Copper(II)-Rare Earth(III)(Ln=La,Gd,Lu) Binuclear Complexes of Bis(2-(3-carboxysalicylidene)aminoethyl)amine: Characterization and Specific Binding of Amino Alcohols.

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概要

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• Heterometal complexes, [CuLn(fsadien)(NO<SUB>3</SUB>)(H<SUB>2</SUB>O)<I><SUB>n</SUB></I>]·(H<SUB>2</SUB>O)<SUB>5−<I>n</I></SUB> (Ln=La, Gd, or Lu), have been synthesized and characterized, where H<SUB>4</SUB> fsadien denotes bis[2-(3-carboxysalicylidene)aminoethyl]amine. Based on electronic absorption and CD spectra, it was suggested that amino alcohols were specifically bound to the Cu(II)–Ln(III) heterometal center, through the nitrogen to the copper(II) ion and through the oxygen to the rare earth(III) ion.

• 公益社団法人 日本化学会の論文

著者

• Okawa Hisashi

  Department Of Chemistry Faculty Of Science Kyushu University

• Tajima Kunihiko

  Department Of Applied Biology Kyoto Institute Of Technology

• Ishizu Kazuhiko

  Department Of Chemistry Faculty Of Science Ehime University

• Matsuki Kimihiro

  Department Of Applied Chemistry Faculty Of Engineering Ehime University

• SAKAMOTO Masatomi

  Department of Applied Chemistry, Faculty of Engineering, Ehime University

• Hashimura Masayuki

  Department of Applied Chemistry, Faculty of Engineering, Ehime University

• Hashimura Masayuki

  Department of Industrial Chemistry, Faculty of Engineering, Ehime University

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