Binuclear Metal Complexes. III. Preparation and Properties of Mononuclear and Binuclear Copper(II) and Nickel(II) Complexes of New Macrocycles and Their Related Ligands

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概要

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• The syntheses and properties of copper(II) and nickel(II) complexes of <I>N</I>,<I>N</I>′-alkylenebis(3-formyl-5-methylsalicylaldimine (alkylene=ethylene, propylene, or trimethylene) are described. By the reaction of these complexes with other alkylenediamines (ethylenediamine or trimethylenediamine), mononuclear copper(II) and nickel(II) complexes of new N<SUB>4</SUB>O<SUB>2</SUB>-type macrocycles have been synthesized. These complexes react with additional copper(II) or nickel(II) ions to form binuclear copper(II) or nickel(II) complexes. The geometries and properties of these new complexes are discussed.

• 公益社団法人 日本化学会の論文

著者

• Okawa Hisashi

  Department Of Chemistry Faculty Of Science Kyushu University

• Kida Sigeo

  Department of Chemistry Wakayama University

関連論文

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