Dinuclear cobalt(II), iron(II), and manganese(II), and trinuclear manganese(II) complexes with tridentate ligands of NNS-donor set derived from 2-aminoethanethiol.
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概要
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Thiolate-bridged dinuclear cobalt(II), iron(II), and Manganese(II) complexes and trinuclear manganese(II) complexes of thiolic ligands, 2-[(2-aminoethyl)amino]ethanethiol, 2-[(3-aminopropyl)amino]ethanethiol, 2-[(2-pyridylmethyl)amino]ethanethiol, and 2-[[(2-pyridylethyl]amino]ethanethiol, were prepared and their magnetic properties were examined in the temperature range 80–300 K. The results indicated a significant antiferromagnetic spin-exchange interactions through the bridging sulfur atom for all the complexes.
- 公益社団法人 日本化学会の論文
著者
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Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
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Handa Makoto
Department Of Chemistry Faculty Of Science Shimane University
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Kida Sigeo
Department of Chemistry Wakayama University
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Handa Makoto
Department of Chemistry, Faculty of Science, Kyushu University
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