Synthesis and magnetic property of binuclear oxovanadium(IV) complex of 2,6-diformyl-4-methylphenol bis(benzoylhydrazone).
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概要
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Binuclear oxovanadium(IV) complex, [(VO)<SUB>2</SUB>L(OCH<SUB>3</SUB>)], has been synthesized, where H<SUB>3</SUB>L denotes 2,6-diformyl-4-methylphenol bis(benzoylhydrazone). Two metal ions are bridged by the phenolic oxygen of L<SUP>3</SUP> and a methoxide oxygen. Cryomagnetic measurements (80–300 K) indicated the operation of an antiferromagnetic spin-exchange interaction (<I>J</I>=−191.3 cm<SUP>−1</SUP>) between the oxovanadium(IV) ions.
- 公益社団法人 日本化学会の論文
著者
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Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
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Matsumoto Naohide
Department Of Chemistry Faculty Of Science Kumamoto University
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Kida Sigeo
Department of Chemistry Wakayama University
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SAKAMOTO Masatomi
Department of Applied Chemistry, Faculty of Engineering, Ehime University
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Kida Sigeo
Department of Chemistry, Faculty of Science, Kyushu University
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Itose Shoichi
Department of Industrial Chemistry, Faculty of Engineering, Ehime University
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Ishimori Tomitaro
Department of Industrial Chemistry, Faculty of Engineering, Ehime University
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SAKAMOTO Masatomi
Department of Industrial Chemistry, Faculty of Engineering, Ehime University
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Matsumoto Naohide
Department of Applied Chemistry, Faculty of Engineering, Kumamoto University
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