Binuclear metal complexes. XXXI. Synthesis and magnetic property of binuclear manganese (III) complexes with 3-salicylideneamino-1-propanol and its homologues.
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概要
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Binuclear manganese(III) complexes with 3-salicylideneamino-1-propanol and its homologues, MnL(ac) and MnLXH<SUB>2</SUB>O (L=Schiff base dianion; ac=acetate ion; X<SUP>−</SUP>=Cl<SUP>−</SUP>, Br<SUP>−</SUP>, N<SUB>3</SUB><SUP>−</SUP>), were synthesized. It was shown that manganese(III) ions were bridged by the deprotonated alcoholic oxygen of the Schiff base in the equatorial plane and coordinated by bidentate acetate ion or X<SUP>−</SUP> and H<SUB>2</SUB>O groups in apical positions to form six-coordination. Cryomagnetic measurements indicated that an antiferromagnetic spin-exchange interaction operates between a pair of manganese(III) ions; exchange integral being evaluated at −13.5–−20.4 cm<SUP>−1</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
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Mikuriya Masahiro
Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S
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Kida Sigeo
Department of Chemistry Wakayama University
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Torihara Naoyuki
Department of Chemistry, Faculty of Science, Kyushu University
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Mikuriya Masahiro
Department of Chemistry, Faculty of Science, Kyushu University
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