Macro Chelate Rings. III. Syntheses and Configurations of Complexes of New Ligands, 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)-diphenyl Ether and 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)diphenylamine
スポンサーリンク
概要
- 論文の詳細を見る
Two quadridentate chelating agents, 4,4′-dimethyl-2,2′-bis(salicylideneaminomethyl)diphenyl ether and 4,4′-dimethyl-2,2′-bis(salicylideneaminoinethyl)diphenylarnine, which may form a metal complex with a ten-membered chelate ring, were synthesized by a sequence of steps. The cobalt(II), nickel(II), copper(II), and zinc(II) complexes could be derived from the ligands. Their configurations around the central divalent metal ion were explored on the basis of the absorption in the ligand field in a solution. A tetrahedral configuration for cobalt(II) complexes as well as the zinc(II) complexes, and a pseudo-tetrahedral configuration for the nickel(II) and copper(II) complexes, were concluded.
- 公益社団法人 日本化学会の論文
著者
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Inazu Takahiko
Department Of Chemistry Faculty Of Science Kyushu University
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Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
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Koyama Hiroyuki
Department Of Biotechnology Faculty Of Agriculture Gifu University
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Yoshino Tamotsu
Department of Chemistry, Faculty of Science, Kyushu University
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