-N,N'-bis(2-pyridylmethyl)-1,3-propanediamine-N,N'-diacetate
• Synthesis, Structures and Properties of Vanadium(III) Complexes with the exadentate Ligand, Tetramethlenediamine-N,N,N',N',-tetraacetate, N,N'-Bis(2-pyridylmethyl)-1,2-ethanediamine-N,N'-diacetate, and N,N'-Bis(2-pyridylmethyl)-1,3-propanediamine-N,N'-dia
• Reaction of Silyl(carbonyl)iron Complexes with LiAlH_4 Giving Methylsilanes : Reduction of a Carbonyl Ligand and Coupling with a Silyl Group
• Sarcoidosis Complicated with Major Pulmonary Artery Obstruction and Stenosis
• The structure of diaquatetrakis(thiocyanato)cobalt(II)mercury(II)-N-methyl-2-pyrrolidone(1/2), CoHg(SCN)4(H2O)22(C3H6CONCH3).
• Polarographic Determination of the Formation Constant of Sulfatonickel(II) Complex
• The Raman spectral study on the solution structure of iron(III)-edta complexes.
• Structural studies of thiocyanato and isothiocyanato cobalt(III) complexes ligating diamine-N,N'-polycarboxylates.
• Metal complexes of EDTA and its related compounds. II. Geometric isomers of [Co(X)(trimethylenediamine-N,N,N'-triacetate)] complexes with X=H2O, NH3, Cl-, and CN-.
• The structure of dichloro(4-hydroxy-L-proline)cadmium(II).
• Kinetics and mechanisms of the reduction of cobalt(III) complexes by the chromium(II) complex ligating N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetate.
• X-ray crystal structures of cis- and trans-dinitrobis(1,4-butanediamine)cobalt(III) nitrates. Conformation of seven-membered chelate rings.
• A finite element approach to the two-dimensional vibrational Schroedinger equation and its application to the hydrogen bond.
• A resonance Raman study of polymeric thiolato cobalt (III) complexes: Possible bridging modes.
• Syntheses and characterizations of .MU.-dicarboxylato-bis(pentaamminecobalt(III)) complexes.
• Syntheses and properties of some trimethylantimony(V) complexes of dithiocarbonate derivatives.
• A Kinetic Study of the Ligand Substitution Reaction of Tetramethylenediaminetetraacetatocobaltate(II) with Trimethylenediaminetetraacetate
• Kinetic Studies of Oxygen Atom Transfer Reactions between Various cis-Dioxobis(dithiocarbamato)molybdenum(VI) Complexes and Triphenylphosphine.
• The structure of diaquatris((methylthio)acetato)ytterbium(III), (Yb(CH3SCH2CO2)3(H2O)2)n.
• The structure and properties of the triaquahexakis(methylthioacetato)dineodymium(III) polymer, (Nd2(C3H5SO2)6(H2O)3)n, and the same-ligand complexes of lanthanoid elements.
• The structure and properties of (.ETA.-cyclopentadienyl)(O-methyl dithiocarbonato)(triphenylphosphine)nickel(II).
• Syntheses and crystal and molecular structure of (hexaaquabis(2-naphthalenesulfonato)lanthanoid(III)) 2-naphthalenesulfonate trihydrate, (Ln(C10H7SO3)2(H2O)6)(C10H7SO3)3H2O(Ln=Pr, Nd, Sm, Eu, Gd, Dy, Er, and Yb).
• First synthesis of (Fe4(.ETA.5-C5H5)4S4)(PF6)3 and improved syntheses of (Fe4(.ETA.5-C5H5)4S4)(PF6)n (n=1,2).
• The structure of (hydrogen ethylenediaminetetraacetato)antimony(III) dihydrate Sb(C10H13N2O8)2H2O.
• The crystal and molecular structure of bis(4-methylpyridine)-bis(thiocyanato)cadmium(II) in polymeric form, (Cd(SCN)2(CH3C5H4N)2)n.
• The crystal and molecular structure of tetrakisthiocyanatobis(triphenylphosphine)cobalt(II)mercury(II) in dimer form, (CoHg(SCN)4{(C6H5)3P}2)2.
• Syntheses, structure, and properties of several bis(O,O'-dialkyl dithiophosphato)cobalt(II)adducts.
• Structure and properties of diaquabis(ethylthioacetato)copper(II), (Cu(C4H7SO2)2(H2O)2).
• The synthesis, and the crystal and molecular structure of (diaquatetrakis(thiocyanato)cobalt(II)mercury(II))-N,N-dimethylacetamide (1/2), CoHg(SCN)4(H2O)22{CH3CON(CH3)2}.
• Kinetics of the ligand substitution reactions of a labilized ruthenium(III) complex, (Ru{N'-(2-hydroxyethyl)ethylenediamine-N, N, N'-triacetate}(H2O)).
• The Raman spectra of cobalt(III) complexes. V. Differentiation between two cis(a) isomers of (Coa2(NH3)2(en)) type complexes (a=NO2- and CN-).
• The preparation and spectral properties of trans(CN)-(Co(CN)2(tmdda))- and -(Co(CN)2(L-ala)2)- complexes.
• The structure of diaquatris(1,1,1-trifluoro-2,4-pentanedionato)neodymium(III)-acetone (1/1).
• Electronic spectra of square-planar bis(biuretato) cobaltate (III)-type complexes.
• The Raman spectra of cobalt(III) complexes. IV. Differentiation between cis and trans isomers of bis(trimethylenediamine)cobalt(III) complexes.
• The Raman spectra of cobalt(III) complexes. I. Differentiation between cis and trans isomers of bis(ethylenediamine)cobalt(III) complexes.
• タイトル無し
• Raman spectra of cobalt(III) complexes. II. Nitroammine series of cobalt(III) complexes.
• The crystal and molecular structure of the hydrated light lanthanoid(III) chloroacetates, [{M(ClCH2CO2)3}3(H2O)5]n, (M=La, Pr, Nd, and Eu)
• The synthesis and the crystal and molecular structure of (tris(dibutyl sulfoxide)bis(O,O'-diisopropyl dithiophosphato)neodymium(III))(tetrakis(O,O'-diisopropyl dithiophosphato)neodymium(III)) (Nd{(C3H7O)2PS2}2{(C4H9)2SO}3)(Nd{(C3H7O)2PS2}4).
• A stoichiometric investigation of the reaction of nitrosylpentaamminechromium(2+) with ethylenediaminetetraacetatoaquachromate(II).
• Syntheses and crystal structures of diaquatris(m-hydroxybenzoato)lanthanoid(III) m-hydroxybenzoic acid dihydrate (M=La,Ce,Pr, and Nd), and di-.MU.-(m-hydroxybenzoato)bis{triaquabis(m-hydroxybenzoato)lanthanoid(III)}dihydrate (M=Sm,Gd,Dy,Er, and Yb).

もっと見る 閉じる

スポンサーリンク