Specific binding of substrates containing nitrogen and oxygen donor groups to copper(II)-gadolinium(III) hetero-metal center.

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概要

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• Substrate binding to the Cu(II)–Gd(III) heterometal complex of <I>N</I>,<I>N</I>′-bis(3-carboxysalicylidene)ethylenediamine was studied in <I>N</I>,<I>N</I>-dimethylformamide. It was suggested that substrates with a nitrogenous and an oxygenous groups (amino alcohols, 8-quinolinol, amino acids, and amino acid esters) were specifically bound to the Cu(II)–Gd(III) center, with the nitrogen to the copper and with the oxygen to the gadolinium.

• 公益社団法人 日本化学会の論文

著者

• Okawa Hisashi

  Department Of Chemistry Faculty Of Science Kyushu University

• SAKAMOTO Masatomi

  Department of Applied Chemistry, Faculty of Engineering, Ehime University

• Ishimori Tomitaro

  Department of Industrial Chemistry, Faculty of Engineering, Ehime University

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