Synthesis, spectral and magnetic properties and crystal structures of alkoxo-oxygen coordinated copper(II) complexes of N,N'-disubstituted malonamide and oxamide derivatives.
スポンサーリンク
概要
- 論文の詳細を見る
1:1 Copper(II) complexes with <I>N</I>,<I>N</I>′-bis(2-hydroxyethyl)malonamide (abbreviated as H<SUB>4</SUB>maae), MCu(maae) (M=Ca, Sr, Ba), and 2:1 copper(II) complexes with <I>N</I>,<I>N</I>′-bis(5-amino-3-hydroxypentyl)malonamide and <I>N</I>,<I>N</I>′-bis(5-amino-3-hydroxypentyl)oxamide (abbreviated as H<SUB>4</SUB>madpl and H<SUB>4</SUB>oxdpl, respectively),[Cu<SUB>2</SUB>(madpl)]·3H<SUB>2</SUB>O and [Cu<SUB>2</SUB>(oxdpl)]·2H<SUB>2</SUB>O, were prepared and characterized by elemental analyses, infrared and electronic spectra, and magnetic susceptibilities. The 2:1 complexes exhibit a band at 23.3–27.0×10<SUP>3</SUP> cm<SUP>−1</SUP> characteristic of alkoxo-oxygen bridged structure and show a very strong antiferromagnetic interaction, whereas the 1:1 complexes show no such band and their magnetic moments fall in the range of those for ordinary mononuclear copper(II) complexes. The crystal structures of [Cu<SUB>2</SUB>(madpl)]·3H<SUB>2</SUB>O and BaCu(maae)·7H<SUB>2</SUB>O were determined by the single-crystal X-ray diffraction method. The structure of [Cu<SUB>2</SUB>(madpl)]·3H<SUB>2</SUB>O consists of alkoxo-oxygen bridged binuclear molecules, where madpl<SUP>4−</SUP> functions as a sexadentate binucleating ligand with an N<SUB>2</SUB>O<SUB>2</SUB>N<SUB>2</SUB> donor set. In BaCu(maae)·7H<SUB>2</SUB>O, the basic unit is a hetero-metal tetranuclear entity (H<SUB>2</SUB>O)<SUB>2</SUB>{Ba(H<SUB>2</SUB>O)<SUB>4</SUB>Cu-(maae)}<SUB>2</SUB> in which the two Ba<SUP>2+</SUP> are linked sharing two H<SUB>2</SUB>O and are also bound to alkoxo oxygens of Cu(maae)<SUP>2−</SUP>. On the basis of the crystal structures, their spectral properties were discussed.
- 公益社団法人 日本化学会の論文
著者
-
Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
-
Mikuriya Masahiro
Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S
-
Kida Sigeo
Department of Chemistry Wakayama University
-
Toki Takashi
Department of Chemistry, Faculty of Science, Kyushu University 33
-
Murase Ichiro
Laboratory of Chemistry, College of General Education, Kyushu University
関連論文
- Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers
- Synthesis and Electrochemical Properties of Tetranuclear Di-μ-oxo-bis[di-μ-phenolatodiiron(III)] Complexes
- Dinuclear Mn(II), Ni(II), and Zn(II) Complexes Bridged by Bis(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase
- μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal = Fe, Co, Ni, Cu, Zn) Complexes with Low-Spin Co(II) : Synthesis, Structures, and Magnetism
- Novel Cerium(III)-(R)-BNP Complex as a Storable Chiral Lewis Acid Catalyst for the Enantioselective Hetero-Diels-Alder Reaction
- Synthesis, Structure and Magnetic Property of a Tetranuclear Iron(III) Complex of "Face-to-Face" Type
- Synthesis and Structures of Novel Discrete Ni(II)-Ln(III) Heterodinuclear Complexes (Ln=Gd or Lu)
- A Novel Discrete d-f Heterobinuclear Complex Designed from Tetrahedrally Distorted [Cu (salabza)] (H_2salabza : N,N'-Bis (salicylidene)-2-aminobenzylamine) and [Gd (hfac)_3]
- Copper(II)-Lanthanide(III) Complexes of Symmetric Dinucleating Macrocycle with Two Phenolate Bridges
- Polymer Complexes of Rhodium(II) Trifluoroacetamidate with Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicy-clo[2.2.2]octane
- Dinuclear Copper(II) Complexes of Free Radical Carboxylic Acids
- Antiferromagnetic Adducts of Copper(II) Propionate with Pyridyl Nitronyl Nitroxides
- Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4, 4'-Bipyridine, 1, 4-Diazabicyclo[2. 2. 2]octane, Triethylamine, and Pyridine
- Synthesis, X-Ray Structures, and Magnetic Properties of [Cu_2(piv)_4(Et_3N)_2] and [Cu_6(piv)_6(EtO)_6] (Hpiv = Pivalic Acid ) : Role of Base for Dinuclear Adduct and Oligonuclear Formation
- Self-assembly of Mixed-valent Ruthenium(II, III) Pivalate and Octacyanotungstate(V) Building Blocks
- Characterization of a Fluoride-bridged Mixed-valent Tetrairon(II,II,III,III) Complex
- Structures of Bimetallic Assemblies Derived from a Macrocyclic Dinuclear Copper(II) Complex and [Cr(ox)3]〔3-〕 or [Co(CN)6]〔3-〕
- A Polymer Complex [Cu(O_2CC_6F_5)_2-(pyz)]_n Formed from Copper(II) Pentafluorobenzoate and Pyrazine
- Electrochemical Studies for Interaction between [Cu(salen)] and La(III) Ion in N,N-Dimethylformamide
- New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring
- Di(phenoxo)-bridged Dinuclear Mn_2(II,II) and Mn_2(II,III) Complexes of Macrocyclic Ligands : Structure, Properties, and Catalase-Like Function :
- Template Synthesis and Structure of a Dilead(II) Complex of a Macrocycle with N_8O_2 Donor Set
- Dinuclear Copper(II) Complexes of a Macrocyclic Compartmental Ligand in Two Isomeric Forms. Exogenous Ion Effect upon Ligand Isomerism
- Synthesis of a Tetracopper Assembly Complex Comprised of One Macrocyclic Dinuclear Copper Unit and Two Mononuclear Copper Units : Intramolecular Electron Transfer Relevant to Multicopper Oxidase
- Macrocyclic Heterodinuclear Co^M^ (M = Ni, Zn) Complexes. Ferromagnetic Interaction and EPR of Co^Ni (S_ = 1/2, S_ = 1) Complex
- Tetranuclear Ni^ and Dinuclear Mn^ Complexes Derived from a New Macrocyclic Ligand with Four Endogenous Phenolic Groups
- Hydrolytic Activity of A Fe^Zn^ Complex toward Di(p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiestelase
- μ-Hydroxo-μ-phenolato Dinuclear Zinc(II) and Nickel(II) Complexes Derived from Dinucleating Compartmental Ligands of "End-off" Type : Synthesis, Structures, and Properties
- Template Synthesis of Copper Complexes of Dinucleating and Tetranucleating Macrocyclic Ligands
- Hydrolytic Activity of Zn^Zn^ and Zn^Ba^ Complexes toward Tri (p-nitrophenyl) Phosphate and Di (p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiesterase
- Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Network and Bulk Structures
- Synthesis and Characterization of Triple-decker Sandwich Dinuclear La(III)and Lu(III)Complexes of 2, 3, 9, 10, 16, 17, 23, 24-Octabutoxyphthalocyanine
- Syntheses and Structural Characterization of Dinuclear and Trinuclear Iron(II) Complexes of Tridentate Thiolic Ligands with an NNS Donor Set
- Metal-Complex Ferrimagnets with the Formula {NBu_4[M(II)Fe(III)(ox)_3]}_(NBu_4^+=Tetra(n-butyl)ammonium Ion, ox^=Oxalate Ion, M=Fe^, Ni^)
- Synthesis and Characterization of a Tetrahedral and Octahedral Cobalt(II) Alternate Chain Complex
- Magneto-optical Properties of Two-dimensional Cyanide-Bridged M^Ni^ Bimetallic Assemblies (M=Fe,Co)
- A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation
- Structures and Magnetism of Cyanide-Bridged Bimetallic Compounds : Design of Complex-Based Magnetic Materials
- A Rare μ_3η^1, η^2 Perolxo Bridge between Two Co^Pb^ Dinuclear Units and Hydrolytic Conversion into a Hydroxo-Bridged Co^Pb^ Complex
- Hydrolytic Function of a Hydroxo-Zn^Pb^ Complex toward Tris-p-nitrophenyl Phosphate:A Functional Model of Heterobimetallic Phosphatases
- Heterodinuclear M^Ni^ (M = Co, Ni, Cu, Zn) Complexes of a Macrocyclic Compartmental Ligand. Anomalous EPR of Cu^Ni^ Complex by Coordination of 1-Methylimidazole
- A Geometrically Asymmetric Dinuclear Copper(II) Complex Derived from A New Unsymmetric 'End-off' Compartmental Ligand
- Template Synthesis of Phenol-based Heterodinucleating Macrocycles with Dissimilar N(amine)_2O_2 and N(imine)_2O_2 Metal-binding Sites
- Reversible Oxygenation of a μ-Acetato-di (μ-phenoxo) dicobalt (II) Core Complex and Crystal Structure of Its Oxygenated Complex
- Dinuclear Zinc Complexes of Phenol-Based "End-off" Compartmental Ligands: Synthesis, Structures and Phosphatase-Like Activity
- Magnetic Susceptibility of Some Mixed-Metal Compounds : NBu_4Zn(II)_xFe(II)_[Fe(III)(ox)_3]
- Isomerization of a Linear Pentamine, 1,4,7,10,13-Pentaazatridecane, to a Branched Form, 4-(Aminoethyl)-1,4,7,10-tetraazadecane, on a Schiff-base Copper Complex Relevant to Multi-copper Enzymes
- Synthesis and Ferromagnetic Spin-Coupling of Imidazolate-Bridged 3d-4d Cu(II)-Ru(III) Binuclear Complex
- Template Synthesis of Masrocyclic Dinuclear Cu^ Complexes and Conversion into Mononuclear Complexes by Site-Selective Copper Elimination
- A Macrocyclic Co(II)Pb(II)Complex : Neighboring Pb(II)Effect upon Reversible Superoxo-cobalt Complex Formation in Solid State
- Dioxygen Oxidation of Coordinated Nitrosyl to Nitro on Dmf-Bridged Dinuclear CoPb Complex
- Crystal structure of (chloro(tris((1-ethyl-1H-benzimidazol-2-yl)-methyl)amine)zinc(II)) tetraphenylborate acetone.
- Crystal structure and magnetic property of cubane tetranuclear copper(II) complex with ferromagnetic coupling.
- Specific binding of substrates containing nitrogen and oxygen donor groups to copper(II)-gadolinium(III) hetero-metal center.
- Crystal and molecular structure of a binuclear copper(II) complex with 1,2,3,4-tetrakis(salicylideneamino)-2,3-dimethylbutane.
- Binuclear metal complexes. XLIII. Magnetic, spectroscopic, and electrochemical studies on hetero-metal binuclear complexes of N,N'-bis(3-carboxysalicylidene)-1,1-dibenzylethylenediamine.
- Catalytic function of cobalt(III) complexes with N,N'-disalicyl-ideneethylenediamine on oxygenation of t-butylphenols.
- Synthesis and characterization of a chloro-bridged binuclear iron(III) complex.
- Ferromagnetic Spin-Coupling between Gadolinium(III) and Copper(II) Ions in Discrete Binuclear Gd(III)-Cu(II) Complexes.
- Nocovalent interactions in metal complexes. 14 Proton NMR spectroscopic investigation on stereoselectivity in cobalt(III) complexes of various 3-substituted 1-phenyl-1,3-propanediones.
- Binuclear Metal Complexes. X. Preparation and Magnetism of Mononuclear and Binuclear Copper(II) Complexes of Schiff Bases Derived from 4,6-Diacetylresorcine and Polyamines
- Noncovalent interactions in metal complexes. VIII. Syntheses, properties, and stereoselectivities of lanthanoid complexes with 1-l-menthyloxy-3-benzoylacetone.
- Binuclear metal complexes. LI. Synthesis and characterization of the tetrachloro-o-benzoquinone adducts of binuclear iron(II) complexes with 2-(salicylideneamino)phenol and its substituted homologs.
- Synthesis and magnetic property of binuclear oxovanadium(IV) complex of 2,6-diformyl-4-methylphenol bis(benzoylhydrazone).
- Synthesis and characterization of a new quinquedentate ligand consisting of salen skeleton and phenolic tail capable of axial coordination and its metal complexes.
- Binuclear metal complexes. 58 Synthesis and properties of mixed-valence diiron(III,IV) complexes of salen analogs with pendant thioether group.
- High stereoselectivity of tris(4-(l-menthyloxy)-1-(p-tolyl)-1,3-butandionato)lanthanoid(III).
- Binuclear metal complexes. XXIV. Synthesis and magnetism of binuclear cobalt(II) complexes in mixed-spin state.
- Binuclear metal complexes. XXXI. Synthesis and magnetic property of binuclear manganese (III) complexes with 3-salicylideneamino-1-propanol and its homologues.
- Binuclear metal complexes. XLII. Manganese(IV) complexes synthesized by oxidation of binuclear manganese(II) complexes of 2-(salicylideneamino)phenols with tetrachloro-o-benzoquinone.
- Binuclear metal complexes. XLV. Synthesis and magnetic, spectral, and electrochemical studies of strati-bis copper(II) complexes of some Schiff bases derived from primary tetraamines and salicylaldehydes.
- Binuclear metal complexes. IL. Synthesis, ESR, and electrochemical properties of strati-bis copper(II)-nickel(II) complexes.
- Macro Chelate Rings. III. Syntheses and Configurations of Complexes of New Ligands, 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)-diphenyl Ether and 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)diphenylamine
- Macro Chelate Rings. II. Syntheses and Properties of 2,7-Dimethyl-4,5-bis(salicylideneaminomethyl)xanthone as a Quadridentate Chelating Agent and Its Metal Complexes
- Binuclear Metal Complexes. IX. Syntheses and Magnetic Properties of Copper(II) and Nickel(II) Complexes of Schiff Bases Derived from 3-Formylsalicylic Acid and Alkyl Amines
- Binuclear metal complexes. XXIII. Molecular structure of a hetero-metal binuclear complex, CuCo(fsaen) 3H2O(C18H18N2O9CoCu).
- Substituent effect on stereoselectivity for cobalt(III), chromium(III), and manganese(III) complexes of ring-substituted 1-l-menthyloxy-3-benzoylacetones.
- Synthesis, spectral and magnetic properties and crystal structures of alkoxo-oxygen coordinated copper(II) complexes of N,N'-disubstituted malonamide and oxamide derivatives.
- Binuclear Metal Complexes. XIII. Syntheses and Magnetic Properties of Thiocyanato-Bridged Binuclear Copper(II) Complexes
- Synthesis and characterization of copper(II) and nikel(II) complexes of 1,5-diamino-3-pentanol and its derivatives.
- Stereoselectivity in Diastereomeric Tetrahedral Metal(II) Complexes of Chiral Salicylideneamines: Crystal Structure and Molecular Mechanics Calculation of Bis(N-(l-menthyl)salicylideneaminato)cobalt(II).
- Copper(II)-lanthanoid(III) complexes of binucleating ligands derived from 3-formylsalicylic acid and diamines.
- Binuclear metal complexes. XXXIX. Synthesis and properties of binuclear copper(II) complexes with (2-(2-pyridyl)ethylamino)-alkanols and (2-(2-pyridyl)ethylthio)alkanols.
- Binuclear metal complexes. XLI. Crystal structure and unusual magnetic property of isothiocyanato{2-(2-(dimethylamino)ethylthio)ethanolato}copper(II).
- Antiferromagnetic spin-exchange interaction in mixed-spin trinuclear cobalt(II) complexes with quadridentate schiff bases.
- Non-covalent interactions in metal complexes. II. Induction of asymmetry in cobalt(III) complexes with amino acid-schiff bases. Importance of CH .PI.-interaction in determining configuration of complexes.
- Synthesis and magnetism of trinuclear copper(II) complexes with a salen-like Schiff base and a tertiary diamine.
- Copper(II)-Rare Earth(III)(Ln=La,Gd,Lu) Binuclear Complexes of Bis(2-(3-carboxysalicylidene)aminoethyl)amine: Characterization and Specific Binding of Amino Alcohols.
- Binuclear metal complexes. XLIV. Crystal structures and magnetic properties of alkoxo-oxygen bridged binuclear copper(II) complexes with 2-(2-(dialkylamino)ethylthio)ethanol.
- Syntheses and configurations of copper(II) and nickel(II) complexes of trans-1,2-dicyano-1,2-cyclohexanediamine.
- Template synthesis and crystal structure of a dilead(II) complex of a macrocycle with N4O2 donor set.
- Synthesis and characterization of imidazolate-bridged copper(II) complexes of triangular skeleton.
- Synthesis, magnetic property, and crystal structure of imidazolate-bridged manganese(III)-copper(II) dinuclear complex.
- Binuclear Metal Complexes. XI. Substituent Effect upon Magnetisms of Binuclear Oxovanadium(IV) and Copper(II) Complexes of the Schiff Bases, 2,6-Bis[N-(2-hydroxy-5-substituted-phenyl)iminomethyl]-4-methylphenol
- Binuclear metal complexes XXXV. Synthesis and magnetism of binuclear copper(II) complexes with 3-(2-(dialkylamino)ethylthio)-1-propanols.
- Binuclear Copper(II) Complexes Derived From 3-Formyl-5-methyIsaIicyIaldehyde and Glycine
- Binuclear Metal Complexes. VII. Preparation and Properties of Binuclear Copper(II) and Nickel(II) Complexes of Hydrogen-bridged Macrocycles
- Binuclear Metal Complexes. III. Preparation and Properties of Mononuclear and Binuclear Copper(II) and Nickel(II) Complexes of New Macrocycles and Their Related Ligands
- Binuclear metal complexes. XXXVII. Crystal and molecular structure of a binuclear manganese(III) complex bridged by two alkoxo oxygens and two bidentate acetate ions.
- Dinuclear cobalt(II), iron(II), and manganese(II), and trinuclear manganese(II) complexes with tridentate ligands of NNS-donor set derived from 2-aminoethanethiol.