Synthesis and characterization of a chloro-bridged binuclear iron(III) complex.
スポンサーリンク
概要
- 論文の詳細を見る
A chloro-bridged binuclear iron(III)complex [Fe<SUB>2</SUB>ClL](BPh<SUB>4</SUB>), where [H<SUB>4</SUB>L] and BPh<SUB>4</SUB><SUP>−</SUP> denote <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetrakis(3-salicylideneaminopropyl)ethylenediamine and tetraphenylborate, respectively, was prepared and characterized by elemental analysis, electrical conductivity, Mössbauer spectrum, and cryomagnetic data. The magnetic susceptibility data of the complex was analyzed by the Heisenberg model on the basis of a binuclear structure \hat<I>H</I>=−2<I>J</I>\hat<I>S</I><SUB>1</SUB>·\hat<I>S</I><SUB>2</SUB> (<I>S</I><SUB>1</SUB>=<I>S</I><SUB>2</SUB>=5⁄2), leading to an antiferromagnetic interaction parameter of <I>J</I>=−3.9 cm<SUP>−1</SUP>.
- 公益社団法人 日本化学会の論文
著者
-
Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
-
Maeda Yonezo
Department Of Chemistry And Physics Graduate School Of Sciences Kyushu University
-
Matsumoto Naohide
Department Of Chemistry Faculty Of Science Kumamoto University
-
Ohyoshi Akira
Department Of Applied Chemistry Faculty Of Engineering Kumamoto University
-
Yoshimura Chikako
Department of Synthetic Chemistry, Faculty of Engineering, Kumamoto University
-
Matsumoto Naohide
Department of Synthetic Chemistry, Faculty of Engineering, Kumamoto University
関連論文
- Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers
- Preparation of a Carboxylate-binding Mononuclear Iron(II) (-)-Sparteine Complex with Structural Distortion and Its Reaction with Oxidants
- Synthesis and Electrochemical Properties of Tetranuclear Di-μ-oxo-bis[di-μ-phenolatodiiron(III)] Complexes
- Dinuclear Mn(II), Ni(II), and Zn(II) Complexes Bridged by Bis(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase
- μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal = Fe, Co, Ni, Cu, Zn) Complexes with Low-Spin Co(II) : Synthesis, Structures, and Magnetism
- Novel Cerium(III)-(R)-BNP Complex as a Storable Chiral Lewis Acid Catalyst for the Enantioselective Hetero-Diels-Alder Reaction
- Synthesis, Structure and Magnetic Property of a Tetranuclear Iron(III) Complex of "Face-to-Face" Type
- Synthesis and Structures of Novel Discrete Ni(II)-Ln(III) Heterodinuclear Complexes (Ln=Gd or Lu)
- A Novel Discrete d-f Heterobinuclear Complex Designed from Tetrahedrally Distorted [Cu (salabza)] (H_2salabza : N,N'-Bis (salicylidene)-2-aminobenzylamine) and [Gd (hfac)_3]
- Copper(II)-Lanthanide(III) Complexes of Symmetric Dinucleating Macrocycle with Two Phenolate Bridges
- Indications and Limitations of the Wolff-Parkinson-White Syndrome : SYMPOSIUM ON SURGICAL TREATMENT OF ARRHYTHMIAS
- Pressure-Stabilized Low-Spin State for Binuclear Iron(III) Spin-Crossover Compounds
- Valence States and Structure of Mixed-Valence Dinuclear Iron(II,III) Complexes [Fe_2(2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-menthyl-phenol)(L)_2](BF_4)_2
- Effects of the Encapsulation of Alkali Ions into Iron(III) Complexes with a Macrocyclic Ring on Magnetic Properties
- Hysteresis Loops in Dielectric Properties of the Thermochromic Copper(II) Compounds
- Study of Intermolecular Interaction for the Spin-Crossover Iron(II) Compounds
- Characterization of a Fluoride-bridged Mixed-valent Tetrairon(II,II,III,III) Complex
- Structures of Bimetallic Assemblies Derived from a Macrocyclic Dinuclear Copper(II) Complex and [Cr(ox)3]〔3-〕 or [Co(CN)6]〔3-〕
- Electrochemical Studies for Interaction between [Cu(salen)] and La(III) Ion in N,N-Dimethylformamide
- New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring
- Di(phenoxo)-bridged Dinuclear Mn_2(II,II) and Mn_2(II,III) Complexes of Macrocyclic Ligands : Structure, Properties, and Catalase-Like Function :
- Template Synthesis and Structure of a Dilead(II) Complex of a Macrocycle with N_8O_2 Donor Set
- Dinuclear Copper(II) Complexes of a Macrocyclic Compartmental Ligand in Two Isomeric Forms. Exogenous Ion Effect upon Ligand Isomerism
- Synthesis of a Tetracopper Assembly Complex Comprised of One Macrocyclic Dinuclear Copper Unit and Two Mononuclear Copper Units : Intramolecular Electron Transfer Relevant to Multicopper Oxidase
- Macrocyclic Heterodinuclear Co^M^ (M = Ni, Zn) Complexes. Ferromagnetic Interaction and EPR of Co^Ni (S_ = 1/2, S_ = 1) Complex
- Tetranuclear Ni^ and Dinuclear Mn^ Complexes Derived from a New Macrocyclic Ligand with Four Endogenous Phenolic Groups
- Hydrolytic Activity of A Fe^Zn^ Complex toward Di(p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiestelase
- μ-Hydroxo-μ-phenolato Dinuclear Zinc(II) and Nickel(II) Complexes Derived from Dinucleating Compartmental Ligands of "End-off" Type : Synthesis, Structures, and Properties
- Template Synthesis of Copper Complexes of Dinucleating and Tetranucleating Macrocyclic Ligands
- Hydrolytic Activity of Zn^Zn^ and Zn^Ba^ Complexes toward Tri (p-nitrophenyl) Phosphate and Di (p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiesterase
- Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Network and Bulk Structures
- Synthesis and Characterization of Triple-decker Sandwich Dinuclear La(III)and Lu(III)Complexes of 2, 3, 9, 10, 16, 17, 23, 24-Octabutoxyphthalocyanine
- Syntheses and Structural Characterization of Dinuclear and Trinuclear Iron(II) Complexes of Tridentate Thiolic Ligands with an NNS Donor Set
- Metal-Complex Ferrimagnets with the Formula {NBu_4[M(II)Fe(III)(ox)_3]}_(NBu_4^+=Tetra(n-butyl)ammonium Ion, ox^=Oxalate Ion, M=Fe^, Ni^)
- Synthesis and Characterization of a Tetrahedral and Octahedral Cobalt(II) Alternate Chain Complex
- Magneto-optical Properties of Two-dimensional Cyanide-Bridged M^Ni^ Bimetallic Assemblies (M=Fe,Co)
- A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation
- Structures and Magnetism of Cyanide-Bridged Bimetallic Compounds : Design of Complex-Based Magnetic Materials
- A Rare μ_3η^1, η^2 Perolxo Bridge between Two Co^Pb^ Dinuclear Units and Hydrolytic Conversion into a Hydroxo-Bridged Co^Pb^ Complex
- Hydrolytic Function of a Hydroxo-Zn^Pb^ Complex toward Tris-p-nitrophenyl Phosphate:A Functional Model of Heterobimetallic Phosphatases
- Heterodinuclear M^Ni^ (M = Co, Ni, Cu, Zn) Complexes of a Macrocyclic Compartmental Ligand. Anomalous EPR of Cu^Ni^ Complex by Coordination of 1-Methylimidazole
- A Geometrically Asymmetric Dinuclear Copper(II) Complex Derived from A New Unsymmetric 'End-off' Compartmental Ligand
- Template Synthesis of Phenol-based Heterodinucleating Macrocycles with Dissimilar N(amine)_2O_2 and N(imine)_2O_2 Metal-binding Sites
- Reversible Oxygenation of a μ-Acetato-di (μ-phenoxo) dicobalt (II) Core Complex and Crystal Structure of Its Oxygenated Complex
- Dinuclear Zinc Complexes of Phenol-Based "End-off" Compartmental Ligands: Synthesis, Structures and Phosphatase-Like Activity
- Magnetic Susceptibility of Some Mixed-Metal Compounds : NBu_4Zn(II)_xFe(II)_[Fe(III)(ox)_3]
- Isomerization of a Linear Pentamine, 1,4,7,10,13-Pentaazatridecane, to a Branched Form, 4-(Aminoethyl)-1,4,7,10-tetraazadecane, on a Schiff-base Copper Complex Relevant to Multi-copper Enzymes
- Synthesis and Ferromagnetic Spin-Coupling of Imidazolate-Bridged 3d-4d Cu(II)-Ru(III) Binuclear Complex
- Template Synthesis of Masrocyclic Dinuclear Cu^ Complexes and Conversion into Mononuclear Complexes by Site-Selective Copper Elimination
- A Macrocyclic Co(II)Pb(II)Complex : Neighboring Pb(II)Effect upon Reversible Superoxo-cobalt Complex Formation in Solid State
- Dioxygen Oxidation of Coordinated Nitrosyl to Nitro on Dmf-Bridged Dinuclear CoPb Complex
- Crystal structure of (chloro(tris((1-ethyl-1H-benzimidazol-2-yl)-methyl)amine)zinc(II)) tetraphenylborate acetone.
- Crystal structure and magnetic property of cubane tetranuclear copper(II) complex with ferromagnetic coupling.
- Specific binding of substrates containing nitrogen and oxygen donor groups to copper(II)-gadolinium(III) hetero-metal center.
- Crystal and molecular structure of a binuclear copper(II) complex with 1,2,3,4-tetrakis(salicylideneamino)-2,3-dimethylbutane.
- Binuclear metal complexes. XLIII. Magnetic, spectroscopic, and electrochemical studies on hetero-metal binuclear complexes of N,N'-bis(3-carboxysalicylidene)-1,1-dibenzylethylenediamine.
- Catalytic function of cobalt(III) complexes with N,N'-disalicyl-ideneethylenediamine on oxygenation of t-butylphenols.
- Synthesis and characterization of a chloro-bridged binuclear iron(III) complex.
- Ferromagnetic Spin-Coupling between Gadolinium(III) and Copper(II) Ions in Discrete Binuclear Gd(III)-Cu(II) Complexes.
- Nocovalent interactions in metal complexes. 14 Proton NMR spectroscopic investigation on stereoselectivity in cobalt(III) complexes of various 3-substituted 1-phenyl-1,3-propanediones.
- Binuclear Metal Complexes. X. Preparation and Magnetism of Mononuclear and Binuclear Copper(II) Complexes of Schiff Bases Derived from 4,6-Diacetylresorcine and Polyamines
- Noncovalent interactions in metal complexes. VIII. Syntheses, properties, and stereoselectivities of lanthanoid complexes with 1-l-menthyloxy-3-benzoylacetone.
- Binuclear metal complexes. LI. Synthesis and characterization of the tetrachloro-o-benzoquinone adducts of binuclear iron(II) complexes with 2-(salicylideneamino)phenol and its substituted homologs.
- Synthesis and magnetic property of binuclear oxovanadium(IV) complex of 2,6-diformyl-4-methylphenol bis(benzoylhydrazone).
- Synthesis and characterization of a new quinquedentate ligand consisting of salen skeleton and phenolic tail capable of axial coordination and its metal complexes.
- Binuclear metal complexes. 58 Synthesis and properties of mixed-valence diiron(III,IV) complexes of salen analogs with pendant thioether group.
- High stereoselectivity of tris(4-(l-menthyloxy)-1-(p-tolyl)-1,3-butandionato)lanthanoid(III).
- Binuclear metal complexes. XXIV. Synthesis and magnetism of binuclear cobalt(II) complexes in mixed-spin state.
- Binuclear metal complexes. XXXI. Synthesis and magnetic property of binuclear manganese (III) complexes with 3-salicylideneamino-1-propanol and its homologues.
- Binuclear metal complexes. XLII. Manganese(IV) complexes synthesized by oxidation of binuclear manganese(II) complexes of 2-(salicylideneamino)phenols with tetrachloro-o-benzoquinone.
- Binuclear metal complexes. XLV. Synthesis and magnetic, spectral, and electrochemical studies of strati-bis copper(II) complexes of some Schiff bases derived from primary tetraamines and salicylaldehydes.
- Binuclear metal complexes. IL. Synthesis, ESR, and electrochemical properties of strati-bis copper(II)-nickel(II) complexes.
- Macro Chelate Rings. III. Syntheses and Configurations of Complexes of New Ligands, 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)-diphenyl Ether and 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)diphenylamine
- Macro Chelate Rings. II. Syntheses and Properties of 2,7-Dimethyl-4,5-bis(salicylideneaminomethyl)xanthone as a Quadridentate Chelating Agent and Its Metal Complexes
- Binuclear Metal Complexes. IX. Syntheses and Magnetic Properties of Copper(II) and Nickel(II) Complexes of Schiff Bases Derived from 3-Formylsalicylic Acid and Alkyl Amines
- Binuclear metal complexes. XXIII. Molecular structure of a hetero-metal binuclear complex, CuCo(fsaen) 3H2O(C18H18N2O9CoCu).
- Substituent effect on stereoselectivity for cobalt(III), chromium(III), and manganese(III) complexes of ring-substituted 1-l-menthyloxy-3-benzoylacetones.
- Synthesis, spectral and magnetic properties and crystal structures of alkoxo-oxygen coordinated copper(II) complexes of N,N'-disubstituted malonamide and oxamide derivatives.
- Binuclear Metal Complexes. XIII. Syntheses and Magnetic Properties of Thiocyanato-Bridged Binuclear Copper(II) Complexes
- Synthesis and characterization of copper(II) and nikel(II) complexes of 1,5-diamino-3-pentanol and its derivatives.
- Stereoselectivity in Diastereomeric Tetrahedral Metal(II) Complexes of Chiral Salicylideneamines: Crystal Structure and Molecular Mechanics Calculation of Bis(N-(l-menthyl)salicylideneaminato)cobalt(II).
- Copper(II)-lanthanoid(III) complexes of binucleating ligands derived from 3-formylsalicylic acid and diamines.
- Binuclear metal complexes. XXXIX. Synthesis and properties of binuclear copper(II) complexes with (2-(2-pyridyl)ethylamino)-alkanols and (2-(2-pyridyl)ethylthio)alkanols.
- Binuclear metal complexes. XLI. Crystal structure and unusual magnetic property of isothiocyanato{2-(2-(dimethylamino)ethylthio)ethanolato}copper(II).
- Antiferromagnetic spin-exchange interaction in mixed-spin trinuclear cobalt(II) complexes with quadridentate schiff bases.
- Non-covalent interactions in metal complexes. II. Induction of asymmetry in cobalt(III) complexes with amino acid-schiff bases. Importance of CH .PI.-interaction in determining configuration of complexes.
- Synthesis and magnetism of trinuclear copper(II) complexes with a salen-like Schiff base and a tertiary diamine.
- Copper(II)-Rare Earth(III)(Ln=La,Gd,Lu) Binuclear Complexes of Bis(2-(3-carboxysalicylidene)aminoethyl)amine: Characterization and Specific Binding of Amino Alcohols.
- Binuclear metal complexes. XLIV. Crystal structures and magnetic properties of alkoxo-oxygen bridged binuclear copper(II) complexes with 2-(2-(dialkylamino)ethylthio)ethanol.
- Syntheses and configurations of copper(II) and nickel(II) complexes of trans-1,2-dicyano-1,2-cyclohexanediamine.
- Template synthesis and crystal structure of a dilead(II) complex of a macrocycle with N4O2 donor set.
- Synthesis and characterization of imidazolate-bridged copper(II) complexes of triangular skeleton.
- Synthesis, magnetic property, and crystal structure of imidazolate-bridged manganese(III)-copper(II) dinuclear complex.
- Binuclear Metal Complexes. XI. Substituent Effect upon Magnetisms of Binuclear Oxovanadium(IV) and Copper(II) Complexes of the Schiff Bases, 2,6-Bis[N-(2-hydroxy-5-substituted-phenyl)iminomethyl]-4-methylphenol
- Binuclear metal complexes XXXV. Synthesis and magnetism of binuclear copper(II) complexes with 3-(2-(dialkylamino)ethylthio)-1-propanols.
- Binuclear Copper(II) Complexes Derived From 3-Formyl-5-methyIsaIicyIaldehyde and Glycine
- Binuclear Metal Complexes. VII. Preparation and Properties of Binuclear Copper(II) and Nickel(II) Complexes of Hydrogen-bridged Macrocycles
- Binuclear Metal Complexes. III. Preparation and Properties of Mononuclear and Binuclear Copper(II) and Nickel(II) Complexes of New Macrocycles and Their Related Ligands
- Binuclear metal complexes. XXXVII. Crystal and molecular structure of a binuclear manganese(III) complex bridged by two alkoxo oxygens and two bidentate acetate ions.
- Dinuclear cobalt(II), iron(II), and manganese(II), and trinuclear manganese(II) complexes with tridentate ligands of NNS-donor set derived from 2-aminoethanethiol.